AgPd nanoparticles for electrocatalytic CO2 reduction: bimetallic composition-dependent ligand and ensemble effects

Cui, Meiyang; Johnson, Grayson; Zhang, Zhiyong; Li, Shuang; Hwang, Sooyeon; Zhang, Xu; Zhang, Sen

doi:10.1039/D0NR03203D

AgPd nanoparticles for electrocatalytic CO₂ reduction: bimetallic composition-dependent ligand and ensemble effects

Journal Article · Mon Jun 08 00:00:00 UTC 2020 · Nanoscale

DOI:https://doi.org/10.1039/D0NR03203D· OSTI ID:1633604

^[1]; ^[1]; Zhang, Zhiyong ^[1]; Li, Shuang ^[2]; ^[2]; Zhang, Xu ^[3]; ^[1]

Univ. of Virginia, Charlottesville, VA (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
California State Univ., Northridge, CA (United States)

By balancing bimetallic composition-associated ligand and ensemble effects, Ag₁₅Pd₈₅ nanoparticles show enhanced catalytic properties for electrochemical CO₂ reduction.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1633604

Alternate ID(s):: OSTI ID: 1635043

Report Number(s):: BNL--216048-2020-JAAM

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 26 Vol. 12; ISSN NANOHL; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (52)

Electrochemical CO ₂ Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design Kibria, Md Golam; Edwards, Jonathan P.; Gabardo, Christine M. Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201807166	journal	December 2018
Shape-Controlled CO ₂ Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra Zhu, Wenlei; Kattel, Shyam; Jiao, Feng Advanced Energy Materials, Vol. 9, Issue 9 https://doi.org/10.1002/aenm.201802840	journal	January 2019
Monodisperse AgPd Alloy Nanoparticles and Their Superior Catalysis for the Dehydrogenation of Formic Acid Zhang, Sen; Metin, Önder; Su, Dong Angewandte Chemie International Edition, Vol. 52, Issue 13 https://doi.org/10.1002/anie.201300276	journal	February 2013
Exclusive Formation of Formic Acid from CO ₂ Electroreduction by a Tunable Pd-Sn Alloy Bai, Xiaofang; Chen, Wei; Zhao, Chengcheng Angewandte Chemie International Edition, Vol. 56, Issue 40 https://doi.org/10.1002/anie.201707098	journal	August 2017
Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles Gao, Dunfeng; Zhou, Hu; Cai, Fan Nano Research, Vol. 10, Issue 6 https://doi.org/10.1007/s12274-017-1514-6	journal	April 2017
Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839 https://doi.org/10.1016/0013-4686(94)85172-7	journal	August 1994
FT-IR investigation of CO-adsorption on Pd-black and on supported Pd-samples Mink, J.; Keresztury, G.; Szilágyi, T. Journal of Molecular Structure, Vol. 293 https://doi.org/10.1016/0022-2860(93)80068-7	journal	March 1993
Chemisorption on metals Muscat, J. P.; Newns, D. M. Progress in Surface Science, Vol. 9, Issue 1 https://doi.org/10.1016/0079-6816(78)90005-9	journal	January 1978
Infrared spectroscopic investigation of CO adsorbed on Pd aggregates deposited on an alumina model support Wolter, K.; Seiferth, O.; Kuhlenbeck, H. Surface Science, Vol. 399, Issue 2-3 https://doi.org/10.1016/S0039-6028(97)00817-0	journal	March 1998
Density functional calculations on hydrogen in palladium–silver alloys Løvvik, O. M.; Olsen, R. A. Journal of Alloys and Compounds, Vol. 330-332 https://doi.org/10.1016/S0925-8388(01)01491-8	journal	January 2002
Poisoning and deactivation of palladium catalysts Albers, Peter; Pietsch, Jörg; Parker, Stewart F. Journal of Molecular Catalysis A: Chemical, Vol. 173, Issue 1-2 https://doi.org/10.1016/S1381-1169(01)00154-6	journal	September 2001
Highly selective hydrodechlorination of 1,2-dichloroethane to ethylene over Ag-Pd/ZrO2 catalysts with trace Pd Han, Yuxiang; Sun, Jingya; Fu, Heyun Applied Catalysis A: General, Vol. 519 https://doi.org/10.1016/j.apcata.2016.03.017	journal	June 2016
Opportunities and prospects in the chemical recycling of carbon dioxide to fuels Centi, Gabriele; Perathoner, Siglinda Catalysis Today, Vol. 148, Issue 3-4 https://doi.org/10.1016/j.cattod.2009.07.075	journal	November 2009
Effect of nanostructured carbon support on copper electrocatalytic activity toward CO2 electroreduction to hydrocarbon fuels Baturina, Olga; Lu, Qin; Xu, Feng Catalysis Today, Vol. 288 https://doi.org/10.1016/j.cattod.2016.11.001	journal	June 2017
Facet design promotes electroreduction of carbon dioxide to carbon monoxide on palladium nanocrystals Dong, Hao; Zhang, Lei; Yang, Piaoping Chemical Engineering Science, Vol. 194 https://doi.org/10.1016/j.ces.2018.03.029	journal	February 2019
Hydrodechlorination of 1,2-dichloroethane on supported AgPd catalysts Ball, Madelyn R.; Rivera-Dones, Keishla R.; Stangland, Eric Journal of Catalysis, Vol. 370 https://doi.org/10.1016/j.jcat.2018.12.019	journal	February 2019
Highly selective palladium-copper bimetallic electrocatalysts for the electrochemical reduction of CO2 to CO Yin, Zhen; Gao, Dunfeng; Yao, Siyu Nano Energy, Vol. 27 https://doi.org/10.1016/j.nanoen.2016.06.035	journal	September 2016
Competition between Hydrogen Evolution and Carbon Dioxide Reduction on Copper Electrodes in Mildly Acidic Media Ooka, Hideshi; Figueiredo, Marta C.; Koper, Marc T. M. Langmuir, Vol. 33, Issue 37 https://doi.org/10.1021/acs.langmuir.7b00696	journal	May 2017
Electrochemical CO ₂ Reduction to Formic Acid at Low Overpotential and with High Faradaic Efficiency on Carbon-Supported Bimetallic Pd–Pt Nanoparticles Kortlever, Ruud; Peters, Ines; Koper, Sander ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00602	journal	June 2015
Rational Design of Bi Nanoparticles for Efficient Electrochemical CO ₂ Reduction: The Elucidation of Size and Surface Condition Effects Zhang, Zhiyong; Chi, Miaofang; Veith, Gabriel M. ACS Catalysis, Vol. 6, Issue 9 https://doi.org/10.1021/acscatal.6b01297	journal	August 2016
Pd-Containing Nanostructures for Electrochemical CO ₂ Reduction Reaction Gao, Dunfeng; Zhou, Hu; Cai, Fan ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03612	journal	January 2018
Bimetallic Composition-Promoted Electrocatalytic Hydrodechlorination Reaction on Silver–Palladium Alloy Nanoparticles Peng, Yiyin; Cui, Meiyang; Zhang, Zhiyong ACS Catalysis, Vol. 9, Issue 12 https://doi.org/10.1021/acscatal.9b02282	journal	September 2019
Catalysis for the Valorization of Exhaust Carbon: from CO ₂ to Chemicals, Materials, and Fuels. Technological Use of CO ₂ Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella Chemical Reviews, Vol. 114, Issue 3 https://doi.org/10.1021/cr4002758	journal	November 2013
Structural, Optical, and Electrical Properties of PbSe Nanocrystal Solids Treated Thermally or with Simple Amines Law, Matt; Luther, Joseph M.; Song, Qing Journal of the American Chemical Society, Vol. 130, Issue 18 https://doi.org/10.1021/ja800040c	journal	May 2008
Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation Mazumder, Vismadeb; Sun, Shouheng Journal of the American Chemical Society, Vol. 131, Issue 13 https://doi.org/10.1021/ja9004915	journal	April 2009
Programmable Synthesis of Multimetallic Phosphide Nanorods Mediated by Core/Shell Structure Formation and Conversion Zhang, Yulu; Li, Na; Zhang, Zhiyong Journal of the American Chemical Society, Vol. 142, Issue 18 https://doi.org/10.1021/jacs.0c02584	journal	April 2020
Size-Dependent Electrocatalytic Reduction of CO ₂ over Pd Nanoparticles Gao, Dunfeng; Zhou, Hu; Wang, Jing Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/jacs.5b00046	journal	March 2015
Ensemble Effect in Bimetallic Electrocatalysts for CO ₂ Reduction Wang, Yuxuan; Cao, Liang; Libretto, Nicole J. Journal of the American Chemical Society, Vol. 141, Issue 42 https://doi.org/10.1021/jacs.9b05766	journal	September 2019
Generalized Synthetic Strategy for Transition-Metal-Doped Brookite-Phase TiO ₂ Nanorods Zhang, Zhiyong; Wu, Qiyuan; Johnson, Grayson Journal of the American Chemical Society, Vol. 141, Issue 42 https://doi.org/10.1021/jacs.9b06389	journal	September 2019
Surface Reactivity of Pd Nanoparticles Supported on Polycrystalline Substrates As Compared to Thin Film Model Catalysts: Infrared Study of CO Adsorption Bertarione, Serena; Scarano, Domenica; Zecchina, Adriano The Journal of Physical Chemistry B, Vol. 108, Issue 11 https://doi.org/10.1021/jp036718t	journal	March 2004
Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction Whipple, Devin T.; Kenis, Paul J. A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458 https://doi.org/10.1021/jz1012627	journal	December 2010
Activity Descriptors for CO ₂ Electroreduction to Methane on Transition-Metal Catalysts Peterson, Andrew A.; Nørskov, Jens K. The Journal of Physical Chemistry Letters, Vol. 3, Issue 2 https://doi.org/10.1021/jz201461p	journal	January 2012
Rational Synthesis of Ultrathin n-Type Bi₂Te₃ Nanowires with Enhanced Thermoelectric Properties Zhang, Genqiang; Kirk, Benjamin; Jauregui, Luis A. Nano Letters, Vol. 12, Issue 1, p. 56-60 https://doi.org/10.1021/nl202935k	journal	November 2011
Effects of process conditions and electrode material on reaction pathways for carbon dioxide electroreduction with particular reference to formate formation Chaplin, R. P. S.; Wragg, A. A. Journal of Applied Electrochemistry, Vol. 33, Issue 12, p. 1107-1123 https://doi.org/10.1023/B:JACH.0000004018.57792.b8	journal	December 2003
The effects of currents and potentials on the selectivities of copper toward carbon dioxide electroreduction Ren, Dan; Fong, Jinhuan; Yeo, Boon Siang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03286-w	journal	March 2018
Tuning the activity and selectivity of electroreduction of CO2 to synthesis gas using bimetallic catalysts Lee, Ji Hoon; Kattel, Shyam; Jiang, Zhao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11352-0	journal	August 2019
Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts Schneider, Jacob; Jia, Hongfei; Muckerman, James T. Chem. Soc. Rev., Vol. 41, Issue 6 https://doi.org/10.1039/C1CS15278E	journal	January 2012
Electrochemical promotion of catalysis over Pd nanoparticles for CO ₂ reduction Cai, Fan; Gao, Dunfeng; Zhou, Hu Chemical Science, Vol. 8, Issue 4 https://doi.org/10.1039/C6SC04966D	journal	January 2017
Revealing structural evolution of PbS nanocrystal catalysts in electrochemical CO ₂ reduction using in situ synchrotron radiation X-ray diffraction Zhang, Zhiyong; Liu, Chang; Brosnahan, John T. Journal of Materials Chemistry A, Vol. 7, Issue 41 https://doi.org/10.1039/C9TA06750G	journal	January 2019
Ligand and ensemble effects in adsorption on alloy surfaces Liu, P.; Nørskov, J. K. Physical Chemistry Chemical Physics, Vol. 3, Issue 17 https://doi.org/10.1039/b103525h	journal	January 2001
The interaction of CO with PdAg/Pd(111) surface alloys—A case study of ensemble effects on a bimetallic surface Ma, Yunsheng; Diemant, T.; Bansmann, J. Physical Chemistry Chemical Physics, Vol. 13, Issue 22 https://doi.org/10.1039/c1cp00009h	journal	January 2011
Localized Magnetic States in Metals Anderson, P. W. Physical Review, Vol. 124, Issue 1 https://doi.org/10.1103/PhysRev.124.41	journal	October 1961
Self-Consistent Model of Hydrogen Chemisorption Newns, D. M. Physical Review, Vol. 178, Issue 3 https://doi.org/10.1103/PhysRev.178.1123	journal	February 1969
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals Hammer, B.; Hansen, L. B.; Nørskov, J. K. Physical Review B, Vol. 59, Issue 11 https://doi.org/10.1103/PhysRevB.59.7413	journal	March 1999
Core-level shifts in fcc random alloys: A first-principles approach Olovsson, W.; Göransson, C.; Pourovskii, L. V. Physical Review B, Vol. 72, Issue 6 https://doi.org/10.1103/PhysRevB.72.064203	journal	August 2005
Effects of d -band shape on the surface reactivity of transition-metal alloys Xin, Hongliang; Vojvodic, Aleksandra; Voss, Johannes Physical Review B, Vol. 89, Issue 11 https://doi.org/10.1103/PhysRevB.89.115114	journal	March 2014
Valence-Band Hybridization and Core Level Shifts in Random Ag-Pd Alloys Abrikosov, I. A.; Olovsson, W.; Johansson, B. Physical Review Letters, Vol. 87, Issue 17 https://doi.org/10.1103/PhysRevLett.87.176403	journal	October 2001
The Promotional Effect of Gold in Catalysis by Palladium-Gold Chen, M. Science, Vol. 310, Issue 5746 https://doi.org/10.1126/science.1115800	journal	October 2005
PbSe Nanocrystal Solids for n- and p-Channel Thin Film Field-Effect Transistors Talapin, D. V. Science, Vol. 310, Issue 5745, p. 86-89 https://doi.org/10.1126/science.1116703	journal	October 2005

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