Cyclic phosphonium ionic liquids

Lall-Ramnarine, Sharon I.; Mukhlall, Joshua A.; Wishart, James F.; Engel, Robert R.; Romeo, Alicia R.; Gohdo, Masao; Ramati, Sharon; Berman, Marc; Suarez, Sophia N.

doi:10.3762/bjoc.10.22

Cyclic phosphonium ionic liquids

Journal Article · Fri Jan 24 00:00:00 UTC 2014 · Beilstein Journal of Organic Chemistry

DOI:https://doi.org/10.3762/bjoc.10.22· OSTI ID:1628624

Lall-Ramnarine, Sharon I. ^[1]; Mukhlall, Joshua A. ^[2]; Wishart, James F. ^[3]; Engel, Robert R. ^[4]; Romeo, Alicia R. ^[5]; Gohdo, Masao ^[6]; Ramati, Sharon ^[2]; Berman, Marc ^[7]; Suarez, Sophia N. ^[8]

Queensborough Community College of the City Univ. of New York, Bayside, NY (United States). Chemistry Dept.; DOE/OSTI
Queensborough Community College of the City Univ. of New York, Bayside, NY (United States). Chemistry Dept.; Queens College of the City Univ. of New York (CUNY), NY (United States). Dept. of Chemistry and Biochemistry
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
Queens College of the City Univ. of New York (CUNY), NY (United States). Dept. of Chemistry and Biochemistry
Queensborough Community College of the City Univ. of New York, Bayside, NY (United States). Chemistry Dept.
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Osaka Univ. (Japan). Inst. of Scientific and Industrial Research (ISIR)
Hunter College of the City Univ. of New York (CUNY), NY (United States). Dept. of Physics and Astronomy
Brooklyn College of the City Univ. of New York (CUNY), NY (United States). Dept. of Physics

Ionic liquids (ILs) incorporating cyclic phosphonium cations are a novel category of materials. We report here on the synthesis and characterization of four new cyclic phosphonium bis(trifluoromethylsulfonyl)amide ILs with aliphatic and aromatic pendant groups. In addition to the syntheses of these novel materials, we report on a comparison of their properties with their ammonium congeners. These exemplars are slightly less conductive and have slightly smaller self-diffusion coefficients than their cyclic ammonium congeners.

View Accepted Manuscript (DOE)

Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-98CH10886

OSTI ID:: 1628624

Journal Information:: Beilstein Journal of Organic Chemistry, Journal Name: Beilstein Journal of Organic Chemistry Vol. 10; ISSN 1860-5397

Publisher:: Beilstein-InstitutCopyright Statement

Country of Publication:: United States

Language:: English

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Cited By (2)

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Electrochemical Stability of Functionalized Cyclic Phosphonium ( CylP ⁺ _n A ⁻ ) Ionic Liquid Based Battery Electrolytes Dathar, Gopi Krishna Phani; Pandian, Shanthi; Raju, Srinivasa G. Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.1131606jes	journal	January 2016

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