Melting temperature measurement of refractory oxide ceramics as a function of oxygen fugacity using containerless methods

Agca, Can; Neuefeind, Jörg C.; McMurray, Jake W.; Weber, Richard; Navrotsky, Alexandra

doi:10.1111/jace.17216

Melting temperature measurement of refractory oxide ceramics as a function of oxygen fugacity using containerless methods

Journal Article · Wed May 13 00:00:00 EDT 2020 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.17216· OSTI ID:1648884

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Univ. of California, Davis, CA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Materials Development, Inc., Arlington Heights, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Univ. of California, Davis, CA (United States); Arizona State Univ., Tempe, AZ (United States)

An aerodynamic conical nozzle levitator (CNL) has been used to measure the melting temperatures of refractory ceramics. The well-established method of cooling traces has been adapted to allow measurements for air-sensitive samples using a controlled atmosphere, where the oxygen partial pressure can be adjusted and monitored in real time. In this study, we explain the details of a system that we developed for use at the Spallation Neutron Source (Oak Ridge National Laboratory). Measurements of the melting behavior of (Fe,Cr,Al)₃O₄ spinels were made between log (PO₂ (atm)) of -0.7 and -5. The melting temperature of hercynite is found to be oxygen potential dependent, ranging between 1692 and 1767°C at log (PO₂) values from -4.42 to -0.70.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725

OSTI ID:: 1648884

Alternate ID(s):: OSTI ID: 1632217
OSTI ID: 1756847

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 9 Vol. 103; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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