A 29Si, 1H, and 13C Solid-State NMR Study on the Surface Species of Various Depolymerized Organosiloxanes at Silica Surface

Protsak, Iryna S.; Morozov, Yevhenii M.; Dong, Wen; Le, Zichun; Zhang, Dong; Henderson, Ian M.

doi:10.1186/s11671-019-2982-2

A 29Si, 1H, and 13C Solid-State NMR Study on the Surface Species of Various Depolymerized Organosiloxanes at Silica Surface

Journal Article · Tue May 14 00:00:00 EDT 2019 · Nanoscale Research Letters

DOI:https://doi.org/10.1186/s11671-019-2982-2· OSTI ID:1618187

Protsak, Iryna S.; Morozov, Yevhenii M.; Dong, Wen; ; Zhang, Dong; Henderson, Ian M.

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Research Organization:: Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396; NA0003525

OSTI ID:: 1618187

Alternate ID(s):: OSTI ID: 1626749

Journal Information:: Nanoscale Research Letters, Journal Name: Nanoscale Research Letters Journal Issue: 1 Vol. 14; ISSN 1931-7573

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (44)

Reversible amine solubilization of cured siloxane polymers Hsiao, Y. -C.; Hill, L. W.; Pappas, S. P. Journal of Applied Polymer Science, Vol. 19, Issue 10 https://doi.org/10.1002/app.1975.070191017	journal	October 1975
Thermal analysis of polydimethylsiloxanes. I. Thermal degradation in controlled atmospheres Thomas, T. Howard; Kendrick, T. C. Journal of Polymer Science Part A-2: Polymer Physics, Vol. 7, Issue 3 https://doi.org/10.1002/pol.1969.160070308	journal	March 1969
Surface reaction of particulate silica with polydimethylsiloxanes Yu-Fu, Li; Yong-Xia, Xia; Dong-Peng, Xu Journal of Polymer Science: Polymer Chemistry Edition, Vol. 19, Issue 12 https://doi.org/10.1002/pol.1981.170191204	journal	December 1981
A molecular dynamics simulation and quantum chemistry study of poly(dimethylsiloxane)–silica nanoparticle interactions Smith, James S.; Borodin, Oleg; Smith, Grant D. Journal of Polymer Science Part B: Polymer Physics, Vol. 45, Issue 13 https://doi.org/10.1002/polb.21119	journal	January 2007
Structure investigation of organosilicon polymers by silicon-29 NMR Engelhardt, G.; Jancke, H. Polymer Bulletin, Vol. 5, Issue 11-12 https://doi.org/10.1007/BF00255295	journal	January 1981
Kinetics and mechanism of the reaction of organosiloxanes with the surface of pyrogenic silica Guba, G. Ya.; Bogillo, V. I.; Chuiko, A. A. Theoretical and Experimental Chemistry, Vol. 28, Issue 2 https://doi.org/10.1007/BF00573927	journal	January 1993
Nucleophilic Cleavage of Crosslinked Polysiloxanes to Cyclic Siloxane Monomers: Mild Catalysis by a Designed Polar Solvent System Chang, Cheng-Liang; Lee, Howard Shih-Jen; Chen, Cheng-Kwo Journal of Polymer Research, Vol. 12, Issue 6 https://doi.org/10.1007/s10965-004-1871-1	journal	December 2005
Characterization of modified silica powders by fourier transform infrared spectroscopy and cross-polarization magic angle spinning NMR De Haan, J. W.; van den Bogaert, H. M.; Ponjeé, J. J. Journal of Colloid and Interface Science, Vol. 110, Issue 2 https://doi.org/10.1016/0021-9797(86)90411-X	journal	April 1986
Studies of cyclic and linear poly(dimethyl-siloxanes): 21. High temperature thermal behaviour Clarson, S. J.; Semlyen, J. A. Polymer, Vol. 27, Issue 1 https://doi.org/10.1016/0032-3861(86)90360-5	journal	January 1986
Application of 1H NMR spectroscopy method for determination of characteristics of thin layers of water adsorbed on the surface of dispersed and porous adsorbents Turov, V. V.; Leboda, R. Advances in Colloid and Interface Science, Vol. 79, Issue 2-3 https://doi.org/10.1016/S0001-8686(97)00036-5	journal	February 1999
Thermogravimetric and 1H NMR spectroscopy studies of water on silicalites Turov, V. V.; Chodorowski, S.; Leboda, R. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 158, Issue 3 https://doi.org/10.1016/S0927-7757(99)00180-6	journal	November 1999
Synthesis and characterization of hydrophobic silica nanocomposites Daoud, Walid A.; Xin, John H.; Tao, Xiaoming Applied Surface Science, Vol. 252, Issue 15 https://doi.org/10.1016/j.apsusc.2005.12.020	journal	May 2006
Polydimethylsiloxane at the interfaces of fumed silica and zirconia/fumed silica Gun’ko, V. M.; Borysenko, M. V.; Pissis, P. Applied Surface Science, Vol. 253, Issue 17 https://doi.org/10.1016/j.apsusc.2007.02.185	journal	June 2007
Structural and hydrophobic–hydrophilic properties of nanosilica/zirconia alone and with adsorbed PDMS Sulym, I. Y.; Borysenko, M. V.; Goncharuk, O. V. Applied Surface Science, Vol. 258, Issue 1 https://doi.org/10.1016/j.apsusc.2011.08.045	journal	October 2011
Influence of hydrophobization of fumed oxides on interactions with polar and nonpolar adsorbates Gun’ko, V. M.; Pakhlov, E. M.; Goncharuk, O. V. Applied Surface Science, Vol. 423 https://doi.org/10.1016/j.apsusc.2017.06.207	journal	November 2017
Cleavage of Organosiloxanes with Dimethyl Carbonate: A Mild Approach To Graft-to-Surface Modification Protsak, Iryna; Henderson, Ian M.; Tertykh, Valentyn Langmuir, Vol. 34, Issue 33 https://doi.org/10.1021/acs.langmuir.8b01580	journal	July 2018
Effect of Curvature on the Packing and Ordering of Organosilane Monolayers Supported on Solids Bernardoni, Frank; Kouba, Megan; Fadeev, Alexander Y. Chemistry of Materials, Vol. 20, Issue 2 https://doi.org/10.1021/cm070842y	journal	January 2008
An Intrinsic Relationship between Molecular Structure in Self-Assembled n-Alkylsiloxane Monolayers and Deposition Temperature Parikh, Atul N.; Allara, David L.; Azouz, Issam Ben The Journal of Physical Chemistry, Vol. 98, Issue 31 https://doi.org/10.1021/j100082a031	journal	August 1994
Reactions of Ethoxysilanes with Silica: A Solid-State NMR Study Bluemel, Janet Journal of the American Chemical Society, Vol. 117, Issue 7 https://doi.org/10.1021/ja00112a033	journal	February 1995
Formation of monolayer films by the spontaneous assembly of organic thiols from solution onto gold Bain, Colin D.; Troughton, E. Barry; Tao, Yu Tai Journal of the American Chemical Society, Vol. 111, Issue 1, p. 321-335 https://doi.org/10.1021/ja00183a049	journal	January 1989
The structure of self-assembled monolayers of alkylsiloxanes on silicon: a comparison of results from ellipsometry and low-angle x-ray reflectivity Wasserman, Stephen R.; Whitesides, George M.; Tidswell, Ian M. Journal of the American Chemical Society, Vol. 111, Issue 15 https://doi.org/10.1021/ja00197a054	journal	July 1989
Proton NMR study of dehydration of the silica gel surface Bronnimann, Charles E.; Zeigler, Robert C.; Maciel, Gary E. Journal of the American Chemical Society, Vol. 110, Issue 7 https://doi.org/10.1021/ja00215a001	journal	March 1988
Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning Maciel, Gary E.; Sindorf, Dean W. Journal of the American Chemical Society, Vol. 102, Issue 25 https://doi.org/10.1021/ja00545a056	journal	December 1980
Solid-State NMR Study of MCM-41-type Mesoporous Silica Nanoparticles Trébosc, Julien; Wiench, Jerzy W.; Huh, Seong Journal of the American Chemical Society, Vol. 127, Issue 9 https://doi.org/10.1021/ja043567e	journal	March 2005
Reaction of Organosilicon Hydrides with Solid Surfaces: An Example of Surface-Catalyzed Self-Assembly Helmy, Roy; Wenslow, Robert W.; Fadeev, Alexander Y. Journal of the American Chemical Society, Vol. 126, Issue 24 https://doi.org/10.1021/ja0498336	journal	June 2004
The Fumed Silica Surface: A Study by NMR Liu, Changhua C.; Maciel, Gary E. Journal of the American Chemical Society, Vol. 118, Issue 21 https://doi.org/10.1021/ja954120w	journal	January 1996
Silanization of Solid Substrates: A Step Toward Reproducibility Brzoska, J. B.; Azouz, I. Ben; Rondelez, F. Langmuir, Vol. 10, Issue 11 https://doi.org/10.1021/la00023a072	journal	November 1994
Self-Assembly Is Not the Only Reaction Possible between Alkyltrichlorosilanes and Surfaces: Monomolecular and Oligomeric Covalently Attached Layers of Dichloro- and Trichloroalkylsilanes on Silicon Fadeev, Alexander Y.; McCarthy, Thomas J. Langmuir, Vol. 16, Issue 18 https://doi.org/10.1021/la000471z	journal	September 2000
Formation and characterization of a highly ordered and well-anchored alkylsilane monolayer on mica by self-assembly Kessel, Carl R.; Granick, Steve. Langmuir, Vol. 7, Issue 3 https://doi.org/10.1021/la00051a020	journal	March 1991
Adsorption Characterization of Oligo(dimethylsiloxane)-Modified Silicas: An Example of Highly Hydrophobic Surfaces with Non-Aliphatic Architecture Kazakevich, Yuri V.; Fadeev, Alexander Y. Langmuir, Vol. 18, Issue 8 https://doi.org/10.1021/la011490r	journal	April 2002
Covalently Attached Monolayers of Oligo(dimethylsiloxane)s on Silica: A Siloxane Chemistry Approach for Surface Modification Fadeev, Alexander Y.; Kazakevich, Yuri V. Langmuir, Vol. 18, Issue 7 https://doi.org/10.1021/la011491j	journal	April 2002
Displacement Reactions of Covalently Attached Organosilicon Monolayers on Si Krumpfer, Joseph W.; Fadeev, Alexander Y. Langmuir, Vol. 22, Issue 20 https://doi.org/10.1021/la060969m	journal	September 2006
Covalent Functionalization of Silica Surface Using “Inert” Poly(dimethylsiloxanes) Graffius, Gabriel; Bernardoni, Frank; Fadeev, Alexander Y. Langmuir, Vol. 30, Issue 49 https://doi.org/10.1021/la5031763	journal	December 2014
Self-Assembled Monolayers of Alkylphosphonic Acids on Metal Oxides Gao, Wei; Dickinson, Lucy; Grozinger, Christina Langmuir, Vol. 12, Issue 26 https://doi.org/10.1021/la9607621	journal	January 1996
Transition Temperatures for n -Alkyltrichlorosilane Monolayers Rye, R. R. Langmuir, Vol. 13, Issue 9 https://doi.org/10.1021/la960934u	journal	April 1997
Thoughts on the Structure of Alkylsilane Monolayers Stevens, Mark J. Langmuir, Vol. 15, Issue 8 https://doi.org/10.1021/la981064e	journal	April 1999
Structure of a PDMS Layer Grafted onto a Silica Surface Studied by Means of DSC and Solid-State NMR Litvinov, V. M.; Barthel, H.; Weis, J. Macromolecules, Vol. 35, Issue 11 https://doi.org/10.1021/ma0119124	journal	May 2002
Synthesis of Highly Branched Alkoxysiloxane−Dimethylsiloxane Copolymers by Nonhydrolytic Dehydrocarbon Polycondensation Catalyzed by Tris(pentafluorophenyl)borane Chojnowski, Julian; Rubinsztajn, Slawomir; Fortuniak, Witold Macromolecules, Vol. 41, Issue 20 https://doi.org/10.1021/ma801130y	journal	October 2008
INS and IR study of intermolecular interactions at the fumed silica-polydimethylsiloxane interphase, Part 3. Sicica-siloxane adsorption complexes Barthel, H.; Nikitina, E. Silicon Chemistry, Vol. 1, Issue 4 https://doi.org/10.1023/B:SILC.0000018353.32350.c9	journal	July 2002
Multinuclear solid-state NMR study: a powerful tool for understanding the structure of ZnO hybrid nanoparticles Spataro, Grégory; Champouret, Yohan; Florian, Pierre Physical Chemistry Chemical Physics, Vol. 20, Issue 18 https://doi.org/10.1039/C8CP01096J	journal	January 2018
Spatial distribution of organic functional groups supported on mesoporous silica nanoparticles (2): a study by ¹ H triple-quantum fast-MAS solid-state NMR Kobayashi, Takeshi; Singappuli-Arachchige, Dilini; Slowing, Igor I. Physical Chemistry Chemical Physics, Vol. 20, Issue 34 https://doi.org/10.1039/C8CP04425B	journal	January 2018
Decarboxylation of dialkyl carbonates to dialkyl ethers over alkali metal-exchanged faujasites Selva, Maurizio; Fabris, Massimo; Perosa, Alvise Green Chemistry, Vol. 13, Issue 4 https://doi.org/10.1039/c0gc00536c	journal	January 2011
29Si solid-state NMR study of the surface structure of aerosil silica Brei, Vladimir V. Journal of the Chemical Society, Faraday Transactions, Vol. 90, Issue 19 https://doi.org/10.1039/ft9949002961	journal	January 1994
Surface etching of silicone elastomers by depolymerization Brook, Michael A.; Zhao, Shigui; Liu, Lihua Canadian Journal of Chemistry, Vol. 90, Issue 1 https://doi.org/10.1139/v11-145	journal	January 2012

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A 29Si, 1H, and 13C Solid-State NMR Study on the Surface Species of Various Depolymerized Organosiloxanes at Silica Surface

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