Low-pressure methanol synthesis from CO2 over metal-promoted Ni-Ga intermetallic catalysts

Duyar, Melis S.; Gallo, Alessandro; Snider, Jonathan L.; Jaramillo, Thomas F.

doi:10.1016/j.jcou.2020.03.001

Title: Low-pressure methanol synthesis from CO₂ over metal-promoted Ni-Ga intermetallic catalysts

Journal Article · Fri Mar 13 00:00:00 EDT 2020 · Journal of CO2 Utilization

DOI:https://doi.org/10.1016/j.jcou.2020.03.001· OSTI ID:1646888

Duyar, Melis S. ^[1]; Gallo, Alessandro ^[2]; Snider, Jonathan L. ^[2]; Jaramillo, Thomas F. ^[2]

Stanford Univ., CA (United States). SUNCAT Center for Interface Science and Catalysis; SLAC National Accelerator Lab., Menlo Park, CA (United States); Univ. of Surrey, Guildford (United Kingdom)
Stanford Univ., CA (United States). SUNCAT Center for Interface Science and Catalysis; SLAC National Accelerator Lab., Menlo Park, CA (United States)

Ni-Ga and M-Ni-Ga (M = Au, Co, Cu) catalysts were evaluated for methanol synthesis from CO₂ at 10 bar and 200-270°C. The following trend in turnover frequency (TOF) for CO₂ hydrogenation was observed: AuNiGa > CuNiGa > NiGa > CoNiGa, where TOF increased with decreasing catalyst affinity for CO. The presence of a third metal was found to influence both the formation of the Ni-Ga intermetallic phase as well as the number of available sites for CO chemisorption. Phase formation, catalyst composition and stability were evaluated using therm ogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning transmission electron microscopy and energy dispersive X-ray spectroscopy (STEM-EDX). Au-Ni-Ga, which showed a nearly 4-fold improvement in TOF at 263°C and 10 bar compared to Ni-Ga, consisted of Ni₃Ga particles decorated with Au, as evidenced by post catalysis characterization.

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Research Organization:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-76SF00515; DGE-114747; ECCS-1542152

OSTI ID:: 1646888

Alternate ID(s):: OSTI ID: 1780544

Journal Information:: Journal of CO2 Utilization, Vol. 39; ISSN 2212-9820

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CO2 hydrogenation
methanol synthesis
intermetallic catalysts
CO2 utilization

Data for: Low-pressure methanol synthesis from CO2 over metal-promoted Ni-Ga intermetallic catalysts Duyar, Melis https://doi.org/10.17632/3rw2w68kdv The current record is supplemented by this dataset	dataset	January 2021
Data for: Low-pressure methanol synthesis from CO2 over metal-promoted Ni-Ga intermetallic catalysts Duyar, Melis https://doi.org/10.17632/3rw2w68kdv.1 The current record is supplemented by this dataset	dataset	January 2021

Title: Low-pressure methanol synthesis from CO2 over metal-promoted Ni-Ga intermetallic catalysts

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Title: Low-pressure methanol synthesis from CO₂ over metal-promoted Ni-Ga intermetallic catalysts