Silicon incorporation in polymethine dyes

Pengshung, Monica; Neal, Patrick; Atallah, Timothy L.; Kwon, Junho; Caram, Justin R.; Lopez, Steven A.; Sletten, Ellen M.

doi:10.1039/c9cc09671j

Silicon incorporation in polymethine dyes

Journal Article · Fri May 01 00:00:00 EDT 2020 · ChemComm

DOI:https://doi.org/10.1039/c9cc09671j· OSTI ID:1646128

Pengshung, Monica ^[1]; ^[2]; ^[3]; ^[3]; ^[3]; ^[2]; ^[3]

Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry; OSTI
Northeastern Univ., Boston, MA (United States). Dept. of Chemistry and Chemical Biology
Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry

Methods to red-shift fluorophores have garnered considerable interest due to the broad utility of low energy light. The incorporation of silicon into xanthene and coumarin scaffolds has resulted in an array of visible and near-infrared fluorophores. In this paper, we extend this approach to polymethine dyes, another popular fluorophore class, performing experimental and computational analyses. We found that when oxygen was replaced with SiMe₂, bathochromic shifts of up to 121 nm and fluorophores with emission above 900 nm were achieved.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Los Angeles, CA (United States)

Sponsoring Organization:: Alfred P. Sloan Foundation; National Institutes of Health (NIH); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019245

OSTI ID:: 1646128

Alternate ID(s):: OSTI ID: 1616777
OSTI ID: 1908036

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 45 Vol. 56; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Silicon incorporation in polymethine dyes

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