Single-Crystal Growth and Room-Temperature Magnetocaloric Effect of X-Type Hexaferrite Sr2Co2Fe28O46

Wu, Meixia; Zhou, Xiang; Croft, Mark; Ehrlich, Steven; Khalid, Syed; Wen, Wen; Lapidus, Saul H.; Xu, Xianghan; Li, Man-Rong; Liu, Zhongwu; Cheong, Sang-Wook

doi:10.1021/acs.inorgchem.9b03724

Single-Crystal Growth and Room-Temperature Magnetocaloric Effect of X-Type Hexaferrite Sr₂Co₂Fe₂₈O₄₆

Journal Article · Mon May 04 04:00:00 EDT 2020 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.9b03724· OSTI ID:1631933

Wu, Meixia ^[1]; Zhou, Xiang ^[2]; Croft, Mark ^[3]; Ehrlich, Steven ^[4]; Khalid, Syed ^[4]; ^[5]; Lapidus, Saul H. ^[6]; Xu, Xianghan ^[3]; ^[7]; Liu, Zhongwu ^[8]; Cheong, Sang-Wook ^[3]

Sun Yat-Sen Univ., Guangzhou (China). School of Chemistry and Chemical Engineering; Rutgers Univ., Piscataway, NJ (United States); South China Univ. of Technology (SCUT), Guangzhou (China)
Guangxi Univ. of Science and Technology, Liuzhou (China)
Rutgers Univ., Piscataway, NJ (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Chinese Academy of Sciences (CAS), Shanghai (China)
Argonne National Lab. (ANL), Argonne, IL (United States)
Sun Yat-Sen Univ., Guangzhou (China). School of Chemistry and Chemical Engineering; Rutgers Univ., Piscataway, NJ (United States)
South China Univ. of Technology (SCUT), Guangzhou (China)

X-type hexaferrites have been receiving considerable attention due to their promising applications in many magnetic-electronic fields. However, the growth of single-crystal X-type hexaferrite is still a challenge. Herein we reported, for the first time, the preparation of single crystal X-type hexaferrite Sr₂Co₂Fe₂₈O₄₆ (Sr₂Co₂X) with high-quality and large size using floating-zone method with laser as the heating source. The crystals show rhombohedral symmetry with space group of R-3m (No. 166, a = 5.8935(1) Å and c = 83.7438(17) Å). Co²⁺ and Fe³⁺ oxidation states were confirmed by the X-ray absorption near-edge spectroscopy. The prepared Sr₂Co₂X exhibits a spin reorientation transition from easy-cone to easy-axis at T₂ of 343 K and a ferrimagnetism–paramagnetism transition at Curie temperature (TC) of ~743 K. The spin reorientation transition was accompanied by magnetocaloric effect (MCE). Both conventional and inverse MCEs were observed near T₂ with a magnetic field applied along the c-axis. The maximum value of the magnetic entropy change along the c-axis was evaluated to be 1.1 J/kg·K for a magnetic field change of 5 T.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704; AC02-06CH11357

OSTI ID:: 1631933

Alternate ID(s):: OSTI ID: 1660272

Report Number(s):: BNL--215979-2020-JAAM

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 10 Vol. 59; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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