Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules

Li, Haiying; Meng, Bo; Chai, Song-Hai; Liu, Honglai; Dai, Sheng

doi:10.1039/c5sc04034e

Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules

Journal Article · Fri Nov 13 00:00:00 EST 2015 · Chemical Science

DOI:https://doi.org/10.1039/c5sc04034e· OSTI ID:1624929

Li, Haiying ^[1]; ^[2]; Chai, Song-Hai ^[2]; Liu, Honglai ^[3]; Dai, Sheng ^[4]

East China University of Science and Technology, Shanghai (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); DOE/OSTI
Univ. of Tennessee, Knoxville, TN (United States)
East China University of Science and Technology, Shanghai (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

A hyper-crosslinked β-cyclodextrin porous polymer (BnCD-HCPP) was designed and synthesized facilely by β-cyclodextrin benzylation and subsequent crosslinking via a Friedel–Crafts alkylation route. The BnCD-HCPP shows an extremely high BET surface area, large pore volume, and high thermal stability, making it a highly efficient adsorbent for removal of aromatic pollutants from water. The adsorption efficiency in terms of distribution coefficient, defined as the ratio of adsorption capacity to equilibrium adsorbate concentration, ranged from 10³ to 10⁶ mL g^-1 within a concentration of 0–100 ppm, one order of magnitude higher than that of other β-cyclodextrin-based adsorbents reported previously. The molar percentage of adsorbate to β-cyclodextrin exceeded 300%, suggesting that the adsorption occurred not only in the cyclodextrin cavities via a 1 : 1 complexation, but also in the nanopores of the BnCD-HCPP created during the hyper-crosslinking. The BnCD-HCPP can be further functionalized by incorporation of gold nanoparticles for catalytic transformation of adsorbed phenolic compounds such as 4-nitrophenol to 4-aminophenol.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: 111 Project of China; Fundamental Research Funds for the Central Universities of China; National Basic Research Program of China; National Natural Science Foundation of China (NSFC); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1624929

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 2 Vol. 7; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO ₂ Capturing Materials Luo, Yali; Li, Buyi; Wang, Wei Advanced Materials, Vol. 24, Issue 42 https://doi.org/10.1002/adma.201202447	journal	September 2012
Triisobutylaluminium and Diisobutylaluminium Hydride as Molecular Scalpels: The Regioselective Stripping of Perbenzylated Sugars and Cyclodextrins Lecourt, Thomas; Herault, Alexandre; Pearce, Alan J. Chemistry - A European Journal, Vol. 10, Issue 12 https://doi.org/10.1002/chem.200305683	journal	June 2004
EDTA-Cross-Linked β-Cyclodextrin: An Environmentally Friendly Bifunctional Adsorbent for Simultaneous Adsorption of Metals and Cationic Dyes Zhao, Feiping; Repo, Eveliina; Yin, Dulin Environmental Science & Technology, Vol. 49, Issue 17 https://doi.org/10.1021/acs.est.5b02227	journal	August 2015
Evaluation of Mesoporous Cyclodextrin-Silica Nanocomposites for the Removal of Pesticides from Aqueous Media Sawicki, Richard; Mercier, Louis Environmental Science & Technology, Vol. 40, Issue 6 https://doi.org/10.1021/es051441r	journal	March 2006
Nanocage Structure Derived from Sulfonated β-Cyclodextrin Intercalated Layered Double Hydroxides and Selective Adsorption for Phenol Compounds Xue, Xiangyu; Gu, Qingyang; Pan, Guohua Inorganic Chemistry, Vol. 53, Issue 3 https://doi.org/10.1021/ic402494m	journal	January 2014
Carbohydrate-Mediated Purification of Petrochemicals Holcroft, James M.; Hartlieb, Karel J.; Moghadam, Peyman Z. Journal of the American Chemical Society, Vol. 137, Issue 17 https://doi.org/10.1021/ja511878b	journal	April 2015
Polymeric molecular sieve membranes via in situ cross-linking of non-porous polymer membrane templates Qiao, Zhen-An; Chai, Song-Hai; Nelson, Kimberly Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4705	journal	April 2014
Intraframework Metal Ion Adsorption in Ligand-Functionalized Mesoporous Silica Hossain, K. Z.; Mercier, L. Advanced Materials, Vol. 14, Issue 15 https://doi.org/10.1002/1521-4095(20020805)14:15<1053::AID-ADMA1053>3.0.CO;2-X	journal	August 2002
A Nanoreactor Framework of a Au@SiO2 Yolk/Shell Structure for Catalytic Reduction ofp-Nitrophenol Lee, Joongoo; Park, Ji Chan; Song, Hyunjoon Advanced Materials, Vol. 20, Issue 8 https://doi.org/10.1002/adma.200702338	journal	April 2008
Dopamine as a Carbon Source: The Controlled Synthesis of Hollow Carbon Spheres and Yolk-Structured Carbon Nanocomposites Liu, Rui; Mahurin, Shannon M.; Li, Chen Angewandte Chemie, Vol. 123, Issue 30 https://doi.org/10.1002/ange.201102070	journal	June 2011
Hypercrosslinked Phenolic Polymers with Well-Developed Mesoporous Frameworks Zhang, Jinshui; Qiao, Zhen-An; Mahurin, Shannon M. Angewandte Chemie, Vol. 127, Issue 15 https://doi.org/10.1002/ange.201500305	journal	February 2015
Dopamine as a Carbon Source: The Controlled Synthesis of Hollow Carbon Spheres and Yolk-Structured Carbon Nanocomposites Liu, Rui; Mahurin, Shannon M.; Li, Chen Angewandte Chemie International Edition, Vol. 50, Issue 30 https://doi.org/10.1002/anie.201102070	journal	June 2011
Hypercrosslinked Phenolic Polymers with Well-Developed Mesoporous Frameworks Zhang, Jinshui; Qiao, Zhen-An; Mahurin, Shannon M. Angewandte Chemie International Edition, Vol. 54, Issue 15 https://doi.org/10.1002/anie.201500305	journal	February 2015
Synthesis of Some Trifluoromethylated Cyclodextrin Derivatives and Analysis of Their Properties as Artificial Glycosidases and Oxidases Bjerre, Jeannette; Hauch Fenger, Thomas; Marinescu, Lavinia G. European Journal of Organic Chemistry, Vol. 2007, Issue 4 https://doi.org/10.1002/ejoc.200600762	journal	February 2007
Recent Development of Hypercrosslinked Microporous Organic Polymers Xu, Shujun; Luo, Yali; Tan, Bien Macromolecular Rapid Communications, Vol. 34, Issue 6 https://doi.org/10.1002/marc.201200788	journal	January 2013
Characterization, molecular dynamics, and encapsulation ability of β-cyclodextrin polymers crosslinked by polyethylene glycol Kono, Hiroyuki; Nakamura, Taichi; Hashimoto, Hisaho Carbohydrate Polymers, Vol. 128 https://doi.org/10.1016/j.carbpol.2015.04.009	journal	September 2015
Macromolecules based on recognition between cyclodextrin and guest molecules: Synthesis, properties and functions Liu, Bo-wen; Zhou, Hang; Zhou, Si-tong European Polymer Journal, Vol. 65 https://doi.org/10.1016/j.eurpolymj.2015.01.017	journal	April 2015
Responsive catalysis of thermoresponsive micelle-supported gold nanoparticles Wang, Yao; Wei, Guangwei; Zhang, Wangqing Journal of Molecular Catalysis A: Chemical, Vol. 266, Issue 1-2 https://doi.org/10.1016/j.molcata.2006.11.014	journal	April 2007
Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment Crini, Grégorio Progress in Polymer Science, Vol. 30, Issue 1 https://doi.org/10.1016/j.progpolymsci.2004.11.002	journal	January 2005
Environmental applications of water-insoluble β-cyclodextrin–epichlorohydrin polymers Morin-Crini, Nadia; Crini, Grégorio Progress in Polymer Science, Vol. 38, Issue 2 https://doi.org/10.1016/j.progpolymsci.2012.06.005	journal	February 2013
Polymerization of β-cyclodextrin with 1,2,3,4-butanetetracarboxylic dianhydride: Synthesis, structural characterization, and bisphenol A adsorption capacity Kono, Hiroyuki; Nakamura, Taichi Reactive and Functional Polymers, Vol. 73, Issue 8 https://doi.org/10.1016/j.reactfunctpolym.2013.04.006	journal	August 2013
Recyclable Capture and Destruction of Aqueous Micropollutants Using the Molecule-Specific Cavity of Cyclodextrin Polymer Coupled with KMnO ₄ Oxidation Cai, Xiyun; Liu, Qingquan; Xia, Chunlong Environmental Science & Technology, Vol. 49, Issue 15 https://doi.org/10.1021/acs.est.5b01734	journal	July 2015
Incorporation of Cyclodextrin into Mesostructured Silica Huq, R.; Mercier, L.; Kooyman, P. J. Chemistry of Materials, Vol. 13, Issue 12 https://doi.org/10.1021/cm010171i	journal	December 2001
Cyclodextrin-Functionalized Hierarchical Porous Architectures for High-Throughput Capture and Release of Organic Pollutants from Wastewater Schofield, W. C. E.; Bain, C. D.; Badyal, J. P. S. Chemistry of Materials, Vol. 24, Issue 9 https://doi.org/10.1021/cm300552k	journal	April 2012
New Organic Nanoporous Polymers and Their Inclusion Complexes Ma, Min; Li, DeQuan Chemistry of Materials, Vol. 11, Issue 4 https://doi.org/10.1021/cm981090y	journal	April 1999
Review: A History of Cyclodextrins Crini, Grégorio Chemical Reviews, Vol. 114, Issue 21 https://doi.org/10.1021/cr500081p	journal	September 2014
Biomimetic Reactions Catalyzed by Cyclodextrins and Their Derivatives Breslow, Ronald; Dong, Steven D. Chemical Reviews, Vol. 98, Issue 5 https://doi.org/10.1021/cr970011j	journal	July 1998
Cyclodextrin Polymers as Highly Effective Adsorbents for Removal and Recovery of Polychlorobiphenyl (PCB) Contaminants in Insulating Oil Kawano, Shintaro; Kida, Toshiyuki; Miyawaki, Kazuhiro Environmental Science & Technology, Vol. 48, Issue 14 https://doi.org/10.1021/es501243v	journal	June 2014
Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A. Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315 https://doi.org/10.1021/ja206525x	journal	October 2011
Supramolecular catalysis. Part 2: artificial enzyme mimics Raynal, Matthieu; Ballester, Pablo; Vidal-Ferran, Anton Chem. Soc. Rev., Vol. 43, Issue 5 https://doi.org/10.1039/C3CS60037H	journal	January 2014
Carbohydrate based hyper-crosslinked organic polymers with –OH functional groups for CO ₂ separation Li, Haiying; Meng, Bo; Mahurin, Shannon M. Journal of Materials Chemistry A, Vol. 3, Issue 42 https://doi.org/10.1039/C5TA03213J	journal	January 2015
Adsorption and separation of water-soluble aromatic molecules by cyclodextrin-functionalized mesoporous silicaElectronic supplementary information (ESI) available: Figs. S1–5: distribution coefficient profiles. See http://www.rsc.org/suppdata/gc/b2/b209251b/ Bibby, A.; Mercier, L. Green Chemistry, Vol. 5, Issue 1 https://doi.org/10.1039/b209251b	journal	December 2002
Synthesis of tetra-layer polymer composite microspheres and the corresponding hollow polymer microspheres with Au nanoparticles functionalized movable cores Zhang, Han; Yang, Xinlin Polymer Chemistry, Vol. 1, Issue 5 https://doi.org/10.1039/b9py00372j	journal	January 2010
β-Cyclodextrin-modified hybrid magnetic nanoparticles for catalysis and adsorption Kang, Yan; Zhou, Lilin; Li, Xia Journal of Materials Chemistry, Vol. 21, Issue 11 https://doi.org/10.1039/c0jm03513k	journal	January 2011
Au/graphene hydrogel: synthesis, characterization and its use for catalytic reduction of 4-nitrophenol Li, Jing; Liu, Chun-yan; Liu, Yun Journal of Materials Chemistry, Vol. 22, Issue 17 https://doi.org/10.1039/c2jm16386a	journal	January 2012
In situ growth synthesis of heterostructured LnPO4–SiO2 (Ln = La, Ce, and Eu) mesoporous materials as supports for small gold particles used in catalytic CO oxidation Tian, Chengcheng; Chai, Song-Hai; Zhu, Xiang Journal of Materials Chemistry, Vol. 22, Issue 48 https://doi.org/10.1039/c2jm35416k	journal	January 2012
Supramolecular chemistry and chemical warfare agents: from fundamentals of recognition to catalysis and sensing Sambrook, M. R.; Notman, S. Chemical Society Reviews, Vol. 42, Issue 24 https://doi.org/10.1039/c3cs60230c	journal	January 2013
Identification of site requirements for reduction of 4-nitrophenol using gold nanoparticle catalysts Nigra, Michael M.; Ha, Jeong-Myeong; Katz, Alexander Catalysis Science & Technology, Vol. 3, Issue 11 https://doi.org/10.1039/c3cy00298e	journal	January 2013
A renewable HSO3/H2PO3-grafted polyethylene fiber catalyst: an efficient heterogeneous catalyst for the synthesis of 5-hydroxymethylfurfural from fructose in water Tian, Chengcheng; Oyola, Yatsandra; Nelson, Kimberly M. RSC Advances, Vol. 3, Issue 44 https://doi.org/10.1039/c3ra43275k	journal	January 2013
Surface modification of zeolite with β-cyclodextrin for removal of p-nitrophenol from aqueous solution Li, Xiaohong; Zhu, Kun; Hao, Xuekui Water Science and Technology, Vol. 60, Issue 2 https://doi.org/10.2166/wst.2009.315	journal	July 2009

Cited By (31)

Porous Aromatic Frameworks as a Platform for Multifunctional Applications Yuan, Ye; Zhu, Guangshan ACS Central Science, Vol. 5, Issue 3 https://doi.org/10.1021/acscentsci.9b00047	journal	February 2019
One-pot synthesis of trifunctional chitosan-EDTA-β-cyclodextrin polymer for simultaneous removal of metals and organic micropollutants Zhao, Feiping; Repo, Eveliina; Yin, Dulin Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-16222-7	journal	November 2017
Emerging Functional Porous Polymeric and Carbonaceous Materials for Environmental Treatment and Energy Storage Zheng, Bingna; Lin, Xidong; Zhang, Xingcai Advanced Functional Materials, Vol. 30, Issue 41 https://doi.org/10.1002/adfm.201907006	journal	November 2019
Porous Polymers as Multifunctional Material Platforms toward Task-Specific Applications Wu, Jinlun; Xu, Fei; Li, Shimei Advanced Materials, Vol. 31, Issue 4 https://doi.org/10.1002/adma.201802922	journal	October 2018
Three-Dimensional Anionic Cyclodextrin-Based Covalent Organic Frameworks Zhang, Yuanyuan; Duan, Jiyun; Ma, Dou Angewandte Chemie, Vol. 129, Issue 51 https://doi.org/10.1002/ange.201710633	journal	November 2017
Dynamic Macromolecular Material Design-The Versatility of Cyclodextrin-Based Host-Guest Chemistry Schmidt, Bernhard V. K. J.; Barner-Kowollik, Christopher Angewandte Chemie International Edition, Vol. 56, Issue 29 https://doi.org/10.1002/anie.201612150	journal	June 2017
Three-Dimensional Anionic Cyclodextrin-Based Covalent Organic Frameworks Zhang, Yuanyuan; Duan, Jiyun; Ma, Dou Angewandte Chemie International Edition, Vol. 56, Issue 51 https://doi.org/10.1002/anie.201710633	journal	November 2017
Adsorption behavior and kinetics of CO ₂ on amine‐functionalized hyper‐crosslinked polymer Liu, Fenglei; Fu, Wenhao; Chen, Shuixia Journal of Applied Polymer Science, Vol. 137, Issue 12 https://doi.org/10.1002/app.48479	journal	September 2019
Highly Porous Hypercrosslinked Polymers Derived from Biobased Molecules Björnerbäck, Fredrik; Hedin, Niklas ChemSusChem, Vol. 12, Issue 4 https://doi.org/10.1002/cssc.201802681	journal	January 2019
Imidazolium‐Functionalized Ionic Hypercrosslinked Porous Polymers for Efficient Synthesis of Cyclic Carbonates from Simulated Flue Gas Zhang, Wenli; Ma, Fangpei; Ma, Long ChemSusChem, Vol. 13, Issue 2 https://doi.org/10.1002/cssc.201902952	journal	December 2019
Investigation on Naphthalene and Its Derivatives‐Based Microporous Organic Hyper‐Cross‐Linked Polymers via Different Methodologies Teng, Dao‐Guang; Wei, Xian‐Yong; Yang, Zheng Macromolecular Chemistry and Physics, Vol. 221, Issue 4 https://doi.org/10.1002/macp.201900302	journal	January 2020
Fibers with Hyper-Crosslinked Functional Porous Frameworks Sheng, Yujie; Chen, Qibin; Mahurin, Shannon M. Macromolecular Rapid Communications, Vol. 39, Issue 8 https://doi.org/10.1002/marc.201700767	journal	February 2018
A cost‐effective crosslinked β‐cyclodextrin polymer for the rapid and efficient removal of micropollutants from wastewater Yang, ChangAn; Huang, He; Ji, Tuo Polymer International, Vol. 68, Issue 4 https://doi.org/10.1002/pi.5771	journal	October 2018
Porphyrin-based covalent triazine frameworks: Porosity, adsorption performance, and drug delivery Luo, Yali; Liu, Jun; Liu, Yunfei Journal of Polymer Science Part A: Polymer Chemistry, Vol. 55, Issue 16 https://doi.org/10.1002/pola.28543	journal	May 2017
Synergistic Activity of Silver Nanoparticles and Polyaminocyclodextrins in Nanosponge Architectures Russo, Marco; Spinella, Alberto; Di Vincenzo, Antonella ChemistrySelect, Vol. 4, Issue 3 https://doi.org/10.1002/slct.201803424	journal	January 2019
Insight into the Catalytic Behavior in Nitroarenes Reduction over Non-Noble Metals Modified Polymer Carbon Nitride Xu, Yang-sen; Li, Li-ping; Qiu, Chun-tian ChemistrySelect, Vol. 4, Issue 1 https://doi.org/10.1002/slct.201803451	journal	January 2019
Monochlorotriazinyl‐β‐cyclodextrin Grafted on Graphene Oxide as an Attractive Green Heterogeneous Nanoreactor for Selective Oxidation Reaction with NBS in Water Pour, Shadi Rasoul; Dinari, Mohammad; Abdolmaleki, Amir ChemistrySelect, Vol. 4, Issue 20 https://doi.org/10.1002/slct.201900962	journal	May 2019
Hypercrosslinked porous polymer materials: design, synthesis, and applications Tan, Liangxiao; Tan, Bien Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c6cs00851h	journal	January 2017
Swellable functional hypercrosslinked polymer networks for the uptake of chemical warfare agents Wilson, Craig; Main, Marcus J.; Cooper, Nicholas J. Polymer Chemistry, Vol. 8, Issue 12 https://doi.org/10.1039/c7py00040e	journal	January 2017
Ordered and disordered cyclodextrin nanosponges with diverse physicochemical properties Singh, Vikramjeet; Xu, Jianghui; Wu, Li RSC Advances, Vol. 7, Issue 38 https://doi.org/10.1039/c7ra00584a	journal	January 2017
Recent developments in the synthesis and applications of graphene-family materials functionalized with cyclodextrins Kasprzak, Artur; Poplawska, Magdalena Chemical Communications, Vol. 54, Issue 62 https://doi.org/10.1039/c8cc04120b	journal	January 2018
Adsorptive removal of p -nitrophenol from water with mechano-synthesized porous organic polymers Zeng, Heng; Lu, Weigang; Hao, Leiduan New Journal of Chemistry, Vol. 42, Issue 24 https://doi.org/10.1039/c8nj04575e	journal	January 2018
Effects of synthesis methodology on microporous organic hyper-cross-linked polymers with respect to structural porosity, gas uptake performance and fluorescence properties Hou, Shuangshuang; Razzaque, Shumaila; Tan, Bien Polymer Chemistry, Vol. 10, Issue 11 https://doi.org/10.1039/c8py01730a	journal	January 2019
A porous β-cyclodextrin-based terpolymer fluorescence sensor for in situ trinitrophenol detection Danquah, Michael K.; Wang, Shan; Wang, Qianyou RSC Advances, Vol. 9, Issue 14 https://doi.org/10.1039/c8ra06192k	journal	January 2019
Simple synthesis of a swellable porous β-cyclodextrin-based polymer in the aqueous phase for the rapid removal of organic micro-pollutants from water Xu, Guizhou; Xie, Xianchuan; Qin, Long Green Chemistry, Vol. 21, Issue 22 https://doi.org/10.1039/c9gc02422k	journal	January 2019
β-Cyclodextrin-based hollow nanoparticles with excellent adsorption performance towards organic and inorganic pollutants Liu, Yinli; Liu, Miao; Jia, Jie Nanoscale, Vol. 11, Issue 40 https://doi.org/10.1039/c9nr07342f	journal	January 2019
Cross-linking of poly(dimethylaminoethyl methacrylate) by phytic acid: pH-responsive adsorbent for high-efficiency removal of cationic and anionic dyes Liu, Wenbo; Hu, Rui; Li, Yanke RSC Advances, Vol. 10, Issue 8 https://doi.org/10.1039/c9ra09391e	journal	January 2020
Isolation and Determination of Beta-Carotene in Carrots by Magnetic Chitosan Beta-Cyclodextrin Extraction and High-Performance Liquid Chromatography (HPLC) Dai, Yunliang; Row, Kyung Ho Analytical Letters, Vol. 52, Issue 11 https://doi.org/10.1080/00032719.2019.1570245	journal	February 2019
Covalent Organic Frameworks: Promising Materials as Heterogeneous Catalysts for C-C Bond Formations Ma, Dongge; Wang, Yi; Liu, Anan Catalysts, Vol. 8, Issue 9 https://doi.org/10.3390/catal8090404	journal	September 2018
Isolation and Determination of Beta-Carotene in Carrots by Magnetic Chitosan Beta-Cyclodextrin Extraction and High-Performance Liquid Chromatography (HPLC) Dai, Yunliang; Row, Kyung Ho Taylor & Francis https://doi.org/10.6084/m9.figshare.7678631	text	January 2019
Isolation and Determination of Beta-Carotene in Carrots by Magnetic Chitosan Beta-Cyclodextrin Extraction and High-Performance Liquid Chromatography (HPLC) Dai, Yunliang; Row, Kyung Ho Taylor & Francis https://doi.org/10.6084/m9.figshare.7678631.v2	text	January 2019

Similar Records

Hyper-crosslinked cyclodextrin porous polymer: An efficient CO₂ capturing material with tunable porosity

Journal Article · Thu Nov 10 19:00:00 EST 2016 · RSC Advances · OSTI ID:1341581

Interaction of o-aminophenol and o-nitrophenol with copper, zinc, molybdenum, and chromium ferrocyanides

Journal Article · Mon Sep 15 00:00:00 EDT 1997 · Journal of Colloid and Interface Science · OSTI ID:556747

Kinetic, Isotherm and Thermodynamic Studies for Removal of Methylene Blue Using β-Cyclodextrin/Activated Carbon Aerogels

Journal Article · Wed Aug 15 00:00:00 EDT 2018 · Journal of Polymers and the Environment · OSTI ID:22788009

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry

Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules

Citation Formats

References (40)

Cited By (31)

Similar Records

Related Subjects