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Title: Design of High Efficient Mid-Wavelength Infrared Polarizer on ORMOCHALC Polymer

Journal Article · · Macromolecular Materials and Engineering
 [1];  [2];  [1];  [3];  [4];  [5];  [4];  [4];  [4];  [4];  [4];  [6];  [3];  [1]; ORCiD logo [1]
  1. North Carolina State Univ., Raleigh, NC (United States)
  2. Korea Research Inst. of Standards and Science, Daejeon (Korea)
  3. Air Force Research Lab. (AFRL), Wright-Patterson AFB, OH (United States)
  4. Naval Research Lab. (NRL), Washington, DC (United States)
  5. KBR, Beavercreek, OH (United States)
  6. Argonne National Lab. (ANL), Lemont, IL (United States). Center for Nanoscale Materials

While an organically modified chalcogenide (ORMOCHALC) can be used to fabricate a polymeric mid-wavelength infrared (MWIR) polarizer with competitive extinction ratio compared to the commercial wire-grid polarizers, which are composed of fragile inorganic materials, there is still a knowledge gap regarding the systematic design process to obtain high transmission efficiency and extinction ratio. As such, a computational parameter study for design optimization is conducted with the geometric parameters of the bilayer grating ORMOCHALC polarizer. The computational study shows that the Fabry–Pérot cavity is the primary mechanism that determines the transmission behaviors and the extinction ratio. A bilayer grating design, guided by the parameter study, is realized through the thermal nanoimprint and metal deposition processes. The extinction ratios measured with the Fourier-transform infrared are 245, 304, and 351 at the wavelength of 3, 4, and 5 μm, respectively. Compared to the state-of-the-art of the polymeric MWIR linear polarizers, the extinction ratio is improved by 1.4 times, and the transmission efficiency is increased by 2.5 times. Theoretical analysis with the multiple-layer model based on the transfer matrix method predicts a matched transmission behavior with the experiment and a full-wave electromagnetic simulation.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); US Air Force Office of Scientific Research (AFOSR); Defense University Research Instrumentation Program (DURIP)
Grant/Contract Number:
AC02-06CH11357; FA8750-15-3-6003; FA9550-15-0001; FA2386-18-1-4104; N000141010807; AC02‐06CH11357
OSTI ID:
1632271
Alternate ID(s):
OSTI ID: 1605945
Journal Information:
Macromolecular Materials and Engineering, Vol. 305, Issue 5; ISSN 1438-7492
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 11 works
Citation information provided by
Web of Science

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