Preparation of Nonprecious Metal Electrocatalysts for the Reduction of Oxygen Using a Low-Temperature Sacrificial Metal

Al-Zoubi, Talha; Zhou, Yu; Yin, Xi; Janicek, Blanka; Sun, Chengjun; Schulz, Charles E.; Zhang, Xiaohui; Gewirth, Andrew A.; Huang, Pinshane; Zelenay, Piotr; Yang, Hong

doi:10.1021/jacs.9b11061

Title: Preparation of Nonprecious Metal Electrocatalysts for the Reduction of Oxygen Using a Low-Temperature Sacrificial Metal

Journal Article · Mon Mar 02 00:00:00 EST 2020 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.9b11061· OSTI ID:1632829

Al-Zoubi, Talha ^[1]; Zhou, Yu ^[1];

^[2]; Janicek, Blanka ^[1]; Sun, Chengjun ^[3]; Schulz, Charles E. ^[4]; Zhang, Xiaohui ^[5];

^[1];

^[1]; Zelenay, Piotr ^[2];

^[1]

Univ. of Illinois at Urbana-Champaign, IL (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Knox College, Galesburg, IL (United States)
CRRC Industrial Academy Co., Ltd, Fengtai, Beijing (China)

Non-platinum group metal (non-PGM) electrocatalysts for the oxygen reduction reaction (ORR) are generally composed of iron, nitrogen, and carbon synthesized through high-temperature pyrolysis. Among the various types of precursors, metal-organic frameworks (MOFs), zeolitic imidazolate framework (ZIF)-8 in particular, have often been used in the synthesis. The pyrolysis of ZIF-8 precursor relies on the use of Zn as a sacrificial metal (SM), and the optimal processing temperatures often exceed 1000 degrees C to generate active non-PGM catalysts. The high pyrolysis temperature tends to result in heterogeneous active moieties ranging from Fe single atoms to nanoparticles. In this study, we present the synthesis of non-PGM catalysts using Cd as the sacrificial metal instead of Zn. By using Cd, we were able to generate active non-PGM electrocatalysts from the MOF precursors at a low pyrolysis temperature of 750 degrees C, which helps preserve the single atomic iron active sites.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1632829

Journal Information:: Journal of the American Chemical Society, Vol. 142, Issue 12; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 75 works

Citation information provided by
Web of Science

References (56)

Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
The Priority and Challenge of High-Power Performance of Low-Platinum Proton-Exchange Membrane Fuel Cells Kongkanand, Anusorn; Mathias, Mark F. The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00216	journal	March 2016
Catalysts by Platonic design Strasser, P. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aac7861	journal	July 2015
Platinum-Based Oxygen Reduction Electrocatalysts Wu, Jianbo; Yang, Hong Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300359w	journal	April 2013
Ultralow-loading platinum-cobalt fuel cell catalysts derived from imidazolate frameworks Chong, Lina; Wen, Jianguo; Kubal, Joseph Science, Vol. 362, Issue 6420 https://doi.org/10.1126/science.aau0630	journal	November 2018
Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets Zhang, L.; Roling, L. T.; Wang, X. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aab0801	journal	July 2015
Designer platinum nanoparticles: Control of shape, composition in alloy, nanostructure and electrocatalytic property Peng, Zhenmeng; Yang, Hong Nano Today, Vol. 4, Issue 2 https://doi.org/10.1016/j.nantod.2008.10.010	journal	April 2009
Atomically Dispersed Metal Catalysts for Oxygen Reduction Chen, Mengjie; He, Yanghua; Spendelow, Jacob S. ACS Energy Letters, Vol. 4, Issue 7 https://doi.org/10.1021/acsenergylett.9b00804	journal	June 2019
Current challenge and perspective of PGM-free cathode catalysts for PEM fuel cells Wu, Gang Frontiers in Energy, Vol. 11, Issue 3 https://doi.org/10.1007/s11708-017-0477-3	journal	June 2017
Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1427	journal	August 2011
Advancements in rationally designed PGM-free fuel cell catalysts derived from metal–organic frameworks Barkholtz, Heather M.; Liu, Di-Jia Materials Horizons, Vol. 4, Issue 1 https://doi.org/10.1039/C6MH00344C	journal	January 2017
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol Chemical Reviews, Vol. 116, Issue 6 https://doi.org/10.1021/acs.chemrev.5b00462	journal	February 2016
Nonprecious Metal Catalysts for Oxygen Reduction in Heterogeneous Aqueous Systems Gewirth, Andrew A.; Varnell, Jason A.; DiAscro, Angela M. Chemical Reviews, Vol. 118, Issue 5 https://doi.org/10.1021/acs.chemrev.7b00335	journal	December 2017
Revealing the Role of the Metal in Non-Precious-Metal Catalysts for Oxygen Reduction via Selective Removal of Fe Varnell, Jason A.; Sotiropoulos, James S.; Brown, Therese M. ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00144	journal	March 2018
Design of N-Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction Wang, Jing; Huang, Zhengqing; Liu, Wei Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b10385	journal	November 2017
Improved ethanol electrooxidation performance by shortening Pd–Ni active site distance in Pd–Ni–P nanocatalysts Chen, Lin; Lu, Lilin; Zhu, Hengli Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14136	journal	April 2017
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt Wu, G.; More, K. L.; Johnston, C. M. Science, Vol. 332, Issue 6028, p. 443-447 https://doi.org/10.1126/science.1200832	journal	April 2011
Engineering nanostructures of PGM-free oxygen-reduction catalysts using metal-organic frameworks Zhang, Hanguang; Osgood, Hannah; Xie, Xiaohong Nano Energy, Vol. 31 https://doi.org/10.1016/j.nanoen.2016.11.033	journal	January 2017
Identification of carbon-encapsulated iron nanoparticles as active species in non-precious metal oxygen reduction catalysts Varnell, Jason A.; Tse, Edmund C. M.; Schulz, Charles E. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12582	journal	August 2016
Hollow Spheres of Iron Carbide Nanoparticles Encased in Graphitic Layers as Oxygen Reduction Catalysts Hu, Yang; Jensen, Jens Oluf; Zhang, Wei Angewandte Chemie International Edition, Vol. 53, Issue 14 https://doi.org/10.1002/anie.201400358	journal	February 2014
Iron Carbide Nanoparticles Encapsulated in Mesoporous Fe-N-Doped Carbon Nanofibers for Efficient Electrocatalysis Wu, Zhen-Yu; Xu, Xing-Xing; Hu, Bi-Cheng Angewandte Chemie International Edition, Vol. 54, Issue 28 https://doi.org/10.1002/anie.201502173	journal	May 2015
Understanding the High Activity of Fe–N–C Electrocatalysts in Oxygen Reduction: Fe/Fe ₃ C Nanoparticles Boost the Activity of Fe–N _x Jiang, Wen-Jie; Gu, Lin; Li, Li Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.6b00757	journal	March 2016
Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction Zitolo, Andrea; Ranjbar-Sahraie, Nastaran; Mineva, Tzonka Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01100-7	journal	October 2017
Heat-Treated Fe/N/C Catalysts for O₂ Electroreduction: Are Active Sites Hosted in Micropores? Jaouen, Frédéric; Lefèvre, Michel; Dodelet, Jean-Pol The Journal of Physical Chemistry B, Vol. 110, Issue 11, p. 5553-5558 https://doi.org/10.1021/jp057135h	journal	March 2006
Structure of the catalytic sites in Fe/N/C-catalysts for O2-reduction in PEM fuel cells Kramm, Ulrike I.; Herranz, Juan; Larouche, Nicholas Physical Chemistry Chemical Physics, Vol. 14, Issue 33 https://doi.org/10.1039/c2cp41957b	journal	January 2012
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa Nature Materials, Vol. 14, Issue 9 https://doi.org/10.1038/nmat4367	journal	August 2015
Probing active sites in iron-based catalysts for oxygen electro-reduction: A temperature-dependent 57 Fe Mössbauer spectroscopy study Sougrati, Moulay Tahar; Goellner, Vincent; Schuppert, Anna K. Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.10.017	journal	March 2016
Cobalt Imidazolate Framework as Precursor for Oxygen Reduction Reaction Electrocatalysts Ma, Shengqian; Goenaga, Gabriel A.; Call, Ann V. Chemistry - A European Journal, Vol. 17, Issue 7 https://doi.org/10.1002/chem.201003080	journal	January 2011
Directly converting Fe-doped metal–organic frameworks into highly active and stable Fe-N-C catalysts for oxygen reduction in acid Wang, Xiaojuan; Zhang, Hanguang; Lin, Honghong Nano Energy, Vol. 25 https://doi.org/10.1016/j.nanoen.2016.04.042	journal	July 2016
Directed Growth of Metal-Organic Frameworks and Their Derived Carbon-Based Network for Efficient Electrocatalytic Oxygen Reduction Li, Zhenhua; Shao, Mingfei; Zhou, Lei Advanced Materials, Vol. 28, Issue 12 https://doi.org/10.1002/adma.201505086	journal	January 2016
An efficient Co–N–C oxygen reduction catalyst with highly dispersed Co sites derived from a ZnCo bimetallic zeolitic imidazolate framework Wang, Xiaojuan; Fan, Xinxin; Lin, Honghong RSC Advances, Vol. 6, Issue 44 https://doi.org/10.1039/C6RA04771H	journal	January 2016
Metal-Organic-Framework-Derived Dual Metal- and Nitrogen-Doped Carbon as Efficient and Robust Oxygen Reduction Reaction Catalysts for Microbial Fuel Cells Tang, Haolin; Cai, Shichang; Xie, Shilei Advanced Science, Vol. 3, Issue 2 https://doi.org/10.1002/advs.201500265	journal	December 2015
Carbon-based electrocatalyst derived from bimetallic metal-organic framework arrays for high performance oxygen reduction Li, Zhenhua; Shao, Mingfei; Zhou, Lei Nano Energy, Vol. 25 https://doi.org/10.1016/j.nanoen.2016.04.041	journal	July 2016
Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts Armel, Vanessa; Hindocha, Sheena; Salles, Fabrice Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b11248	journal	December 2016
Metal organic frameworks derived single atom catalysts for electrocatalytic energy conversion Sun, Tingting; Xu, Lianbin; Wang, Dingsheng Nano Research, Vol. 12, Issue 9 https://doi.org/10.1007/s12274-019-2345-4	journal	March 2019
Hard-Magnet L10-CoPt Nanoparticles Advance Fuel Cell Catalysis Li, Junrui; Sharma, Shubham; Liu, Xiaoming Joule, Vol. 3, Issue 1 https://doi.org/10.1016/j.joule.2018.09.016	journal	January 2019
Porous Nitrogen Rich Cadmium-Tetrazolate Based Metal Organic Framework (MOF) for H ₂ and CO ₂ Uptake Pachfule, Pradip; Banerjee, Rahul Crystal Growth & Design, Vol. 11, Issue 12 https://doi.org/10.1021/cg201054f	journal	December 2011
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Metal-Organic Framework-Based Nanomaterials for Electrocatalysis Mahmood, Asif; Guo, Wenhan; Tabassum, Hassina Advanced Energy Materials, Vol. 6, Issue 17 https://doi.org/10.1002/aenm.201600423	journal	May 2016
Three-dimensional cobalt(II) and cadmium(II) MOFs containing 1,4-naphthalenedicarboxylate: Catalytic activity of Cd-MOF Choi, In-Hwan; Kim, Youngmee; Lee, Do Nam Polyhedron, Vol. 105 https://doi.org/10.1016/j.poly.2015.12.022	journal	February 2016
Solvent-Induced Cadmium(II) Metal-Organic Frameworks with Adjustable Guest-Evacuated Porosity: Application in the Controllable Assembly of MOF-Derived Porous Carbon Materials for Supercapacitors Yue, Man-Li; Jiang, Yi-Fan; Zhang, Lin Chemistry - A European Journal, Vol. 23, Issue 62 https://doi.org/10.1002/chem.201702694	journal	September 2017
Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu Journal of the American Chemical Society, Vol. 139, Issue 40 https://doi.org/10.1021/jacs.7b06514	journal	September 2017
Networking Pyrolyzed Zeolitic Imidazolate Frameworks by Carbon Nanotubes Improves Conductivity and Enhances Oxygen-Reduction Performance in Polymer-Electrolyte-Membrane Fuel Cells Zhang, Chao; Wang, Yu-Cheng; An, Bing Advanced Materials, Vol. 29, Issue 4 https://doi.org/10.1002/adma.201604556	journal	November 2016
Single Cobalt Atoms with Precise N-Coordination as Superior Oxygen Reduction Reaction Catalysts Yin, Peiqun; Yao, Tao; Wu, Yuen Angewandte Chemie International Edition, Vol. 55, Issue 36 https://doi.org/10.1002/anie.201604802	journal	August 2016
Single-Atom Catalysts: Synthetic Strategies and Electrochemical Applications Chen, Yuanjun; Ji, Shufang; Chen, Chen Joule, Vol. 2, Issue 7 https://doi.org/10.1016/j.joule.2018.06.019	journal	July 2018
The Solid-Phase Synthesis of an Fe-N-C Electrocatalyst for High-Power Proton-Exchange Membrane Fuel Cells Liu, Qingtao; Liu, Xiaofang; Zheng, Lirong Angewandte Chemie International Edition, Vol. 57, Issue 5 https://doi.org/10.1002/anie.201709597	journal	January 2018
Fe–N–C electrocatalyst with dense active sites and efficient mass transport for high-performance proton exchange membrane fuel cells Wan, Xin; Liu, Xiaofang; Li, Yongcheng Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0237-3	journal	March 2019
High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites Zhang, Hanguang; Chung, Hoon T.; Cullen, David A. Energy & Environmental Science, Vol. 12, Issue 8 https://doi.org/10.1039/C9EE00877B	journal	January 2019
Fe–N–C Catalyst Graphitic Layer Structure and Fuel Cell Performance Workman, Michael J.; Serov, Alexey; Tsui, Lok-kun ACS Energy Letters, Vol. 2, Issue 7 https://doi.org/10.1021/acsenergylett.7b00391	journal	June 2017
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst Chung, Hoon T.; Cullen, David A.; Higgins, Drew Science, Vol. 357, Issue 6350 https://doi.org/10.1126/science.aan2255	journal	August 2017
Fe–N–C Catalysts: Progress in the Development of Fe‐Based PGM‐Free Electrocatalysts for the Oxygen Reduction Reaction (Adv. Mater. 31/2019) Martinez, Ulises; Komini Babu, Siddharth; Holby, Edward F. Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201970224	journal	December 2018
Evolution of nitrogen functionalities in carbonaceous materials during pyrolysis Pels, J. R.; Kapteijn, F.; Moulijn, J. A. Carbon, Vol. 33, Issue 11, p. 1641-1653 https://doi.org/10.1016/0008-6223(95)00154-6	journal	January 1995
Nitrogen-doped magnetic onion-like carbon as support for Pt particles in a hybrid cathode catalyst for fuel cells Wu, Gang; Dai, Changsong; Wang, Dianlong Journal of Materials Chemistry, Vol. 20, Issue 15, p. 3059-3068 https://doi.org/10.1039/b924010a	journal	January 2010
Ambient Electrosynthesis of Ammonia: Electrode Porosity and Composition Engineering Wang, Hong; Wang, Lu; Wang, Qiang Angewandte Chemie International Edition, Vol. 57, Issue 38 https://doi.org/10.1002/anie.201805514	journal	July 2018
Titanium dioxide-supported non-precious metal oxygen reduction electrocatalyst Wu, Gang; Nelson, Mark A.; Mack, Nathan H. Chemical Communications, Vol. 46, Issue 40, p. 7489-7491 https://doi.org/10.1039/c0cc03088k	journal	January 2010
Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts Guo, D.; Shibuya, R.; Akiba, C. Science, Vol. 351, Issue 6271 https://doi.org/10.1126/science.aad0832	journal	January 2016

Similar Records

Effects of Superparamagnetic Iron Nanoparticles on Electrocatalysts for the Reduction of Oxygen

Journal Article · Fri Jan 08 00:00:00 EST 2021 · Inorganic Chemistry · OSTI ID:1632829

Al-Zoubi, Talha; Gao, Wei; Schulz, Charles E.; +5 more

Boosting the activity of non-platinum group metal electrocatalyst for the reduction of oxygen via dual-ligated atomically dispersed precursors immobilized on carbon supports

Journal Article · Wed Sep 22 00:00:00 EDT 2021 · Nano Energy · OSTI ID:1632829

Zhou, Yu; Al-Zoubi, Talha; Ma, Yanling; +5 more

Phthalocyanine Precursors To Construct Atomically Dispersed Iron Electrocatalysts

Journal Article · Wed Jun 05 00:00:00 EDT 2019 · ACS Catalysis · OSTI ID:1632829

Wang, Yang; Wang, Maoyu; Zhang, Zisheng; +8 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Preparation of Nonprecious Metal Electrocatalysts for the Reduction of Oxygen Using a Low-Temperature Sacrificial Metal

Citation Formats

References (56)

Similar Records

Related Subjects