Controlled Release of Hydrogen Isotopes from Hydride-Magnetic Nanomaterials

Hunyadi Murph, Simona E.; Coopersmith, Kaitlin; Sessions, Henry; Brown, Michael; Larsen, George

doi:10.1021/acsami.0c00887

Controlled Release of Hydrogen Isotopes from Hydride-Magnetic Nanomaterials

Journal Article · Thu Jan 30 00:00:00 EST 2020 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.0c00887· OSTI ID:1637908

^[1]; Coopersmith, Kaitlin ^[2]; Sessions, Henry ^[2]; Brown, Michael ^[2]; ^[2]

Univ. of Georgia, Athens, GA (United States)
Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

In this work, hydrogen isotopes in the form of protium and deuterium were rapidly desorbed from magnetic-hydride iron oxide-palladium (Fe₂O₃-Pd) hybrid nanomaterials using an alternating magnetic field (AMF). Palladium, a hydride material with a well-known hydrogen isotope effect, was deposited on Fe₂O₃ magnetic nanoparticle support by solution chemistries and used as a hydrogen isotope storage component. The morphological, structural, optical, and magnetic studies reveal that the Fe₂O₃-Pd nanoparticles (NPs) are hybrid structures exhibiting both hydrogen isotope storage (Pd) and magnetic (Fe₂O₃) properties. The hydrogen isotope sorption/desorption behavior of metal hydride-magnetic nanomaterials was assessed by isothermal pressure-composition response curves (isotherms). The amount and rate of hydrogen isotope gas release was tuned by simply adjusting the strength of the magnetic field strength applied. Protium and deuterium displayed a similar loading capacity, namely H/M 0.55 and H/M=0.45, but different plateau pressures. Significant differences in the kinetics of release for protium and deuterium during magnetic heating were observed. A series of magnetically induced charge-discharge cycling experiments were conducted showing that this is a highly reproducible and robust process

View Accepted Manuscript (DOE)

Research Organization:: Savannah River National Lab (SRNL), Aiken, SC (United States); Savannah River Site (SRS), Aiken, SC (United States)

Sponsoring Organization:: USDOE Office of Environmental Management (EM)

Grant/Contract Number:: AC09-08SR22470

OSTI ID:: 1637908

Alternate ID(s):: OSTI ID: 1638473

Report Number(s):: SRNL-STI--2019-00331; SRNL-STI--2020-00009

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 8 Vol. 12; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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