Single-Atom Alloy Catalysis

Hannagan, Ryan T.; Giannakakis, Georgios; Flytzani-Stephanopoulos, Maria; Sykes, E. Charles H.

doi:10.1021/acs.chemrev.0c00078

Title: Single-Atom Alloy Catalysis

Journal Article · Fri Jun 26 00:00:00 EDT 2020 · Chemical Reviews

DOI:https://doi.org/10.1021/acs.chemrev.0c00078· OSTI ID:1635801

Hannagan, Ryan T. ^[1]; Giannakakis, Georgios ^[1]; Flytzani-Stephanopoulos, Maria ^[1];

^[1]

Tufts Univ., Medford, MA (United States)

Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site catalysis and are typically composed of catalytically active elements atomically dispersed in more inert and catalytically selective host metals. SAAs have been shown to catalyze a range of industrially important reactions in electro-, photo-, and thermal catalysis studies. Due to the unique geometry of SAAs, the location of the transition state and the binding site of reaction intermediates are often decoupled, which can enable both facile dissociation of reactants and weak binding of intermediates, two key factors for efficient and selective catalysis. Often, this results in deviations from transition metal scaling relationships that limit conventional catalysts. SAAs also offer reduced susceptibility to CO poisoning, cost savings from reduced precious metal usage, opportunities for bifunctional mechanisms via spillover, and higher resistance to deactivation by coking that plagues many industrial catalysts. In this review, we begin by introducing SAAs and describe how model systems and nanoparticle catalysts can be prepared and characterized. We then review all available SAA literature on a per reaction basis before concluding with a description of the general properties of this new class of heterogeneous catalysts and presenting opportunities for future research and development.

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Research Organization:: Tufts Univ., Medford, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0004738; SC0012573

OSTI ID:: 1635801

Alternate ID(s):: OSTI ID: 1773870; OSTI ID: 1844978

Journal Information:: Chemical Reviews, Vol. 120, Issue 21; ISSN 0009-2665

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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