Photo–thermo Catalytic Oxidation over a TiO 2 ‐WO 3 ‐Supported Platinum Catalyst

Kang, Leilei; Liu, Xiao Yan; Wang, Aiqin; Li, Lin; Ren, Yujing; Li, Xiaoyu; Pan, Xiaoli; Li, Yuanyuan; Zong, Xu; Liu, Hua; Frenkel, Anatoly I.; Zhang, Tao

doi:10.1002/anie.202001701

Photo–thermo Catalytic Oxidation over a TiO ₂ ‐WO ₃ ‐Supported Platinum Catalyst

Journal Article · Fri May 29 00:00:00 EDT 2020 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202001701· OSTI ID:1631190

Kang, Leilei ^[1]; ^[1]; Wang, Aiqin ^[1]; Li, Lin ^[1]; Ren, Yujing ^[2]; Li, Xiaoyu ^[2]; Pan, Xiaoli ^[1]; Li, Yuanyuan ^[3]; Zong, Xu ^[4]; Liu, Hua ^[2]; Frenkel, Anatoly I. ^[5]; Zhang, Tao ^[6]

CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China
CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China, University of Chinese Academy of Sciences Beijing 100049 China
Materials Science and Chemical Engineering Department Stony Brook University Stony Brook NY 11794 USA
State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China
Materials Science and Chemical Engineering Department Stony Brook University Stony Brook NY 11794 USA, Chemistry Division Brookhaven National Laboratory Upton NY 11973 USA
University of Chinese Academy of Sciences Beijing 100049 China, State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian 116023 China

Abstract

Photo–thermo catalysis, which integrates photocatalysis on semiconductors with thermocatalysis on supported nonplasmonic metals, has emerged as an attractive approach to improve catalytic performance. However, an understanding of the mechanisms in operation is missing from both the thermo‐ and photocatalytic perspectives. Deep insights into photo–thermo catalysis are achieved via the catalytic oxidation of propane (C ₃ H ₈ ) over a Pt/TiO ₂ ‐WO ₃ catalyst that severely suffers from oxygen poisoning at high O ₂ /C ₃ H ₈ ratios. After introducing UV/Vis light, the reaction temperature required to achieve 70 % conversion of C ₃ H ₈ lowers to a record‐breaking 90 °C from 324 °C and the apparent activation energy drops from 130 kJ mol ⁻¹ to 11 kJ mol ⁻¹ . Furthermore, the reaction order of O ₂ is −1.4 in dark but reverses to 0.1 under light, thereby suppressing oxygen poisoning of the Pt catalyst. An underlying mechanism is proposed based on direct evidence of the in‐situ‐captured reaction intermediates.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-03ER15476

OSTI ID:: 1631190

Alternate ID(s):: OSTI ID: 22943753

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 31 Vol. 59; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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