Controlled growth of imine-linked two-dimensional covalent organic framework nanoparticles

Li, Rebecca L.; Flanders, Nathan C.; Evans, Austin M.; Ji, Woojung; Castano, Ioannina; Chen, Lin X.; Gianneschi, Nathan C.; Dichtel, William R.

doi:10.1039/C9SC00289H

Controlled growth of imine-linked two-dimensional covalent organic framework nanoparticles

Journal Article · Wed Mar 27 00:00:00 EDT 2019 · Chemical Science

DOI:https://doi.org/10.1039/C9SC00289H· OSTI ID:1497429

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Department of Chemistry, Northwestern University, Evanston, 60208 USA
Department of Chemistry, Northwestern University, Evanston, 60208 USA, Chemical Sciences and Engineering Division
Department of Chemistry, Northwestern University, Evanston, 60208 USA, Department of Materials Science and Engineering

Highly crystalline, monodisperse, imine-linked covalent organic framework nanoparticles were obtained under Sc(OTf) ₃ -catalyzed conditions and enlarged by a slow monomer addition technique that prevents secondary nucleation.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); US Army Research Office (ARO); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1497429

Alternate ID(s):: OSTI ID: 1624972
OSTI ID: 1755765

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 13 Vol. 10; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (28)

Rapid Photochemical Synthesis of Sea-Urchin-Shaped Hierarchical Porous COF-5 and Its Lithography-Free Patterned Growth Kim, Soyoung; Park, Chibeom; Lee, Minkyung Advanced Functional Materials, Vol. 27, Issue 32 https://doi.org/10.1002/adfm.201700925	journal	July 2017
Hybridization of MOFs and COFs: A New Strategy for Construction of MOF@COF Core-Shell Hybrid Materials Peng, Yongwu; Zhao, Meiting; Chen, Bo Advanced Materials, Vol. 30, Issue 3 https://doi.org/10.1002/adma.201705454	journal	November 2017
Manipulation of Amorphous-to-Crystalline Transformation: Towards the Construction of Covalent Organic Framework Hybrid Microspheres with NIR Photothermal Conversion Ability Tan, Jing; Namuangruk, Supawadee; Kong, Weifu Angewandte Chemie International Edition, Vol. 55, Issue 45 https://doi.org/10.1002/anie.201606155	journal	October 2016
Microtubular Self-Assembly of Covalent Organic Frameworks Gole, Bappaditya; Stepanenko, Vladimir; Rager, Sabrina Angewandte Chemie International Edition, Vol. 57, Issue 3 https://doi.org/10.1002/anie.201708526	journal	December 2017
Confining Functional Nanoparticles into Colloidal Imine-Based COF Spheres by a Sequential Encapsulation-Crystallization Method Rodríguez-San-Miguel, David; Yazdi, Amirali; Guillerm, Vincent Chemistry - A European Journal, Vol. 23, Issue 36 https://doi.org/10.1002/chem.201702072	journal	June 2017
Superior Charge Storage and Power Density of a Conducting Polymer-Modified Covalent Organic Framework Mulzer, Catherine R.; Shen, Luxi; Bisbey, Ryan P. ACS Central Science, Vol. 2, Issue 9 https://doi.org/10.1021/acscentsci.6b00220	journal	August 2016
Colloidal Covalent Organic Frameworks Smith, Brian J.; Parent, Lucas R.; Overholts, Anna C. ACS Central Science, Vol. 3, Issue 1 https://doi.org/10.1021/acscentsci.6b00331	journal	January 2017
Covalent Organic Frameworks as a Platform for Multidimensional Polymerization Bisbey, Ryan P.; Dichtel, William R. ACS Central Science, Vol. 3, Issue 6 https://doi.org/10.1021/acscentsci.7b00127	journal	May 2017
Scandium(III) Catalysis of Transimination Reactions. Independent and Constitutionally Coupled Reversible Processes Giuseppone, Nicolas; Schmitt, Jean-Louis; Schwartz, Evan Journal of the American Chemical Society, Vol. 127, Issue 15 https://doi.org/10.1021/ja042469q	journal	April 2005
β-Ketoenamine-Linked Covalent Organic Frameworks Capable of Pseudocapacitive Energy Storage DeBlase, Catherine R.; Silberstein, Katharine E.; Truong, Thanh-Tam Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja409421d	journal	October 2013
Postsynthetically Modified Covalent Organic Frameworks for Efficient and Effective Mercury Removal Sun, Qi; Aguila, Briana; Perman, Jason Journal of the American Chemical Society, Vol. 139, Issue 7 https://doi.org/10.1021/jacs.6b12885	journal	February 2017
Targeted Drug Delivery in Covalent Organic Nanosheets (CONs) via Sequential Postsynthetic Modification Mitra, Shouvik; Sasmal, Himadri Sekhar; Kundu, Tanay Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.7b00925	journal	March 2017
Rapid, Low Temperature Formation of Imine-Linked Covalent Organic Frameworks Catalyzed by Metal Triflates Matsumoto, Michio; Dasari, Raghunath R.; Ji, Woojung Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b01240	journal	March 2017
Selective Molecular Separation by Interfacially Crystallized Covalent Organic Framework Thin Films Dey, Kaushik; Pal, Manas; Rout, Kanhu Charan Journal of the American Chemical Society, Vol. 139, Issue 37 https://doi.org/10.1021/jacs.7b06640	journal	September 2017
A Synthetic Route for Crystals of Woven Structures, Uniform Nanocrystals, and Thin Films of Imine Covalent Organic Frameworks Zhao, Yingbo; Guo, Lei; Gándara, Felipe Journal of the American Chemical Society, Vol. 139, Issue 37 https://doi.org/10.1021/jacs.7b07457	journal	September 2017
Reticular Electronic Tuning of Porphyrin Active Sites in Covalent Organic Frameworks for Electrocatalytic Carbon Dioxide Reduction Diercks, Christian S.; Lin, Song; Kornienko, Nikolay Journal of the American Chemical Society, Vol. 140, Issue 3 https://doi.org/10.1021/jacs.7b11940	journal	January 2018
Construction of a Hierarchical Architecture of Covalent Organic Frameworks via a Postsynthetic Approach Zhang, Gen; Tsujimoto, Masahiko; Packwood, Daniel Journal of the American Chemical Society, Vol. 140, Issue 7 https://doi.org/10.1021/jacs.7b12350	journal	February 2018
Removal of GenX and Perfluorinated Alkyl Substances from Water by Amine-Functionalized Covalent Organic Frameworks Ji, Woojung; Xiao, Leilei; Ling, Yuhan Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b06958	journal	September 2018
Covalent organic frameworks: a materials platform for structural and functional designs Huang, Ning; Wang, Ping; Jiang, Donglin Nature Reviews Materials, Vol. 1, Issue 10 https://doi.org/10.1038/natrevmats.2016.68	journal	September 2016
Stable, crystalline, porous, covalent organic frameworks as a platform for chiral organocatalysts Xu, Hong; Gao, Jia; Jiang, Donglin Nature Chemistry, Vol. 7, Issue 11 https://doi.org/10.1038/nchem.2352	journal	September 2015
Self-templated chemically stable hollow spherical covalent organic framework Kandambeth, Sharath; Venkatesh, V.; Shinde, Digambar B. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7786	journal	April 2015
Facile room-temperature solution-phase synthesis of a spherical covalent organic framework for high-resolution chromatographic separation Yang, Cheng-Xiong; Liu, Chang; Cao, Yi-Meng Chemical Communications, Vol. 51, Issue 61 https://doi.org/10.1039/C5CC03413B	journal	January 2015
Insight into the crystallization of amorphous imine-linked polymer networks to 2D covalent organic frameworks Smith, Brian J.; Overholts, Anna C.; Hwang, Nicky Chemical Communications, Vol. 52, Issue 18 https://doi.org/10.1039/C5CC10221A	journal	January 2016
Covalent organic frameworks based on Schiff-base chemistry: synthesis, properties and potential applications Segura, José L.; Mancheño, María J.; Zamora, Félix Chemical Society Reviews, Vol. 45, Issue 20 https://doi.org/10.1039/C5CS00878F	journal	January 2016
Sub-micron spheres of an imine-based covalent organic framework: supramolecular functionalization and water-dispersibility Rodríguez-San-Miguel, David; Corral-Pérez, Juan J.; Gil-González, Eva CrystEngComm, Vol. 19, Issue 33 https://doi.org/10.1039/C6CE02200F	journal	January 2017
Ultrahigh volatile iodine uptake by hollow microspheres formed from a heteropore covalent organic framework Yin, Zhi-Jian; Xu, Shun-Qi; Zhan, Tian-Guang Chemical Communications, Vol. 53, Issue 53 https://doi.org/10.1039/C7CC01045A	journal	January 2017
Covalent organic frameworks Feng, Xiao; Ding, Xuesong; Jiang, Donglin Chemical Society Reviews, Vol. 41, Issue 18 https://doi.org/10.1039/c2cs35157a	journal	January 2012
Seeded growth of single-crystal two-dimensional covalent organic frameworks Evans, Austin M.; Parent, Lucas R.; Flanders, Nathan C. Science, Vol. 361, Issue 6397 https://doi.org/10.1126/science.aar7883	journal	June 2018

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Controlled growth of imine-linked two-dimensional covalent organic framework nanoparticles

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