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Comparison of tetravalent cerium and terbium ions in a conserved, homoleptic imidophosphorane ligand field

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/D0SC01414A· OSTI ID:1630778
 [1];  [2];  [1];  [1];  [1];  [1];  [2];  [2];  [3]
  1. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA
  2. Theoretical Division, Los Alamos National Laboratory, Los Alamos, USA
  3. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA, Nuclear and Radiological Engineering and Medical Physics Program
+ Show Author Affiliations

A redox pair of Ce 4+ and Ce 3+ complexes, isotypic to previously prepared Tb 4+ and Tb 3+ complexes, respectively, is reported to establish a comparative physical and spectroscopic analysis of tetravalent lanthanide ions.

Research Organization:
Georgia Inst. of Technology, Atlanta, GA (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
National Institutes of Health (NIH); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
89233218CNA000001; AC02-76SF00515; SC0019385
OSTI ID:
1630778
Alternate ID(s):
OSTI ID: 1677651
OSTI ID: 1688764
Report Number(s):
LA-UR-20-22218
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 24 Vol. 11; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United Kingdom
Language:
English

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