Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Strain incompatibility and residual strains in ferroelectric single crystals

Journal Article · · Scientific Reports
DOI:https://doi.org/10.1038/srep00929· OSTI ID:1624580
 [1];  [2];  [2];  [2];  [3];  [3]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Division; DOE/OSTI
  2. Univ. of Florida, Gainesville, FL (United States). Dept. of Materials Science and Engineering
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Division
Residual strains in ferroelectrics are known to adversely affect the material properties by aggravating crack growth and fatigue degradation. The primary cause for residual strains is strain incompatibility between different microstructural entities. For example, it was shown in polycrystalline ferroelectrics that residual strains are caused due to incompatibility between the electric-field-induced strains in grains with different crystallographic orientations. However, similar characterization of cause-effect in multidomain ferroelectric single crystals is lacking. In this article, we report on the development of plastic residual strains in [111]-oriented domain engineered BaTiO3 single crystals. These internal strains are created due to strain incompatibility across 906 domain walls between the differently oriented domains. The average residual strains over a large crystal volume measured by in situ neutron diffraction is comparable to previous X-ray measurements of localized strains near domain boundaries, but are an order of magnitude lower than electric-field-induced residual strains in polycrystalline ferroelectrics.
Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
National Science Foundation (NSF); US Army Research Office (ARO); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1624580
Journal Information:
Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 2; ISSN 2045-2322
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (37)

Critical Property in Relaxor-PbTiO3 Single Crystals - Shear Piezoelectric Response journal April 2011
Compatibility effects at the phase interfaces in duplex steel () bicrystals journal February 1997
Damage evolution in ferroelectric PZT induced by bipolar electric cycling journal September 2000
Direct measurement of triaxial strain fields around ferroelectric domains using X-ray microdiffraction journal May 2003
Large strain electrostrictive actuation in barium titanate journal September 2000
Virtual piezoforce microscopy of polycrystalline ferroelectric films journal September 2006
Ferroelectric, dielectric and piezoelectric properties of ferroelectric thin films and ceramics journal September 1998
Domain Dynamics During Ferroelectric Switching journal November 2011
Rotator and extender ferroelectrics: Importance of the shear coefficient to the piezoelectric properties of domain-engineered crystals and ceramics text January 2007
The deformation behavior of isoaxial bicrystals of Fe-3%Si journal March 1967
Compatibility effects at the phase interfaces in duplex steel () bicrystals journal February 1997
Influence of the electric field on vickers indentation crack growth in BaTiO3 journal June 1999
Damage evolution in ferroelectric PZT induced by bipolar electric cycling journal September 2000
Computational modeling of domain wall interactions with dislocations in ferroelectric crystals journal March 2009
Micromechanics of residual stress and texture development due to poling in polycrystalline ferroelectric ceramics journal February 2005
Texture of poled tetragonal PZT detected by synchrotron X-ray diffraction and micromechanics analysis journal November 2005
VULCAN—The engineering diffractometer at the SNS journal November 2006
Structural Consequences of Ferroelectric Nanolithography journal August 2011
Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics journal January 2000
Link‐up of 90° domain boundaries with interface dislocations in BaTiO 3 /LaAlO 3 journal May 1996
Phenomenologically derived electric field-temperature phase diagrams and piezoelectric coefficients for single crystal barium titanate under fields along different axes journal April 2001
Domain engineering of the transverse piezoelectric coefficient in perovskite ferroelectrics journal July 2005
Enhanced piezoelectric properties of barium titanate single crystals with different engineered-domain sizes journal July 2005
Rotator and extender ferroelectrics: Importance of the shear coefficient to the piezoelectric properties of domain-engineered crystals and ceramics journal March 2007
Neutron diffraction study of the polarization reversal mechanism in [111]c-oriented Pb(Zn1∕3Nb2∕3)O3−xPbTiO3 journal May 2007
X-ray diffraction and phenomenological studies of the engineered monoclinic crystal domains in single crystal relaxor ferroelectrics journal June 2000
Stress and strain around grain-boundary dislocations measured by high-resolution electron microscopy journal October 2006
Principles and Applications of Ferroelectrics and Related Materials book February 2001
Double Hysteresis Loop of BaTi O 3 at the Curie Point journal August 1953
Neutron diffraction study of field-cooling effects on the relaxor ferroelectric Pb [ ( Zn 1 / 3 Nb 2 / 3 ) 0.92 Ti 0.08 ] O 3 journal March 2003
Microstructure of Ferroelectric Domains in BaTiO 3 Observed via X-Ray Microdiffraction journal August 2005
Domain wall nanoelectronics journal February 2012
X-ray diffraction study of KTP (KTiOPO 4 ) crystals under a static electric field journal April 1992
Materials Science: Shape-Changing Crystals Get Shiftier journal March 1997
Enhanced Piezoelectric Property of Barium Titanate Single Crystals with Engineered Domain Configurations journal September 1999
X-Ray Diffraction Topography on a BaTiO 3 Crystal journal April 2004
Ferroelasticity of the displacive tetragonal phase in Y 2 O 3 partially stabilized ZrO 2 (Y-PSZ) single crystals journal August 1996

Cited By (4)

Both High Reliability and Giant Electrocaloric Strength in BaTiO3 Ceramics journal October 2013
Large field-induced-strain at high temperature in ternary ferroelectric crystals journal October 2016
90-degree polarization switching in BaTiO 3 crystals without domain wall motion journal December 2013
Characterization of Pb-Free KNbO3- and (Na,Bi)TiO3-Based Piezoelectric Single-Crystals Using X-ray and Neutron Diffraction journal January 2018

Similar Records

Direct measurement of triaxial strain fields around ferroelectric domains using X-ray microdiffraction
Journal Article · Fri May 30 00:00:00 EDT 2003 · Nature Materials · OSTI ID:815370

Fatigue of ferroelectric polarization and the electric field induced strain in lead lanthanum zirconate titanate ceramics
Journal Article · Mon Jun 01 00:00:00 EDT 1992 · Journal of the American Ceramic Society; (United States) · OSTI ID:7237999

Interaction of ferroelectric twins with grain boundaries
Conference · Sat Dec 30 23:00:00 EST 1995 · OSTI ID:175098