Triple Layer Tungsten Trioxide, Graphene, and Polyaniline Composite Films for Combined Energy Storage and Electrochromic Applications

Lyu, Hailong

doi:10.3390/polym12010049

Triple Layer Tungsten Trioxide, Graphene, and Polyaniline Composite Films for Combined Energy Storage and Electrochromic Applications

Journal Article · Mon Dec 30 00:00:00 EST 2019 · Polymers

DOI:https://doi.org/10.3390/polym12010049· OSTI ID:1628525

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; DOE/OSTI

Different polyaniline (PANI)-based hybrid films were successfully prepared by electro-polymerizing aniline monomers onto pre-spin-coated indium tin oxide (ITO) glass slides with WO₃, graphene, or WO₃/graphene films. Comparing with pristine PANI, the shifts of the characteristic peaks of PANI-based nanocomposites in UV-visible absorption spectra (UV-vis) and Fourier transform infrared spectroscopy (FT-IR) indicate the chemical interaction between the PANI matrix and the nanofillers, which is also confirmed by the scanning electron microscope (SEM) images. Corresponding coloration efficiencies were obtained for the WO₃/PANI (40.42 cm² C^-1), graphene/PANI (78.64 cm² C^-1), and WO₃/graphene/PANI (67.47 cm² C^-1) films, higher than that of the pristine PANI film (29.4 cm² C^-1), suggesting positive effects of the introduced nanofillers on the electrochromic performance. The areal capacitances of the films were observed to increase following the order as bare WO₃ < WO₃/graphene < pristine PANI < WO₃/PANI < graphene/PANI < WO₃/graphene/PANI films from both the cyclic voltammogram (CV) and galvanostatic charge-discharge (GCD) results. The enhanced energy storage and electrochromic performances of the PANI-based nanocomposite films can be attributed to the capacitance contributions of the introduced nanofillers, increased PANI amount, and the rougher morphology due to the embedment of the nanofillers into the PANI matrix. This extraordinary energy storage and electrochromic performances of the WO₃/graphene/PANI film make it a promising candidate for combined electrochromic and energy storage applications.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1628525

Journal Information:: Polymers, Journal Name: Polymers Journal Issue: 1 Vol. 12; ISSN 2073-4360

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

References (47)

Block-Copolymer-Assisted One-Pot Synthesis of Ordered Mesoporous WO _{3− x} /Carbon Nanocomposites as High-Rate-Performance Electrodes for Pseudocapacitors Jo, Changshin; Hwang, Jongkook; Song, Hannah Advanced Functional Materials, Vol. 23, Issue 30 https://doi.org/10.1002/adfm.201202682	journal	March 2013
Enhanced Electrochromism in Gyroid-Structured Vanadium Pentoxide Scherer, Maik R. J.; Li, Li; Cunha, Pedro M. S. Advanced Materials, Vol. 24, Issue 9 https://doi.org/10.1002/adma.201104272	journal	January 2012
Hybrid Materials and Polymer Electrolytes for Electrochromic Device Applications Thakur, Vijay Kumar; Ding, Guoqiang; Ma, Jan Advanced Materials, Vol. 24, Issue 30 https://doi.org/10.1002/adma.201200213	journal	May 2012
Electrochemical synthesis of polyaniline and its comparison with chemically synthesized polyaniline Bhadra, Sambhu; Singha, Nikhil K.; Khastgir, Dipak Journal of Applied Polymer Science, Vol. 104, Issue 3 https://doi.org/10.1002/app.25867	journal	January 2007
Simultaneously Boosting the Ionic Conductivity and Mechanical Strength of Polymer Gel Electrolyte Membranes by Confining Ionic Liquids into Hollow Silica Nanocavities Thapaliya, Bishnu P.; Do‐Thanh, Chi‐Linh; Jafta, Charl J. Batteries & Supercaps, Vol. 2, Issue 12 https://doi.org/10.1002/batt.201900095	journal	September 2019
Aromatic Polyimide/Graphene Composite Organic Cathodes for Fast and Sustainable Lithium-Ion Batteries Lyu, Hailong; Li, Peipei; Liu, Jiurong ChemSusChem, Vol. 11, Issue 4 https://doi.org/10.1002/cssc.201702001	journal	January 2018
Fluorination of MXene by Elemental F ₂ as Electrode Material for Lithium‐Ion Batteries Thapaliya, Bishnu P.; Jafta, Charl J.; Lyu, Hailong ChemSusChem, Vol. 12, Issue 7 https://doi.org/10.1002/cssc.201900003	journal	March 2019
Optical properties of polyaniline Huang, W. S.; MacDiarmid, A. G. Polymer, Vol. 34, Issue 9 https://doi.org/10.1016/0032-3861(93)90424-9	journal	May 1993
Electrospun titania nanofibers segregated by graphene oxide for improved visible light photocatalysis Zhang, Li; Zhang, Qinghong; Xie, Hongyong Applied Catalysis B: Environmental, Vol. 201 https://doi.org/10.1016/j.apcatb.2016.08.056	journal	February 2017
Ion transport across the film of poly(5,6-dimethoxyindole-2-carboxylic acid) in relation to its electrochromic switching: An electrochemical quartz crystal microbalance study Tseng, Chen-Ya; Hu, Chih-Wei; Huang, Kuan-Chieh Electrochimica Acta, Vol. 101 https://doi.org/10.1016/j.electacta.2012.12.039	journal	July 2013
Toward interconnected hierarchical porous structure via chemical depositing organic nano-polyaniline on inorganic carbon scaffold for supercapacitor Shen, Kui-wen; Ran, Fen; Tan, Yong-tao Synthetic Metals, Vol. 199 https://doi.org/10.1016/j.synthmet.2014.11.034	journal	January 2015
Spray-On Polyaniline/Poly(acrylic acid) Electrodes with Enhanced Electrochemical Stability Jeon, Ju-Won; Kwon, Se Ra; Li, Fei ACS Applied Materials & Interfaces, Vol. 7, Issue 43 https://doi.org/10.1021/acsami.5b07459	journal	October 2015
Origin of Electrochromism in High-Performing Nanocomposite Nickel Oxide Lin, Feng; Nordlund, Dennis; Weng, Tsu-Chien ACS Applied Materials & Interfaces, Vol. 5, Issue 9 https://doi.org/10.1021/am400105y	journal	March 2013
Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E. Chemistry of Materials, Vol. 25, Issue 24 https://doi.org/10.1021/cm403726v	journal	December 2013
Color Control in π-Conjugated Organic Polymers for Use in Electrochromic Devices Beaujuge, Pierre M.; Reynolds, John R. Chemical Reviews, Vol. 110, Issue 1, p. 268-320 https://doi.org/10.1021/cr900129a	journal	January 2010
A Trilayer Film Approach to Multicolor Electrochromism Matsui, Jun; Kikuchi, Rie; Miyashita, Tokuji Journal of the American Chemical Society, Vol. 136, Issue 3 https://doi.org/10.1021/ja4107786	journal	January 2014
A review of electrode materials for electrochemical supercapacitors Wang, Guoping; Zhang, Lei; Zhang, Jiujun Chemical Society Reviews, Vol. 41, Issue 2, p. 797-828 https://doi.org/10.1039/c1cs15060j	journal	January 2012
Multicolor electrochromic polyaniline–WO3 hybrid thin films: One-pot molecular assembling synthesis Zhang, Jun; Tu, Jiang-ping; Zhang, Dong Journal of Materials Chemistry, Vol. 21, Issue 43 https://doi.org/10.1039/c1jm13069b	journal	January 2011
Integrated energy storage and electrochromic function in one flexible device: an energy storage smart window Wang, Kai; Wu, Haiping; Meng, Yuena Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee21643d	journal	January 2012
Electrochemical supercapacitors from conducting polyaniline–graphene platforms Ashok Kumar, Nanjundan; Baek, Jong-Beom Chemical Communications, Vol. 50, Issue 48 https://doi.org/10.1039/c4cc01049c	journal	January 2014
Improved electromagnetic wave absorption of Co nanoparticles decorated carbon nanotubes derived from synergistic magnetic and dielectric losses Wu, Nannan; Lv, Hailong; Liu, Jiurong Physical Chemistry Chemical Physics, Vol. 18, Issue 46 https://doi.org/10.1039/c6cp06066h	journal	January 2016
Electrochromic Window Based on Conducting Poly(3,4-ethylenedioxythiophene)-Poly(styrene sulfonate) Heuer, H. W.; Wehrmann, R.; Kirchmeyer, S. Advanced Functional Materials, Vol. 12, Issue 2 https://doi.org/10.1002/1616-3028(20020201)12:2<89::AID-ADFM89>3.0.CO;2-1	journal	February 2002
Fabrication of a Highly Transparent Conductive Thin Film from Polypyrrole/Poly(methyl methacrylate) Core/Shell Nanospheres Jang, J.; Oh, J. H. Advanced Functional Materials, Vol. 15, Issue 3 https://doi.org/10.1002/adfm.200400095	journal	March 2005
Fluorination of MXene by Elemental F ₂ as Electrode Material for Lithium‐Ion Batteries Thapaliya, Bishnu P.; Jafta, Charl J.; Lyu, Hailong ChemSusChem https://doi.org/10.1002/cssc.201900792	journal	March 2019
Fluorination of MXene by Elemental F ₂ as Electrode Material for Lithium‐Ion Batteries Thapaliya, Bishnu P.; Jafta, Charl J.; Lyu, Hailong ChemSusChem, Vol. 12, Issue 7 https://doi.org/10.1002/cssc.201900793	journal	April 2019
Chromium(III) oxide carbon nanocomposites lithium-ion battery anodes with enhanced energy conversion performance Fu, Ya; Gu, Hongbo; Yan, Xingru Chemical Engineering Journal, Vol. 277 https://doi.org/10.1016/j.cej.2015.04.142	journal	October 2015
Li-Ion Storage Performance of MnO Nanoparticles Coated with Nitrogen-Doped Carbon Derived from Different Carbon Sources Lu, Guixia; Qiu, Song; Lv, Hailong Electrochimica Acta, Vol. 146 https://doi.org/10.1016/j.electacta.2014.08.142	journal	November 2014
Nanostructured Antimony/carbon Composite Fibers as Anode Material for Lithium-ion Battery Lv, Hailong; Qiu, Song; Lu, Guixia Electrochimica Acta, Vol. 151 https://doi.org/10.1016/j.electacta.2014.11.013	journal	January 2015
Preparation of graphene nanosheet/carbon nanotube/polyaniline composite as electrode material for supercapacitors Yan, Jun; Wei, Tong; Fan, Zhuangjun Journal of Power Sources, Vol. 195, Issue 9 https://doi.org/10.1016/j.jpowsour.2009.11.028	journal	May 2010
Bis(trimethylsilyl) 2-fluoromalonate derivatives as electrolyte additives for high voltage lithium ion batteries Lyu, Hailong; Li, Yunchao; Jafta, Charl J. Journal of Power Sources, Vol. 412 https://doi.org/10.1016/j.jpowsour.2018.11.083	journal	February 2019
Progress in preparation, processing and applications of polyaniline Bhadra, Sambhu; Khastgir, Dipak; Singha, Nikhil K. Progress in Polymer Science, Vol. 34, Issue 8 https://doi.org/10.1016/j.progpolymsci.2009.04.003	journal	August 2009
Sustainable Rejuvenation of Electrochromic WO ₃ Films Wen, Rui-Tao; Niklasson, Gunnar A.; Granqvist, Claes G. ACS Applied Materials & Interfaces, Vol. 7, Issue 51 https://doi.org/10.1021/acsami.5b09035	journal	December 2015
Facile Synthesis of Porous Nickel/Carbon Composite Microspheres with Enhanced Electromagnetic Wave Absorption by Magnetic and Dielectric Losses Qiu, Song; Lyu, Hailong; Liu, Jiurong ACS Applied Materials & Interfaces, Vol. 8, Issue 31 https://doi.org/10.1021/acsami.6b03159	journal	July 2016
Dual-Polymer Electrochromic Film Characterization Using Bipotentiostatic Control Unur, Ece; Jung, June-Ho; Mortimer, Roger J. Chemistry of Materials, Vol. 20, Issue 6 https://doi.org/10.1021/cm703354q	journal	March 2008
Highly Conducting and Solution-Processable Polyaniline Obtained via Protonation with a New Sulfonic Acid Containing Plasticizing Functional Groups Olinga, Thomas E.; Fraysse, Jérôme; Travers, Jean Pierre Macromolecules, Vol. 33, Issue 6 https://doi.org/10.1021/ma991525i	journal	March 2000
Development of high-performance supercapacitor electrodes using novel ordered mesoporous tungsten oxide materials with high electrical conductivity Yoon, Songhun; Kang, Eunae; Kim, Jin Kon Chem. Commun., Vol. 47, Issue 3 https://doi.org/10.1039/C0CC03594G	journal	January 2011
A review of electrode materials for electrochemical supercapacitors Wang, Guoping; Zhang, Lei; Zhang, Jiujun Chemical Society Reviews, Vol. 41, Issue 2, p. 797-828 https://doi.org/10.1039/C1CS15060J	journal	January 2012
Graphene-based polyaniline nanocomposites: preparation, properties and applications Wang, Li; Lu, Xingping; Lei, Shengbin J. Mater. Chem. A, Vol. 2, Issue 13 https://doi.org/10.1039/C3TA13462H	journal	January 2014
Multi-walled carbon nanotubes composited with nanomagnetite for anodes in lithium ion batteries Li, Xiaoyu; Gu, Hongbo; Liu, Jiurong RSC Advances, Vol. 5, Issue 10 https://doi.org/10.1039/C4RA15228J	journal	January 2015
Enhanced electrochemical performance of barium hexaferrite nanoplates by Zn ²⁺ doping serving as anode materials Hu, Chenxi; Qiu, Song; Lu, Guixia RSC Advances, Vol. 5, Issue 87 https://doi.org/10.1039/C5RA12127B	journal	January 2015
Enhanced electrochemical performances of MoO ₂ nanoparticles composited with carbon nanotubes for lithium-ion battery anodes Qiu, Song; Lu, Guixia; Liu, Jiurong RSC Advances, Vol. 5, Issue 106 https://doi.org/10.1039/C5RA17147D	journal	January 2015
Improved electromagnetic wave absorption of Co nanoparticles decorated carbon nanotubes derived from synergistic magnetic and dielectric losses Wu, Nannan; Lv, Hailong; Liu, Jiurong Physical Chemistry Chemical Physics, Vol. 18, Issue 46 https://doi.org/10.1039/C6CP06066H	journal	January 2016
Carbon composite spun fibers with in situ formed multicomponent nanoparticles for a lithium-ion battery anode with enhanced performance Lyu, Hailong; Liu, Jiurong; Qiu, Song Journal of Materials Chemistry A, Vol. 4, Issue 25 https://doi.org/10.1039/C6TA02083F	journal	January 2016
Synthesis of strontium hexaferrite nanoplates and the enhancement of their electrochemical performance by Zn ²⁺ doping for high-rate and long-life lithium-ion batteries Hu, Chenxi; Cao, Huili; Wang, Shenyu New Journal of Chemistry, Vol. 41, Issue 14 https://doi.org/10.1039/C7NJ01036B	journal	January 2017
Polythiophene coated aromatic polyimide enabled ultrafast and sustainable lithium ion batteries Lyu, Hailong; Liu, Jiurong; Mahurin, Shannon Journal of Materials Chemistry A, Vol. 5, Issue 46 https://doi.org/10.1039/C7TA07893E	journal	January 2017
All-solid-state interpenetrating network polymer electrolytes for long cycle life of lithium metal batteries Tong, Yongfen; Lyu, Hailong; Xu, Yuzhong Journal of Materials Chemistry A, Vol. 6, Issue 30 https://doi.org/10.1039/C8TA03062F	journal	January 2018
A dicyanobenzoquinone based cathode material for rechargeable lithium and sodium ion batteries Lyu, Hailong; Jafta, Charl J.; Popovs, Ilja Journal of Materials Chemistry A, Vol. 7, Issue 30 https://doi.org/10.1039/C9TA04869C	journal	January 2019

Cited By (1)

Evaluation of the Covalent Functionalization of Carbon Nano-Onions with Pyrene Moieties for Supercapacitor Applications Velásquez, José D.; Tomczykowa, Monika; Plonska-Brzezinska, Marta E. Materials, Vol. 13, Issue 5 https://doi.org/10.3390/ma13051141	journal	March 2020

Similar Records

Pseudocapacitive Charge Storage in Electrochromic Transition-Metal Oxide Thin Films

Journal Article · Mon Aug 15 20:00:00 EDT 2022 · Journal of the Electrochemical Society · OSTI ID:1980894

Electrochromism of electrodeposited tungsten trioxide films; 1: Electrochemical characterization

Journal Article · Fri Jul 01 00:00:00 EDT 1994 · Journal of the Electrochemical Society; (United States) · OSTI ID:7021576

Transmission spectra of an electrochromic window based on polyaniline, Prussian blue and tungsten oxide

Journal Article · Tue Nov 30 23:00:00 EST 1993 · Journal of the Electrochemical Society · OSTI ID:142188

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
WO3
electrochemical energy storage
electrochromic
graphene
polyaniline
polymer science

Triple Layer Tungsten Trioxide, Graphene, and Polyaniline Composite Films for Combined Energy Storage and Electrochromic Applications

Citation Formats

References (47)

Cited By (1)

Similar Records

Related Subjects