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Title: 3D Hybrid Plasmonic Framework with Au Nanopillars Embedded in Nitride Multilayers Integrated on Si

Journal Article · · Advanced Materials Interfaces
 [1];  [2];  [3];  [4];  [5];  [2];  [4];  [3];  [6];  [2]; ORCiD logo [2]
  1. Sun Yat-sen Univ., Guangdong (China); Purdue Univ., West Lafayette, IN (United States)
  2. Purdue Univ., West Lafayette, IN (United States)
  3. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  4. Texas A & M Univ., College Station, TX (United States)
  5. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  6. North Carolina State Univ., Raleigh, NC (United States)

Integration of nanoscale photonic and plasmonic components on Si substrates is a critical step toward Si-based integrated nanophotonic devices. Herein, a set of unique complex 3D metamaterials with intercalated nanolayered and nanopillar structures with tunable plasmonic and optical properties on Si substrates is designed. More specifically, the 3D metamaterials combine metal (Au) nanopillars and alternating metal-nitride (Au-TiN and Au-TaN) nanolayers, epitaxially grown on Si substrates. The ultrafine Au nanopillars (d ≈ 3 nm) continuously grow throughout all the nanolayers with high epitaxial quality. Novel optical properties, such as highly anisotropic optical property, high absorbance covering the entire visible spectrum regime, and hyperbolic property in the visible regime, are demonstrated. Furthermore, a waveguide based on a silicon nitride (Si3N4) ridge with a multilayer structure is successfully fabricated. The demonstration of 3D nanoscale metamaterial design integrated on Si opens up a new route toward tunable metamaterials nanostructure designs with versatile material selection for various optical components in Si integrated photonics.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies (CINT)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF); USDOE Office of Science (SC); USDOE Laboratory Directed Research and Development (LDRD) Program
Grant/Contract Number:
AC04-94AL85000; NA0003525; 89233218CNA000001
OSTI ID:
1639062
Alternate ID(s):
OSTI ID: 1634850; OSTI ID: 1739958
Report Number(s):
SAND-2020-6350J; LA-UR-20-28042; 686814
Journal Information:
Advanced Materials Interfaces, Vol. 7, Issue 17; ISSN 2196-7350
Publisher:
Wiley-VCHCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

References (42)

Plasmonic Cu nanostructures in ZnO as hyperbolic metamaterial thin films journal December 2019
Far-Field Optical Hyperlens Magnifying Sub-Diffraction-Limited Objects journal March 2007
Plasmonic nanorod metamaterials for biosensing journal October 2009
Reactively sputtered TiN as a diffusion barrier between Cu and Si journal November 1990
Temperature stability of thin film refractory plasmonic materials journal January 2018
Broad-band optical parametric gain on a silicon photonic chip journal June 2006
Tailorable Optical Response of Au-LiNbO 3 Hybrid Metamaterial Thin Films for Optical Waveguide Applications journal July 2018
Silicon CMOS-integrated nano-photonics for computer and data communications beyond 100G journal February 2012
Diffusion barrier property of TaN between Si and Cu journal August 1996
Experimental realization of three-dimensional indefinite cavities at the nanoscale with anomalous scaling laws journal June 2012
Optical Properties of Plasmonic Ultrathin TiN Films journal May 2017
Broadband Purcell effect: Radiative decay engineering with metamaterials journal April 2012
Enhancing spontaneous emission rates of molecules using nanopatterned multilayer hyperbolic metamaterials journal January 2014
Metamaterial-inspired silicon nanophotonics journal April 2017
Bridging the gap between optical fibers and silicon photonic integrated circuits journal January 2014
Self-assembled vertically aligned Ni nanopillars in CeO 2 with anisotropic magnetic and transport properties for energy applications journal January 2018
Optical Hyperlens: Far-field imaging beyond the diffraction limit journal January 2006
Optical Nonlocalities and Additional Waves in Epsilon-Near-Zero Metamaterials journal March 2009
Optical Negative Refraction in Bulk Metamaterials of Nanowires journal August 2008
Self-assembled Co–BaZrO 3 nanocomposite thin films with ultra-fine vertically aligned Co nanopillars journal January 2017
Hyperbolic metamaterials and their applications journal March 2015
Epitaxial growth of TiN films on (100) silicon substrates by laser physical vapor deposition journal September 1992
Exchange Bias Effect along Vertical Interfaces in La 0.7 Sr 0.3 MnO 3 :NiO Vertically Aligned Nanocomposite Thin Films Integrated on Silicon Substrates journal June 2018
Three-dimensional photonic metamaterials at optical frequencies journal December 2007
Planar hyperlens based on a modulated graphene monolayer journal February 2014
Controlling Electromagnetic Fields journal June 2006
Hyperbolic and plasmonic properties of Silicon/Ag aligned nanowire arrays journal January 2013
Micrometer-Scale Cubic Unit Cell 3D Metamaterial Layers journal October 2010
High-throughput silicon nanophotonic wavelength-insensitive switch for on-chip optical networks journal March 2008
Excitation of surface plasma wave at TiN/air interface in the Kretschmann geometry journal February 2011
Temperature-dependent optical properties of titanium nitride journal March 2017
Plasmons in Strongly Coupled Metallic Nanostructures journal June 2011
Nanowire metamaterials with extreme optical anisotropy journal December 2006
Optical interconnection networks for high-performance computing systems journal March 2012
Spherical hyperlens for two-dimensional sub-diffractional imaging at visible frequencies journal December 2010
Metamaterials: a new frontier of science and technology journal January 2011
Nanoscale Artificial Plasmonic Lattice in Self-Assembled Vertically Aligned Nitride-Metal Hybrid Metamaterials journal April 2018
Epitaxial superlattices with titanium nitride as a plasmonic component for optical hyperbolic metamaterials journal May 2014
Reversing the size-dependence of surface plasmon resonances journal July 2010
Biosensing with plasmonic nanosensors journal June 2008
Superlenses to overcome the diffraction limit journal June 2008
Self-Assembled Epitaxial Au–Oxide Vertically Aligned Nanocomposites for Nanoscale Metamaterials journal May 2016