Comparison of semi-doped PANI/DBSA complex achieved by thermal doping and roll-mill process: A new perspective for application

Zhou, Yu; Takahashi, Kohei; Naidu, Swathi V.R.; Kumar, Vipin; Goto, Teruya; Takahashi, Tatsuhiro

doi:10.1016/j.polymer.2020.122723

Comparison of semi-doped PANI/DBSA complex achieved by thermal doping and roll-mill process: A new perspective for application

Journal Article · Sat Aug 01 00:00:00 EDT 2020 · Polymer

DOI:https://doi.org/10.1016/j.polymer.2020.122723· OSTI ID:1649059

Zhou, Yu ^[1]; Takahashi, Kohei ^[2]; Naidu, Swathi V.R. ^[3]; ^[4]; Goto, Teruya ^[2]; Takahashi, Tatsuhiro ^[2]

Univ. of Tokyo (Japan)
Yamagata Univ. (Japan)
Univ. Siegen (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Conductive polymers have garnered extensive attention over the last few decades owing to their vast applications and relative ease of production. One such polymer is PANI; with versatile thermo-mechanical, chemical, and electrical properties, has been researched for varied applications in the field of electronics, electrodes and corrosion protection. In this study, we focus on an alternative route to process semi-doped PANI/DBSA complexes with special focus on material properties for improved processability. This study investigates the influence of two different material preparation techniques: roll-milling and thermal-doping, on the formability and processability of such polymer-complex systems. Results confirm similar doping levels achieved in both processes and shear-thinning behavior was only observed for roll-milled samples. These results underline the formability of roll-milled PANI/DBSA with thermosetting resins. It essentially explains the production route and offers a perspective for commercial manufacturing.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1649059

Alternate ID(s):: OSTI ID: 1693678

Journal Information:: Polymer, Journal Name: Polymer Journal Issue: NA Vol. 202; ISSN 0032-3861

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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