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Title: A multirate mass transfer model to represent the interaction of multicomponent biogeochemical processes between surface water and hyporheic zones (SWAT-MRMT-R 1.0)

Journal Article · · Geoscientific Model Development (Online)

Surface water quality along river corridors can be modulated by hyporheic zones (HZs) that are ubiquitous and biogeochemically active. Watershed management practices often ignore the potentially important role of HZs as a natural reactor. To investigate the effect of hydrological exchange and biogeochemical processes on the fate of nutrients in surface water and HZs, a novel model, SWAT-MRMT-R, was developed coupling the Soil and Water Assessment Tool (SWAT) watershed model and the reaction module from a flow and reactive transport code (PFLOTRAN). SWAT-MRMT-R simulates concurrent nonlinear multicomponent biogeochemical reactions in both the channel water and its surrounding HZs, connecting the channel water and HZs through hyporheic exchanges. Within the model, HZs are conceptualized as transient storage zones with distinguished exchange rates and residence times. The biogeochemical processes within HZs are different from those in the channel water. Hyporheic exchanges are modeled as multiple first order mass transfers between the channel water and HZs. As a numerical example, SWAT-MRMT-R is applied to the Hanford Reach of the Columbia River, a large river in the United States, focusing on nitrate dynamics in the channel water. Major nitrate contaminants entering the Hanford Reach include those from the legacy waste, irrigation return flows (irrigation water that is not consumed by crops and runs off as point sources to the stream), and groundwater seepage resulted from irrigated agriculture. A two-step reactions for denitrification and an aerobic respiration reaction are assumed to represent the biogeochemical transformations taking place within the HZs. The spatially variable hyporheic exchange rates and residence times in this example are estimated with the basin-scale Networks with Exchange and Subsurface Storage (NEXSS) model. Our simulation results show that 1) as the commonly used transient storage model for stream–HZ exchange of solutes uses a single residence time to parameterize the exchange coefficient, it may overestimate the nitrate attenuation role of HZs ignoring the contribution from HZs with low residence times; and 2) source locations of nitrate have different impact on surface water quality due to the spatially variable hyporheic exchanges.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC04-94AL85000; AC05‐76RL01830; NA0003525; 54737
OSTI ID:
1646897
Alternate ID(s):
OSTI ID: 1639050; OSTI ID: 1668793
Report Number(s):
SAND-2019-13576J; PNNL-SA-148784
Journal Information:
Geoscientific Model Development (Online), Journal Name: Geoscientific Model Development (Online) Vol. 13 Journal Issue: 8; ISSN 1991-9603
Publisher:
European Geosciences UnionCopyright Statement
Country of Publication:
Germany
Language:
English
Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

References (60)

Surface and hyporheic transient storage dynamics throughout a coastal stream network: SURFACE AND HYPORHEIC TRANSIENT STORAGE journal June 2010
Hyporheic flow and residence time distributions in heterogeneous cross-bedded sediment: HYPORHEIC FLOW IN HETEROGENEOUS SEDIMENT journal August 2009
A general approach to advective–dispersive transport with multirate mass transfer journal January 2005
Dissolved nutrient retention dynamics in river networks: A modeling investigation of transient flows and scale effects: DISSOLVED NUTRIENT RETENTION DYNAMICS IN RIVER NETWORKS journal June 2012
Predicting the Tails of Breakthrough Curves in Regional-Scale Alluvial Systems journal July 2007
A hydrogeomorphic river network model predicts where and why hyporheic exchange is important in large basins journal September 2014
Deterministic influences exceed dispersal effects on hydrologically-connected microbiomes: Deterministic assembly of hyporheic microbiomes journal March 2017
Modeling hyporheic zone processes journal September 2003
Hyporheic zone influences on concentration-discharge relationships in a headwater sandstone stream: HYPORHEIC ZONE AND CQ journal June 2017
Correction to “Coupled transport and reaction kinetics control the nitrate source-sink function of hyporheic zones”: CORRECTION journal December 2012
Assessing regional-scale spatio-temporal patterns of groundwater-surface water interactions using a coupled SWAT-MODFLOW model: SWAT-MODFLOW Coupled Watershed Modelling journal January 2016
Are Rivers just big Streams? a Pulse Method to Quantify Nitrogen Demand in a Large River journal October 2008
The role of the hyporheic zone across stream networks journal May 2011
Multiple-Rate Mass Transfer for Modeling Diffusion and Surface Reactions in Media with Pore-Scale Heterogeneity journal June 1995
Hyporheic zone hydrologic science: A historical account of its emergence and a prospectus: Hyporheic zone hydrologic science: a historical account journal May 2015
Thinking outside the channel: modeling nitrogen cycling in networked river ecosystems journal September 2010
Scale-dependent desorption of uranium from contaminated subsurface sediments: SCALE-DEPENDENT DESORPTION OF URANIUM journal August 2008
On the Matching and Proportional Laws of Cybernetic Models journal February 2007
Evidence that hyporheic zones increase heterotrophic metabolism and phosphorus uptake in forest streams journal May 1997
Transfer of nonsorbing solutes to a streambed with bed forms: Theory journal January 1997
Quantifying the impact of groundwater discharge on the surface-subsurface exchange journal July 2009
Muskingum flood routing of upland streamflow journal January 1966
Biogeochemical Hot Spots and Hot Moments at the Interface of Terrestrial and Aquatic Ecosystems journal June 2003
Geomorphic controls on hyporheic exchange flow in mountain streams: GEOMORPHIC CONTROLS ON HYPORHEIC EXCHANGE journal January 2003
Relating hyporheic fluxes, residence times, and redox-sensitive biogeochemical processes upstream of beaver dams journal June 2013
Implications of water management representations for watershed hydrologic modeling in the Yakima River basin journal January 2019
Application of the transient storage model to analyze advective hyporheic exchange with deep and shallow sediment beds: HYPORHEIC EXCHANGE WITH SEDIMENT BEDS journal July 2003
Hydrogeomorphic controls on hyporheic and riparian transport in two headwater mountain streams during base flow recession: HYDROGEOMORPHIC CONTROLS ON HYPORHEIC TRANSPORT journal February 2016
Residence time distributions in surface transient storage zones in streams: Estimation via signal deconvolution: RTDS IN SURFACE TRANSIENT STORAGE ZONES journal May 2011
Parent lithology, surface-groundwater exchange, and nitrate retention in headwater streams journal March 1996
Residence time of bedform-driven hyporheic exchange journal October 2008
Regulation-Structured Dynamic Metabolic Model Provides a Potential Mechanism for Delayed Enzyme Response in Denitrification Process journal September 2017
A New Approach to Quantify Shallow Water Hydrologic Exchanges in a Large Regulated River Reach journal September 2017
Multiscale hyporheic exchange through strongly heterogeneous sediments journal November 2015
Ambient groundwater flow diminishes nitrate processing in the hyporheic zone of streams: AMBIENT GROUNDWATER AND STREAM N-CYCLING journal May 2017
Hyporheic flow and transport processes: Mechanisms, models, and biogeochemical implications: HYPORHEIC FLOW AND TRANSPORT PROCESSES journal October 2014
The evolution and state of interdisciplinary hyporheic research: The evolution and state of interdisciplinary hyporheic research journal November 2015
Mathematical equivalence between time-dependent single-rate and multirate mass transfer models: The Time-dependent Single-rate Mass Transfer Model journal May 2015
Transient Storage Assessments of Dye-Tracer Injections in Rivers of the Willamette Basin, Oregon journal April 2001
Surface storage dynamics in large rivers: Comparing three-dimensional particle transport, one-dimensional fractional derivative, and multirate transient storage models: SURFACE STORAGE DYNAMICS IN LARGE RIVERS journal September 2011
Drought Conditions Maximize the Impact of High‐Frequency Flow Variations on Thermal Regimes and Biogeochemical Function in the Hyporheic Zone journal October 2018
Denitrification in the Mississippi River network controlled by flow through river bedforms journal October 2015
Residence time distributions in sinuosity-driven hyporheic zones and their biogeochemical effects: RTD IN HYPORHEIC ZONES AND BIOGEOCHEMICAL EFFECTS journal September 2012
Reactive Solute Transport in Streams: 1. Development of an Equilibrium-Based Model journal February 1996
Hyporheic zone denitrification: Controls on effective reaction depth and contribution to whole-stream mass balance: Scaling hyporheic flow controls on stream denitrification journal October 2013
A Perspective on the Future of Transient Storage Modeling: Let's Stop Chasing Our Tails journal March 2020
Scaling Dissolved Nutrient Removal in River Networks: A Comparative Modeling Investigation: DISSOLVED NUTRIENT REMOVAL journal November 2017
Simulation of solute transport in a mountain pool-and-riffle stream: A transient storage model journal June 1983
A general real-time formulation for multi-rate mass transfer problems journal January 2009
The Functional Significance of the Hyporheic zone in Streams and Rivers journal November 1998
Two-zone transient storage modeling using temperature and solute data with multiobjective calibration: 1. Temperature: TWO-ZONE TRANSIENT STORAGE MODELING, 1 journal December 2010
Shape-free inference of hyporheic traveltime distributions from synthetic conservative and “smart” tracer tests in streams: INFERENCE OF HYPORHEIC TRAVEL TIMES journal July 2011
Fragmentation and Flow Regulation of the World's Large River Systems journal April 2005
Integrating hydraulic conductivity with biogeochemical gradients and microbial activity along river–groundwater exchange zones in a subtropical stream journal October 2008
Targeted quantification of functional enzyme dynamics in environmental samples for microbially mediated biogeochemical processes: Targeted quantification of functional enzyme dynamics journal July 2017
A method for estimating surface transient storage parameters for streams with concurrent hyporheic storage: ESTIMATING TRANSIENT STORAGE journal February 2009
Groundwater–surface water mixing shifts ecological assembly processes and stimulates organic carbon turnover journal April 2016
Retention and Transport of Nutrients in a Third-Order Stream in Northwestern California: Hyporheic Processes journal December 1989
Multiscale Framework for Modeling Multicomponent Reactive Transport in Stream Corridors journal October 2018
Gravel-bed river floodplains are the ecological nexus of glaciated mountain landscapes journal June 2016