Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A

Mouchel-Vallon, Camille; Lee-Taylor, Julia; Hodzic, Alma; Artaxo, Paulo; Aumont, Bernard; Camredon, Marie; Gurarie, David; Jimenez, Jose-Luis; Lenschow, Donald H.; Martin, Scot T.; Nascimento, Janaina; Orlando, John J.; Palm, Brett B.; Shilling, John E.; Shrivastava, Manish; Madronich, Sasha

doi:10.5194/acp-20-5995-2020

Title: Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A

Journal Article · Wed May 20 00:00:00 EDT 2020 · Atmospheric Chemistry and Physics (Online)

DOI:https://doi.org/10.5194/acp-20-5995-2020· OSTI ID:1630199

; Lee-Taylor, Julia; Hodzic, Alma;

; Aumont, Bernard; Camredon, Marie; Gurarie, David;

;

; Martin, Scot T.; Nascimento, Janaina; Orlando, John J.;

;

; Madronich, Sasha

The GoAmazon 2014/5 field campaign took place in Manaus, Brazil, and allowed the investigation of the interaction between background-level biogenic air masses and anthropogenic plumes. We present in this work a box model built to simulate the impact of urban chemistry on biogenic secondary organic aerosol (SOA) formation and composition. An organic chemistry mechanism is generated with the Generator for Explicit Chemistry and Kinetics of Organics in the Atmosphere (GECKO-A) to simulate the explicit oxidation of biogenic and anthropogenic compounds. A parameterization is also included to account for the reactive uptake of isoprene oxidation products on aqueous particles. The biogenic emissions estimated from existing emission inventories had to be reduced to match measurements. The model is able to reproduce ozone and NO_x for clean and polluted situations. The explicit model is able to reproduce background case SOA mass concentrations but does not capture the enhancement observed in the urban plume. The oxidation of biogenic compounds is the major contributor to SOA mass. A volatility basis set (VBS) parameterization applied to the same cases obtains better results than GECKO-A for predicting SOA mass in the box model. The explicit mechanism may be missing SOA-formation processes related to the oxidation of monoterpenes that could be implicitly accounted for in the VBS parameterization.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); National Science Foundation (NSF); USEPA; Brazilian National Council for Scientific and Technological Development (CNPq)

Grant/Contract Number:: AC05-76RL01830; SC0016331

OSTI ID:: 1630199

Alternate ID(s):: OSTI ID: 1639167

Report Number(s):: PNNL-SA-148940

Journal Information:: Atmospheric Chemistry and Physics (Online), Journal Name: Atmospheric Chemistry and Physics (Online) Vol. 20 Journal Issue: 10; ISSN 1680-7324

Publisher:: Copernicus Publications, EGUCopyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 10 works

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Title: Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A

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