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Guanidine compounds for carbon dioxide capture

Patent ·
OSTI ID:1637853

A method for removing carbon dioxide from a gaseous source, the method comprising: (i) contacting said gaseous source with an aqueous solution of a carbon dioxide sorbent that reacts with carbon dioxide to form an aqueous-soluble carbonate or bicarbonate salt of said carbon dioxide sorbent; (ii) contacting the aqueous solution from step (i) with a bis-iminoguanidine carbon dioxide complexing compound, which is different from the carbon dioxide sorbent, to result in precipitation of a carbonate or bicarbonate salt of said carbon dioxide complexing compound and regeneration of the carbon dioxide sorbent; and (iii) removing the precipitated carbonate or bicarbonate salt from the aqueous solution in step (ii) to result in a solid form of said carbonate or bicarbonate salt of the carbon dioxide complexing compound. The method may further include a step (iv) of regenerating the carbon dioxide complexing compound by subjecting the precipitated salt to sufficient heat and/or vacuum.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
Assignee:
UT-Battelle, LLC (Oak Ridge, TN)
Patent Number(s):
10,583,387
Application Number:
15/978,323
OSTI ID:
1637853
Country of Publication:
United States
Language:
English

References (5)

The trypanocidal activity of various aromatic bisguanylhydrazones in vivo journal January 1982
Pharmaceutical Salts journal January 1977
Aqueous Sulfate Separation by Sequestration of [(SO 4 ) 2 (H 2 O) 4 ] 4− Clusters within Highly Insoluble Imine-Linked Bis-Guanidinium Crystals journal December 2015
Novel endotoxin-sequestering compounds with terephthalaldehyde-bis-guanylhydrazone scaffolds journal March 2006
Aqueous Sulfate Separation by Crystallization of Sulfate-Water Clusters journal August 2015

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