Effect of Cobalt and Nickel Contents on the Performance of Lithium Rich Materials Synthesized in Glycerol Solvent

Hamad, Khaleel I.; Xing, Yangchuan

doi:10.1149/2.0311811jes

Title: Effect of Cobalt and Nickel Contents on the Performance of Lithium Rich Materials Synthesized in Glycerol Solvent

Journal Article · Sat Aug 11 00:00:00 EDT 2018 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0311811jes· OSTI ID:1630193

Hamad, Khaleel I.;

Lithium-rich cathode materials in the form of Li_1.2Mn_0.51N_i0.145+xCo_0.145-xO₂ (x = 0 (LR2), 0.0725 (LR1)) have been successfully synthesized by a sol-gel method using glycerol as solvent. These materials were characterized by X-ray diffractions (XRD), scanning electron microscopy (SEM), and electrochemical measurements. XRD patterns showed that both materials have typical diffraction peaks of Li-rich material with a well-crystallized structure, but the LR1 sample with less Co has a well-distinguished Li2MnO3 peak between 20°–25°. SEM images demonstrate that LR1 also has a more uniform particle distribution. Electrochemical measurements revealed that LR2 with more Co has a higher initial discharge capacity of 223 mAh/g than LR1 of 185 mAh/g at 0.1 C between 2 and 4.8 V. However, LR1 was observed to have an increasingly improved capacity over several dozens of cycles. The specific discharge capacity of LR1 increased from 185 to 213 mAh/g after 20 cycles. This is ascribed to a gradual activation of the Li-rich phase from the surface of the particles. It is shown that the smaller Co/Mn ratio (1:7.134) of LR1 plays an important role in its continuous activation. Its capacity retention is 98% at 100 cycles at 1C rate, better than that of LR2 and most previously reported lithium-rich materials.

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Research Organization:: Univ. of Missouri, Columbia, MO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007282

OSTI ID:: 1630193

Alternate ID(s):: OSTI ID: 1509881; OSTI ID: 1822891

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 165 Journal Issue: 11; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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Title: Effect of Cobalt and Nickel Contents on the Performance of Lithium Rich Materials Synthesized in Glycerol Solvent

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