Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Liquid‐Crystal‐Elastomer‐Based Dissipative Structures by Digital Light Processing 3D Printing

Journal Article · · Advanced Materials
Abstract

Digital Light Processing (DLP) 3D printing enables the creation of hierarchical complex structures with specific micro‐ and macroscopic architectures that are impossible to achieve through traditional manufacturing methods. Here, this hierarchy is extended to the mesoscopic length scale for optimized devices that dissipate mechanical energy. A photocurable, thus DLP‐printable main‐chain liquid crystal elastomer (LCE) resin is reported and used to print a variety of complex, high‐resolution energy‐dissipative devices. Using compressive mechanical testing, the stress–strain responses of 3D‐printed LCE lattice structures are shown to have 12 times greater rate‐dependence and up to 27 times greater strain–energy dissipation compared to those printed from a commercially available photocurable elastomer resin. The reported behaviors of these structures provide further insight into the much‐overlooked energy‐dissipation properties of LCEs and can inspire the development of high‐energy‐absorbing device applications.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NA0003525
OSTI ID:
1632242
Journal Information:
Advanced Materials, Journal Name: Advanced Materials Journal Issue: 28 Vol. 32; ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

References (46)

Three-Dimensional Printing of Elastomeric, Cellular Architectures with Negative Stiffness journal May 2014
Mechanically Robust, Ultraelastic Hierarchical Foam with Tunable Properties via 3D Printing journal April 2018
Dynamically Crystalizing Liquid‐Crystal Elastomers for an Expandable Endplate‐Conforming Interbody Fusion Cage journal October 2019
3D Soft Metamaterials with Negative Poisson's Ratio journal July 2013
Iris-Like Tunable Aperture Employing Liquid-Crystal Elastomers journal September 2014
Multistable Architected Materials for Trapping Elastic Strain Energy journal June 2015
Topology Optimized Architectures with Programmable Poisson's Ratio over Large Deformations journal August 2015
Highly Stretchable and UV Curable Elastomers for Digital Light Processing Based 3D Printing journal February 2017
Light Robots: Bridging the Gap between Microrobotics and Photomechanics in Soft Materials journal October 2017
Architected Lattices with High Stiffness and Toughness via Multicore-Shell 3D Printing journal January 2018
3D Printing of Liquid Crystal Elastomeric Actuators with Spatially Programed Nematic Order journal January 2018
Enhanced Dynamic Adhesion in Nematic Liquid Crystal Elastomers journal June 2019
Energy Absorption Properties of Periodic and Stochastic 3D Lattice Materials journal July 2019
4D Printed Actuators with Soft-Robotic Functions journal December 2017
Thiol-acrylate main-chain liquid-crystalline elastomers with tunable thermomechanical properties and actuation strain journal October 2016
Liquid crystal elastomer actuators: Synthesis, alignment, and applications journal January 2017
A preliminary study of cushion properties of a 3D printed thermoplastic polyurethane Kelvin foam journal June 2017
Photopolymers for rapid prototyping journal November 2007
Digital design and nonlinear simulation for additive manufacturing of soft lattice structures journal January 2019
Additive manufacturing (3D printing): A review of materials, methods, applications and challenges journal June 2018
3D printed architected polymeric sandwich panels: Energy absorption and structural performance journal September 2018
Biocompatible liquid-crystal elastomers mimic the intervertebral disc journal July 2020
3D printed hierarchical honeycombs with shape integrity under large compressive deformations journal January 2018
Viscoelasticity of the polydomain-monodomain transition in main-chain liquid crystal elastomers journal August 2016
Mechanical energy dissipation in polydomain nematic liquid crystal elastomers in response to oscillating loading journal March 2019
Plasticity in polymeric honeycombs made by photo-polymerization and nozzle based 3D-printing journal October 2017
110th Anniversary : Vat Photopolymerization-Based Additive Manufacturing: Current Trends and Future Directions in Materials Design journal July 2019
Four-dimensional Printing of Liquid Crystal Elastomers journal October 2017
Voxelated Molecular Patterning in Three-Dimensional Freeforms journal July 2019
Programmable Liquid Crystal Elastomers Prepared by Thiol–Ene Photopolymerization journal August 2015
Coincident molecular auxeticity and negative order parameter in a liquid crystal elastomer journal December 2018
Multimaterial 4D Printing with Tailorable Shape Memory Polymers journal August 2016
Tailorable and programmable liquid-crystalline elastomers using a two-stage thiol–acrylate reaction journal January 2015
High strain actuation liquid crystal elastomers via modulation of mesophase structure journal January 2017
Liquid-crystal order during synthesis affects main-chain liquid-crystal elastomer behavior journal January 2017
Liquid crystal elastomer foams with elastic properties specifically engineered as biodegradable brain tissue scaffolds journal January 2018
Thermomechanical properties of monodomain nematic main-chain liquid crystal elastomers journal January 2018
Design and optimization of a light-emitting diode projection micro-stereolithography three-dimensional manufacturing system journal December 2012
Liquid crystal elastomers: an introduction and review of emerging technologies journal January 2018
High-Efficiency High-Resolution Multimaterial Fabrication for Digital Light Processing-Based Three-Dimensional Printing journal September 2018
The Mechanics of Three-Dimensional Cellular Materials journal July 1982
Effect of crosslinker geometry on equilibrium thermal and mechanical properties of nematic elastomers journal November 2001
Voxelated liquid crystal elastomers journal February 2015
Untethered soft robotic matter with passive control of shape morphing and propulsion journal August 2019
Review of Auxetic Materials for Sports Applications: Expanding Options in Comfort and Protection journal June 2018
Liquid Crystal Elastomers—A Path to Biocompatible and Biodegradable 3D-LCE Scaffolds for Tissue Regeneration journal March 2018

Similar Records

3D Printing of Liquid Crystal Elastomer Foams for Enhanced Energy Dissipation Under Mechanical Insult
Journal Article · Sun Dec 27 19:00:00 EST 2020 · ACS Applied Materials and Interfaces · OSTI ID:1760444

Digital Light Process 3D Printing of Magnetically Aligned Liquid Crystalline Elastomer Free–forms
Journal Article · Mon Oct 28 20:00:00 EDT 2024 · Advanced Materials · OSTI ID:2527405

Soft elasticity optimises dissipation in 3D-printed liquid crystal elastomers
Journal Article · Wed Nov 17 19:00:00 EST 2021 · Nature Communications · OSTI ID:1834143

Related Subjects