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{2,6-Bis[(di-tert-butylphosphino)methyl]phenyl}chloridonickel(II)

Journal Article · · Acta Crystallographica. Section E
 [1];  [2];  [3];  [2]
  1. Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry and Chemical Biology; DOE/OSTI
  2. Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry and Chemical Biology
  3. Univ. of Washington, Seattle, WA (United States). Dept. of Chemsitry and Biochemistry
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In the title compound, [Ni(C24H43P2)Cl], the Ni atom adopts a distorted square-planar geometry, with the P atoms of the 2,6- bis[(di-tert-butylphosphino)methyl]phenyl ligand trans to one another. The P—Ni—P plane is twisted out of the plane of the aromatic ring by 21.97 (6)°.
Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States); Univ. of New Mexico, Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
Grant/Contract Number:
AC04-94AL85000; FG02-06ER15765
OSTI ID:
1625724
Journal Information:
Acta Crystallographica. Section E, Journal Name: Acta Crystallographica. Section E Journal Issue: 10 Vol. 64; ISSN 1600-5368
Publisher:
International Union of CrystallographyCopyright Statement
Country of Publication:
United States
Language:
English

References (7)

Palladium complexes with PCP ligands. journal March 2002
Mechanism of Direct Molecular Oxygen Insertion in a Palladium(II)−Hydride Bond journal November 2006
Insertion of Molecular Oxygen into a Palladium(II) Hydride Bond journal March 2006
Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenyl journal January 1976
Ti and Zr bidentate bis-phosphinimide complexes journal January 2003
A short history of SHELX journal December 2007
On enantiomorph-polarity estimation journal November 1983

Cited By (4)

Catalytic and Mechanistic Developments of the Nickel(II) Pincer Complex‐Catalyzed Hydroarsination Reaction journal August 2019
ECE-Type Pincer Complexes of Nickel book August 2012
[2,6-Bis(di- tert -butylphosphinomethyl)phenyl-κ 3 P , C 1 , P ′](nitrato-κ O )nickel(II) journal October 2008
Bis{bis[2-(diisopropylphosphanyl)phenyl]phosphanido-κ 3 P , P ′, P ′′}chloridonickel(II) journal November 2012

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Crystallography