Obstacles to applications of nanostructured thermoelectric alloys

Sharma, Peter A.; Sugar, Joshua D.

doi:10.3389/fchem.2014.00111

Obstacles to applications of nanostructured thermoelectric alloys

Journal Article · Wed Dec 17 23:00:00 EST 2014 · Frontiers in Chemistry

DOI:https://doi.org/10.3389/fchem.2014.00111· OSTI ID:1628997

Sharma, Peter A. ^[1]; Sugar, Joshua D. ^[2]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Quantum Phenomena; DOE/OSTI
Sandia National Lab. (SNL-CA), Livermore, CA (United States). Materials Physics

A major theme in thermoelectric research is based on controlling the formation of nanostructures that occur naturally in bulk intermetallic alloys through various types of thermodynamic phase transformation processes (He et al., 2013). The question of how such nanostructures form and why they lead to a high thermoelectric figure of merit (zT) are scientifically interesting and worthy of attention. However, as we discuss in this opinion, any processing route based on thermodynamic phase transformations alone will be difficult to implement in thermoelectric applications where thermal stability and reliability are important. Attention should also be focused on overcoming these limitations through advanced post-processing techniques.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: NA0003525

OSTI ID:: 1628997

Journal Information:: Frontiers in Chemistry, Journal Name: Frontiers in Chemistry Vol. 2; ISSN 2296-2646

Publisher:: Frontiers Research FoundationCopyright Statement

Country of Publication:: United States

Language:: English

References (19)

Solid-state precipitation of stable and metastable layered compounds in thermoelectric AgSbTe2 Sugar, J. D.; Medlin, D. L. Journal of Materials Science, Vol. 46, Issue 6 https://doi.org/10.1007/s10853-010-4984-4	journal	October 2010
Compositional Sensitivity of Microstructures and Thermoelectric Properties of Ag1−x Pb18Sb1+y Te20 Compounds Perlt, S.; Höche, Th.; Dadda, J. Journal of Electronic Materials, Vol. 42, Issue 7 https://doi.org/10.1007/s11664-012-2283-3	journal	October 2012
Discontinuous coarsening of spinodally decomposed Cu-Ni-Fe alloys Gronsky, R.; Thomas, G. Acta Metallurgica, Vol. 23, Issue 10 https://doi.org/10.1016/0001-6160(75)90034-6	journal	October 1975
A study by means of electron microscopy and electron diffraction of the phase transformation and the domain structure in Ag2Te Manolikas, C. Journal of Solid State Chemistry, Vol. 66, Issue 1 https://doi.org/10.1016/0022-4596(87)90214-3	journal	January 1987
Microstructural refinement of cast p-type Bi2Te3–Sb2Te3 by equal channel angular extrusion Im, Jae-Taek; Hartwig, K. Ted.; Sharp, Jeff Acta Materialia, Vol. 52, Issue 1 https://doi.org/10.1016/j.actamat.2003.08.025	journal	January 2004
Nanostructuration via solid state transformation as a strategy for improving the thermoelectric efficiency of PbTe alloys Gorsse, S.; Bellanger, P.; Brechet, Y. Acta Materialia, Vol. 59, Issue 19 https://doi.org/10.1016/j.actamat.2011.07.049	journal	November 2011
Morphological evolution of Ag2Te precipitates in thermoelectric PbTe Lensch-Falk, J. L.; Sugar, J. D.; Hekmaty, M. A. Journal of Alloys and Compounds, Vol. 504, Issue 1 https://doi.org/10.1016/j.jallcom.2010.05.054	journal	August 2010
High performance bulk thermoelectrics via a panoscopic approach He, Jiaqing; Kanatzidis, Mercouri G.; Dravid, Vinayak P. Materials Today, Vol. 16, Issue 5 https://doi.org/10.1016/j.mattod.2013.05.004	journal	May 2013
Self-Assembled Nanometer Lamellae of Thermoelectric PbTe and Sb ₂ Te ₃ with Epitaxy-like Interfaces Ikeda, Teruyuki; Collins, Lauren A.; Ravi, Vilupanur A. Chemistry of Materials, Vol. 19, Issue 4 https://doi.org/10.1021/cm062121p	journal	February 2007
Spinodal Decomposition and Nucleation and Growth as a Means to Bulk Nanostructured Thermoelectrics: Enhanced Performance in Pb _1- _x Sn _x Te−PbS Androulakis, John; Lin, Chia-Her; Kong, Hun-Jin Journal of the American Chemical Society, Vol. 129, Issue 31 https://doi.org/10.1021/ja071875h	journal	August 2007
Nature of the cubic to rhombohedral structural transformation in (AgSbTe2)15(GeTe)85 thermoelectric material Cook, B. A.; Kramer, M. J.; Wei, X. Journal of Applied Physics, Vol. 101, Issue 5 https://doi.org/10.1063/1.2645675	journal	March 2007
Influence of nanostructuring and heterogeneous nucleation on the thermoelectric figure of merit in AgSbTe2 Sharma, P. A.; Sugar, J. D.; Medlin, D. L. Journal of Applied Physics, Vol. 107, Issue 11 https://doi.org/10.1063/1.3446094	journal	June 2010
Thermoelectric properties of a composite medium Bergman, David J.; Levy, Ohad Journal of Applied Physics, Vol. 70, Issue 11 https://doi.org/10.1063/1.349830	journal	December 1991
Theory of enhancement of thermoelectric properties of materials with nanoinclusions Faleev, Sergey V.; Léonard, François Physical Review B, Vol. 77, Issue 21 https://doi.org/10.1103/physrevb.77.214304	journal	June 2008
Glass-like phonon scattering from a spontaneous nanostructure in AgSbTe2 Ma, J.; Delaire, O.; May, A. F. arXiv https://doi.org/10.48550/arxiv.1401.2595	text	January 2014
High-performance bulk thermoelectrics with all-scale hierarchical architectures Biswas, Kanishka; He, Jiaqing; Blum, Ivan D. Nature, Vol. 489, Issue 7416, p. 414-418 https://doi.org/10.1038/nature11439	journal	September 2012
Glass-like phonon scattering from a spontaneous nanostructure in AgSbTe2 Ma, J.; Delaire, O.; May, A. F. Nature Nanotechnology, Vol. 8, Issue 6 https://doi.org/10.1038/nnano.2013.95	journal	June 2013
Theory of enhancement of thermoelectric properties of materials with nanoinclusions Faleev, Sergey V.; Léonard, François Physical Review B, Vol. 77, Issue 21 https://doi.org/10.1103/PhysRevB.77.214304	journal	June 2008
Thermoelectric Properties of Fine-Grained PbTe Bulk Materials Fabricated by Cryomilling and Spark Plasma Sintering Kuo, Chia-Hung; Chien, Hsiu-Shan; Hwang, Chii-Shyang MATERIALS TRANSACTIONS, Vol. 52, Issue 4 https://doi.org/10.2320/matertrans.M2010331	journal	January 2011

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
decomposition
microstructure
nanostructuring
precipitation
thermoelectrics

Obstacles to applications of nanostructured thermoelectric alloys

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