Designer interphases for the lithium-oxygen electrochemical cell

Choudhury, Snehashis; Wan, Charles Tai-Chieh; Al Sadat, Wajdi I.; Tu, Zhengyuan; Lau, Sampson; Zachman, Michael J.; Kourkoutis, Lena F.; Archer, Lynden A.

doi:10.1126/sciadv.1602809

Title: Designer interphases for the lithium-oxygen electrochemical cell

Journal Article · Sat Apr 01 00:00:00 EDT 2017 · Science Advances

DOI:https://doi.org/10.1126/sciadv.1602809· OSTI ID:1625969

^[1];

^[1]; Tu, Zhengyuan ^[2];

^[1];

^[3];

^[3]; Archer, Lynden A. ^[1]

Cornell Univ., Ithaca, NY (United States). School of Chemical and Biomolecular Engineering
Cornell Univ., Ithaca, NY (United States). Dept. of Materials Science and Engineering
Cornell Univ., Ithaca, NY (United States). School of Applied and Engineering Physics; Cornell Univ., Ithaca, NY (United States). Kavli Inst. at Cornell for Nanoscale Science

An electrochemical cell based on the reversible oxygen reduction reaction: 2Li+ + 2e- + O2 ↔ Li2O2, provides among the most energy dense platforms for portable electrical energy storage. Such Lithium-Oxygen (Li-O2) cells offer specific energies competitive with fossil fuels and are considered promising for electrified transportation. Multiple, fundamental challenges with the cathode, anode, and electrolyte have limited practical interest in Li-O2 cells because these problems lead to as many practical shortcomings, including poor rechargeability, high overpotentials, and specific energies well below theoretical expectations. We create and study in-situ formation of solid-electrolyte interphases (SEIs) based on bromide ionomers tethered to a Li anode that take advantage of three powerful processes for overcoming the most stubborn of these challenges. The ionomer SEIs are shown to protect the Li anode against parasitic reactions and also stabilize Li electrodeposition during cell recharge. Bromine species liberated during the anchoring reaction also function as redox mediators at the cathode, reducing the charge overpotential. Finally, the ionomer SEI forms a stable interphase with Li, which protects the metal in high Gutmann donor number liquid electrolytes. Such electrolytes have been reported to exhibit rare stability against nucleophilic attack by Li2O2 and other cathode reaction intermediates, but also react spontaneously with Li metal anodes. We conclude that rationally designed SEIs able to regulate transport of matter and ions at the electrolyte/anode interface provide a promising platform for addressing three major technical barriers to practical Li-O2 cells.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Engineering & Technology

Grant/Contract Number:: SC0001086

OSTI ID:: 1625969

Journal Information:: Science Advances, Vol. 3, Issue 4; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

References (68)

Single lithium-ion conducting polymer electrolytes based on poly[(4-styrenesulfonyl)(trifluoromethanesulfonyl)imide] anions Feng, Shaowei; Shi, Dongyang; Liu, Fang Electrochimica Acta, Vol. 93 https://doi.org/10.1016/j.electacta.2013.01.119	journal	March 2013
Nanostructured Electrolytes for Stable Lithium Electrodeposition in Secondary Batteries Tu, Zhengyuan; Nath, Pooja; Lu, Yingying Accounts of Chemical Research, Vol. 48, Issue 11 https://doi.org/10.1021/acs.accounts.5b00427	journal	October 2015
Effects of nitrogen on the carbon anode of a lithium secondary battery Wu, Yuping; Fang, Shibi; Jiang, Yingyan Solid State Ionics, Vol. 120, Issue 1-4 https://doi.org/10.1016/S0167-2738(98)00158-1	journal	May 1999
Screening for Superoxide Reactivity in Li-O ₂ Batteries: Effect on Li ₂ O ₂ /LiOH Crystallization Black, Robert; Oh, Si Hyoung; Lee, Jin-Hyon Journal of the American Chemical Society, Vol. 134, Issue 6 https://doi.org/10.1021/ja2111543	journal	February 2012
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Role of LiNO3 in rechargeable lithium/sulfur battery Zhang, Sheng S. Electrochimica Acta, Vol. 70 https://doi.org/10.1016/j.electacta.2012.03.081	journal	May 2012
Advances in understanding mechanisms underpinning lithium–air batteries Aurbach, Doron; McCloskey, Bryan D.; Nazar, Linda F. Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.128	journal	September 2016
On-surface photo-dissociation of C–Br bonds: towards room temperature Ullmann coupling Basagni, Andrea; Ferrighi, Lara; Cattelan, Mattia Chemical Communications, Vol. 51, Issue 63 https://doi.org/10.1039/C5CC04317D	journal	January 2015
A stable cathode for the aprotic Li–O2 battery Ottakam Thotiyl, Muhammed M.; Freunberger, Stefan A.; Peng, Zhangquan Nature Materials, Vol. 12, Issue 11 https://doi.org/10.1038/nmat3737	journal	September 2013
Li–O ₂ cells with LiBr as an electrolyte and a redox mediator Kwak, Won-Jin; Hirshberg, Daniel; Sharon, Daniel Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE00700G	journal	January 2016
Control of the Intermolecular Coupling of Dibromotetracene on Cu(110) by the Sequential Activation of CBr and CH Bonds Ferrighi, Lara; Píš, Igor; Nguyen, Thanh Hai Chemistry - A European Journal, Vol. 21, Issue 15 https://doi.org/10.1002/chem.201405817	journal	February 2015
A self-defense redox mediator for efficient lithium–O ₂ batteries Zhang, Tao; Liao, Kaiming; He, Ping Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE02803E	journal	January 2016
Reactions in the Rechargeable Lithium–O ₂ Battery with Alkyl Carbonate Electrolytes Freunberger, Stefan A.; Chen, Yuhui; Peng, Zhangquan Journal of the American Chemical Society, Vol. 133, Issue 20 https://doi.org/10.1021/ja2021747	journal	May 2011
An Electrochemical Impedance Spectroscopy Study on the Effects of the Surface- and Solution-Based Mechanisms in Li-O ₂ Cells Knudsen, Kristian B.; Vegge, Tejs; McCloskey, Bryan D. Journal of The Electrochemical Society, Vol. 163, Issue 9 https://doi.org/10.1149/2.1111609jes	journal	January 2016
Thermal Stability of Li ₂ O ₂ and Li ₂ O for Li-Air Batteries: In Situ XRD and XPS Studies Yao, Koffi P. C.; Kwabi, David G.; Quinlan, Ronald A. Journal of The Electrochemical Society, Vol. 160, Issue 6 https://doi.org/10.1149/2.069306jes	journal	January 2013
Lithium Fluoride Additives for Stable Cycling of Lithium Batteries at High Current Densities Choudhury, Snehashis; Archer, Lynden A. Advanced Electronic Materials, Vol. 2, Issue 2 https://doi.org/10.1002/aelm.201500246	journal	January 2016
High Lithium Transference Number Electrolytes via Creation of 3-Dimensional, Charged, Nanoporous Networks from Dense Functionalized Nanoparticle Composites Schaefer, Jennifer L.; Yanga, Dennis A.; Archer, Lynden A. Chemistry of Materials, Vol. 25, Issue 6 https://doi.org/10.1021/cm303091j	journal	March 2013
Twin Problems of Interfacial Carbonate Formation in Nonaqueous Li–O ₂ Batteries McCloskey, B. D.; Speidel, A.; Scheffler, R. The Journal of Physical Chemistry Letters, Vol. 3, Issue 8 https://doi.org/10.1021/jz300243r	journal	March 2012
Nucleation and Growth of Lithium Peroxide in the Li–O ₂ Battery Lau, Sampson; Archer, Lynden A. Nano Letters, Vol. 15, Issue 9 https://doi.org/10.1021/acs.nanolett.5b02149	journal	August 2015
Magnetism in Lithium-Oxygen Discharge Product Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun ChemSusChem, Vol. 6, Issue 7, p. 1196-1202 https://doi.org/10.1002/cssc.201300223	journal	May 2013
Understanding the behavior of Li–oxygen cells containing LiI Kwak, Won-Jin; Hirshberg, Daniel; Sharon, Daniel Journal of Materials Chemistry A, Vol. 3, Issue 16 https://doi.org/10.1039/C5TA01399B	journal	January 2015
Stable Cycling of Lithium Metal Batteries Using High Transference Number Electrolytes Lu, Yingying; Tikekar, Mukul; Mohanty, Ritesh Advanced Energy Materials, Vol. 5, Issue 9 https://doi.org/10.1002/aenm.201402073	journal	February 2015
Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries Bouchet, Renaud; Maria, Sébastien; Meziane, Rachid Nature Materials, Vol. 12, Issue 5 https://doi.org/10.1038/nmat3602	journal	March 2013
Controlled grafting of N-isoproply acrylamide brushes onto self-standing isotactic polypropylene thin films: surface initiated atom transfer radical polymerization Desai, Shrojal M.; Solanky, Shailendra S.; Mandale, A. B. Polymer, Vol. 44, Issue 25 https://doi.org/10.1016/j.polymer.2003.09.060	journal	December 2003
Nanoparticle networks reduce the flammability of polymer nanocomposites Kashiwagi, Takashi; Du, Fangming; Douglas, Jack F. Nature Materials, Vol. 4, Issue 12 https://doi.org/10.1038/nmat1502	journal	October 2005
Magnesium(II) Bis(trifluoromethane sulfonyl) Imide-Based Electrolytes with Wide Electrochemical Windows for Rechargeable Magnesium Batteries Ha, Se-Young; Lee, Yong-Won; Woo, Sang Won ACS Applied Materials & Interfaces, Vol. 6, Issue 6, p. 4063-4073 https://doi.org/10.1021/am405619v	journal	March 2014
Nonaqueous Li–Air Batteries: A Status Report Luntz, Alan C.; McCloskey, Bryan D. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500054y	journal	October 2014
A Rechargeable Li–O ₂ Battery Using a Lithium Nitrate/ N , N -Dimethylacetamide Electrolyte Walker, Wesley; Giordani, Vincent; Uddin, Jasim Journal of the American Chemical Society, Vol. 135, Issue 6 https://doi.org/10.1021/ja311518s	journal	January 2013
Improved cycling performances of lithium sulfur batteries with LiNO3-modified electrolyte Liang, Xiao; Wen, Zhaoyin; Liu, Yu Journal of Power Sources, Vol. 196, Issue 22 https://doi.org/10.1016/j.jpowsour.2011.08.027	journal	November 2011
Superior Rechargeability and Efficiency of Lithium-Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst Lim, Hee-Dae; Song, Hyelynn; Kim, Jinsoo Angewandte Chemie International Edition, Vol. 53, Issue 15 https://doi.org/10.1002/anie.201400711	journal	March 2014
Sustainable Redox Mediation for Lithium-Oxygen Batteries by a Composite Protective Layer on the Lithium-Metal Anode Lee, Dong Jin; Lee, Hongkyung; Kim, Yun-Jung Advanced Materials, Vol. 28, Issue 5 https://doi.org/10.1002/adma.201503169	journal	December 2015
Fundamental degradation mechanisms of layered oxide Li-ion battery cathode materials: Methodology, insights and novel approaches Hausbrand, R.; Cherkashinin, G.; Ehrenberg, H. Materials Science and Engineering: B, Vol. 192 https://doi.org/10.1016/j.mseb.2014.11.014	journal	February 2015
Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li–O2 batteries Aetukuri, Nagaphani B.; McCloskey, Bryan D.; García, Jeannette M. Nature Chemistry, Vol. 7, Issue 1 https://doi.org/10.1038/nchem.2132	journal	December 2014
Stabilizing electrodeposition in elastic solid electrolytes containing immobilized anions Tikekar, Mukul D.; Archer, Lynden A.; Koch, Donald L. Science Advances, Vol. 2, Issue 7 https://doi.org/10.1126/sciadv.1600320	journal	July 2016
Trade-Offs in Capacity and Rechargeability in Nonaqueous Li–O ₂ Batteries: Solution-Driven Growth versus Nucleophilic Stability Khetan, Abhishek; Luntz, Alan; Viswanathan, Venkatasubramanian The Journal of Physical Chemistry Letters, Vol. 6, Issue 7 https://doi.org/10.1021/acs.jpclett.5b00324	journal	March 2015
Cycling Li-O2 batteries via LiOH formation and decomposition Liu, T.; Leskes, M.; Yu, W. Science, Vol. 350, Issue 6260 https://doi.org/10.1126/science.aac7730	journal	October 2015
Combining Accurate O ₂ and Li ₂ O ₂ Assays to Separate Discharge and Charge Stability Limitations in Nonaqueous Li–O ₂ Batteries McCloskey, Bryan D.; Valery, Alexia; Luntz, Alan C. The Journal of Physical Chemistry Letters, Vol. 4, Issue 17 https://doi.org/10.1021/jz401659f	journal	August 2013
Charging a Li–O2 battery using a redox mediator Chen, Yuhui; Freunberger, Stefan A.; Peng, Zhangquan Nature Chemistry, Vol. 5, Issue 6 https://doi.org/10.1038/nchem.1646	journal	May 2013
Influence of Lithium Salts on the Discharge Chemistry of Li–Air Cells Veith, Gabriel M.; Nanda, Jagjit; Delmau, Laetitia H. The Journal of Physical Chemistry Letters, Vol. 3, Issue 10 https://doi.org/10.1021/jz300430s	journal	April 2012
On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries Aurbach, Doron; Pollak, Elad; Elazari, Ran Journal of The Electrochemical Society, Vol. 156, Issue 8, p. A694-A702 https://doi.org/10.1149/1.3148721	journal	January 2009
A Highly Active Low Voltage Redox Mediator for Enhanced Rechargeability of Lithium–Oxygen Batteries Kundu, Dipan; Black, Robert; Adams, Brian ACS Central Science, Vol. 1, Issue 9 https://doi.org/10.1021/acscentsci.5b00267	journal	November 2015
Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes Zhang, Zhengcheng; Lu, Jun; Assary, Rajeev S. The Journal of Physical Chemistry C, Vol. 115, Issue 51 https://doi.org/10.1021/jp2087412	journal	December 2011
In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions Lu, Yi-Chun; Crumlin, Ethan J.; Veith, Gabriel M. Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00715	journal	October 2012
An Electrochemical Impedance Spectroscopy Investigation of the Overpotentials in Li–O ₂ Batteries Højberg, Jonathan; McCloskey, Bryan D.; Hjelm, Johan ACS Applied Materials & Interfaces, Vol. 7, Issue 7 https://doi.org/10.1021/am5083254	journal	February 2015
Superior Rechargeability and Efficiency of Lithium-Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst Lim, Hee-Dae; Song, Hyelynn; Kim, Jinsoo Angewandte Chemie, Vol. 126, Issue 15 https://doi.org/10.1002/ange.201400711	journal	March 2014
Properties of surface film on lithium anode with LiNO3 as lithium salt in electrolyte solution for lithium–sulfur batteries Xiong, Shizhao; Xie, Kai; Diao, Yan Electrochimica Acta, Vol. 83 https://doi.org/10.1016/j.electacta.2012.07.118	journal	November 2012
The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li–O2 batteries Johnson, Lee; Li, Chunmei; Liu, Zheng Nature Chemistry, Vol. 6, Issue 12 https://doi.org/10.1038/nchem.2101	journal	November 2014
A Solution-Phase Bifunctional Catalyst for Lithium–Oxygen Batteries Sun, Dan; Shen, Yue; Zhang, Wang Journal of the American Chemical Society, Vol. 136, Issue 25 https://doi.org/10.1021/ja501877e	journal	June 2014
The Identification of Stable Solvents for Nonaqueous Rechargeable Li-Air Batteries Bryantsev, Vyacheslav S.; Uddin, Jasim; Giordani, Vincent Journal of The Electrochemical Society, Vol. 160, Issue 1 https://doi.org/10.1149/2.027302jes	journal	November 2012
Microscopic properties of lithium, sodium, and magnesium battery anode materials related to possible dendrite growth Jäckle, Markus; Groß, Axel The Journal of Chemical Physics, Vol. 141, Issue 17 https://doi.org/10.1063/1.4901055	journal	November 2014
The Influence of Catalysts on Discharge and Charge Voltages of Rechargeable Li–Oxygen Batteries Lu, Yi-Chun; Gasteiger, Hubert A.; Parent, Michael C. Electrochemical and Solid-State Letters, Vol. 13, Issue 6, p. A69-A72 https://doi.org/10.1149/1.3363047	journal	January 2010
A highly active nanostructured metallic oxide cathode for aprotic Li–O ₂ batteries Kundu, Dipan; Black, Robert; Berg, Erik Jämstorp Energy & Environmental Science, Vol. 8, Issue 4 https://doi.org/10.1039/C4EE02587C	journal	January 2015
Limitations in Rechargeability of Li-O ₂ Batteries and Possible Origins McCloskey, B. D.; Bethune, D. S.; Shelby, R. M. The Journal of Physical Chemistry Letters, Vol. 3, Issue 20 https://doi.org/10.1021/jz301359t	journal	September 2012
Design principles for electrolytes and interfaces for stable lithium-metal batteries Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.114	journal	September 2016
Lithium−Air Battery: Promise and Challenges Girishkumar, G.; McCloskey, B.; Luntz, A. C. The Journal of Physical Chemistry Letters, Vol. 1, Issue 14 https://doi.org/10.1021/jz1005384	journal	June 2010
Li–O₂ and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 1, p. 19-29 https://doi.org/10.1038/nmat3191	journal	January 2012
A highly reversible room-temperature lithium metal battery based on crosslinked hairy nanoparticles Choudhury, Snehashis; Mangal, Rahul; Agrawal, Akanksha Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms10101	journal	December 2015
The Effect of Interactions and Reduction Products of LiNO ₃ , the Anti-Shuttle Agent, in Li-S Battery Systems Rosenman, Ariel; Elazari, Ran; Salitra, Gregory Journal of The Electrochemical Society, Vol. 162, Issue 3 https://doi.org/10.1149/2.0861503jes	journal	December 2014
Stabilizing lithium metal using ionic liquids for long-lived batteries Basile, A.; Bhatt, A. I.; O’Mullane, A. P. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11794	journal	June 2016
A highly conductive, non-flammable polymer–nanoparticle hybrid electrolyte Agrawal, Akanksha; Choudhury, Snehashis; Archer, Lynden A. RSC Advances, Vol. 5, Issue 27 https://doi.org/10.1039/C5RA01031D	journal	January 2015
Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization Di Giovannantonio, Marco; El Garah, Mohamed; Lipton-Duffin, Josh ACS Nano, Vol. 7, Issue 9 https://doi.org/10.1021/nn4035684	journal	August 2013
Stability Analysis of Electrodeposition across a Structured Electrolyte with Immobilized Anions Tikekar, Mukul D.; Archer, Lynden A.; Koch, Donald L. Journal of The Electrochemical Society, Vol. 161, Issue 6 https://doi.org/10.1149/2.085405jes	journal	January 2014
A Review of Solid Electrolyte Interphases on Lithium Metal Anode Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Advanced Science, Vol. 3, Issue 3 https://doi.org/10.1002/advs.201500213	journal	November 2015
Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li–O ₂ battery capacity Burke, Colin M.; Pande, Vikram; Khetan, Abhishek Proceedings of the National Academy of Sciences, Vol. 112, Issue 30 https://doi.org/10.1073/pnas.1505728112	journal	July 2015
Ullmann-type coupling of brominated tetrathienoanthracene on copper and silver Gutzler, Rico; Cardenas, Luis; Lipton-Duffin, Josh Nanoscale, Vol. 6, Issue 5 https://doi.org/10.1039/C3NR05710K	journal	January 2014
Cycling Li-O2 Batteries via LiOH Formation and Decomposition Liu, Tao; Leskes, Michal; Yu, Wanjing arXiv https://doi.org/10.48550/arxiv.1805.03042	preprint	January 2018
Understanding the fundamentals of redox mediators in Li–O 2 batteries: a case study on nitroxides Bergner, Benjamin J.; Hofmann, Christine; Schürmann, Adrian Physical Chemistry Chemical Physics, Vol. 17, Issue 47 https://doi.org/10.1039/c5cp04505c	journal	January 2015
Stability and surface diffusion at lithium-electrolyte interphases with connections to dendrite suppression Ozhabes, Yalcin; Gunceler, Deniz; Arias, T. A. arXiv https://doi.org/10.48550/arxiv.1504.05799	preprint	January 2015

Cited By (27)

Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials Zachman, Michael J.; Hachtel, Jordan A.; Idrobo, Juan Carlos Angewandte Chemie, Vol. 132, Issue 4 https://doi.org/10.1002/ange.201902993	journal	October 2019
Langmuir–Blodgett artificial solid-electrolyte interphases for practical lithium metal batteries Kim, Mun Sek; Ryu, Ji-Hyun Nature Energy, Vol. 3, Issue 10 https://doi.org/10.1038/s41560-018-0237-6	journal	September 2018
Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna Angewandte Chemie, Vol. 129, Issue 42 https://doi.org/10.1002/ange.201707754	journal	September 2017
3D TiC/C Core/Shell Nanowire Skeleton for Dendrite-Free and Long-Life Lithium Metal Anode Liu, Sufu; Xia, Xinhui; Zhong, Yu Advanced Energy Materials, Vol. 8, Issue 8 https://doi.org/10.1002/aenm.201702322	journal	December 2017
Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery Fan, Xiulin; Ji, Xiao; Han, Fudong Science Advances, Vol. 4, Issue 12 https://doi.org/10.1126/sciadv.aau9245	journal	December 2018
Electrochemical and Structural Analysis in All‐Solid‐State Lithium Batteries by Analytical Electron Microscopy: Progress and Perspectives Zhang, Chunchen; Feng, Yuzhang; Han, Zhen Advanced Materials https://doi.org/10.1002/adma.201903747	journal	October 2019
Dendrite‐Free Epitaxial Growth of Lithium Metal during Charging in Li–O ₂ Batteries Xin, Xing; Ito, Kimihiko; Dutta, Arghya Angewandte Chemie International Edition, Vol. 57, Issue 40 https://doi.org/10.1002/anie.201808154	journal	October 2018
Prolonging the Cycle Life of a Lithium–Air Battery by Alleviating Electrolyte Degradation with a Ceramic–Carbon Composite Cathode Luo, Zhifu; Li, Yanyan; Liu, Zixuan ChemSusChem, Vol. 12, Issue 22 https://doi.org/10.1002/cssc.201901629	journal	October 2019
A Material Perspective of Rechargeable Metallic Lithium Anodes Li, Bin; Wang, Ying; Yang, Shubin Advanced Energy Materials, Vol. 8, Issue 13 https://doi.org/10.1002/aenm.201702296	journal	February 2018
Design Principles of Functional Polymer Separators for High-Energy, Metal-Based Batteries Zhang, Weidong; Tu, Zhengyuan; Qian, Jiawei Small, Vol. 14, Issue 11 https://doi.org/10.1002/smll.201703001	journal	December 2017
A versatile functionalized ionic liquid to boost the solution-mediated performances of lithium-oxygen batteries Zhang, Jinqiang; Sun, Bing; Zhao, Yufei Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08422-8	journal	February 2019
3D-Printed Graphene Oxide Framework with Thermal Shock Synthesized Nanoparticles for Li-CO ₂ Batteries Qiao, Yun; Liu, Yang; Chen, Chaoji Advanced Functional Materials, Vol. 28, Issue 51 https://doi.org/10.1002/adfm.201805899	journal	October 2018
Designing solid-liquid interphases for sodium batteries Choudhury, Snehashis; Wei, Shuya; Ozhabes, Yalcin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00742-x	journal	October 2017
Upgrading traditional liquid electrolyte via in situ gelation for future lithium metal batteries Liu, Feng-Quan; Wang, Wen-Peng; Yin, Ya-Xia Science Advances, Vol. 4, Issue 10 https://doi.org/10.1126/sciadv.aat5383	journal	October 2018
Interfacial Super‐Assembled Porous CeO ₂ /C Frameworks Featuring Efficient and Sensitive Decomposing Li ₂ O ₂ for Smart Li–O ₂ Batteries Hou, Yue; Wang, Jun; Liu, Jiaqing Advanced Energy Materials, Vol. 9, Issue 40 https://doi.org/10.1002/aenm.201901751	journal	September 2019
PEEK‐WC/Nanosponge Membranes for Lithium‐Anode Protection in Rechargeable Li−O ₂ Batteries Amici, Julia; Alidoost, Mojtaba; Caldera, Fabrizio ChemElectroChem, Vol. 5, Issue 12 https://doi.org/10.1002/celc.201800241	journal	May 2018
Prevention of dendrite growth and volume expansion to give high-performance aprotic bimetallic Li-Na alloy–O2 batteries Ma, Jin-ling; Meng, Fan-lu; Yu, Yue Nature Chemistry, Vol. 11, Issue 1 https://doi.org/10.1038/s41557-018-0166-9	journal	November 2018
Highly efficient and stable solid-state Li–O 2 batteries using a perovskite solid electrolyte Le, Hang T. T.; Ngo, Duc Tung; Didwal, Pravin N. Journal of Materials Chemistry A, Vol. 7, Issue 7 https://doi.org/10.1039/c8ta10771h	journal	January 2019
Graphene-based quasi-solid-state lithium–oxygen batteries with high energy efficiency and a long cycling lifetime Huang, Gang; Han, Jiuhui; Yang, Chuchu NPG Asia Materials, Vol. 10, Issue 11 https://doi.org/10.1038/s41427-018-0095-5	journal	November 2018
Emerging Electron Microscopy Techniques for Probing Functional Interfaces in Energy Materials Zachman, Michael J.; Hachtel, Jordan A.; Idrobo, Juan Carlos Angewandte Chemie International Edition, Vol. 59, Issue 4 https://doi.org/10.1002/anie.201902993	journal	January 2020
Dendrite‐Free Epitaxial Growth of Lithium Metal during Charging in Li–O ₂ Batteries Xin, Xing; Ito, Kimihiko; Dutta, Arghya Angewandte Chemie, Vol. 130, Issue 40 https://doi.org/10.1002/ange.201808154	journal	September 2018
Functional and stability orientation synthesis of materials and structures in aprotic Li–O ₂ batteries Zhang, Peng; Zhao, Yong; Zhang, Xinbo Chemical Society Reviews, Vol. 47, Issue 8 https://doi.org/10.1039/c8cs00009c	journal	January 2018
Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna Angewandte Chemie International Edition, Vol. 56, Issue 42 https://doi.org/10.1002/anie.201707754	journal	September 2017
Taming Interfacial Instability in Lithium–Oxygen Batteries: A Polymeric Ionic Liquid Electrolyte Solution Liu, Zhenjie; Huang, Jun; Zhang, Yantao Advanced Energy Materials, Vol. 9, Issue 41 https://doi.org/10.1002/aenm.201901967	journal	September 2019
Can Hybrid Na–Air Batteries Outperform Nonaqueous Na–O ₂ Batteries? Khan, Ziyauddin; Vagin, Mikhail; Crispin, Xavier Advanced Science, Vol. 7, Issue 5 https://doi.org/10.1002/advs.201902866	journal	January 2020
Cryogenic specimens for nanoscale characterization of solid–liquid interfaces Zachman, Michael J.; de Jonge, Niels; Fischer, Robert MRS Bulletin, Vol. 44, Issue 12 https://doi.org/10.1557/mrs.2019.289	journal	December 2019
An ion redistributor for dendrite-free lithium metal anodes Zhao, Chen-Zi; Chen, Peng-Yu; Zhang, Rui Science Advances, Vol. 4, Issue 11 https://doi.org/10.1126/sciadv.aat3446	journal	November 2018

Similar Records

Stable Solid Electrolyte Interphase Layer Formed by Electrochemical Pretreatment of Gel Polymer Coating on Li Metal Anode for Lithium–Oxygen Batteries

Journal Article · Fri Sep 10 00:00:00 EDT 2021 · ACS Energy Letters · OSTI ID:1625969

Lim, Hyung-Seok; Kwak, Wonjin; Chae, Sujong; +7 more

An Interconnected Channel-Like Framework as Host for Lithium Metal Composite Anodes

Journal Article · Wed Jan 02 00:00:00 EST 2019 · Advanced Energy Materials · OSTI ID:1625969

Wang, Hansen; Lin, Dingchang; Xie, Jin; +11 more

Characterization of the structure and chemistry of the solid–electrolyte interface by cryo-EM leads to high-performance solid-state Li-metal batteries

Journal Article · Thu Jun 30 00:00:00 EDT 2022 · Nature Nanotechnology · OSTI ID:1625969

Lin, Ruoqian; He, Yubin; Wang, Chunyang; +5 more

Related Subjects

25 ENERGY STORAGE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Science & Technology - Other Topics

Title: Designer interphases for the lithium-oxygen electrochemical cell

Citation Formats

References (68)

Cited By (27)

Similar Records

Related Subjects