Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework

Verma, Sanny; Baig, R. B.  Nasir; Nadagouda, Mallikarjuna N.; Varma, Rajender S.

doi:10.1038/s41598-017-00736-1

Fixation of carbon dioxide into dimethyl carbonate over titanium-based zeolitic thiophene-benzimidazolate framework

Journal Article · Wed Apr 05 00:00:00 EDT 2017 · Scientific Reports

DOI:https://doi.org/10.1038/s41598-017-00736-1· OSTI ID:1624283

Verma, Sanny ^[1]; Baig, R. B. Nasir ^[2]; Nadagouda, Mallikarjuna N. ^[3]; ^[4]

Oak Ridge Inst. for Science and Education (ORISE), Oak Ridge, TN (United States); DOE/OSTI
Oak Ridge Inst. for Science and Education (ORISE), Oak Ridge, TN (United States)
US Environmental Protection Agency (EPA), Cincinnati, OH (United States). National Risk Management Research Lab. WQMB. WSWRD
US Environmental Protection Agency (EPA), Cincinnati, OH (United States). National Risk Management Research Lab. Sustainable Technology Division

A titanium-based zeolitic thiophene-benzimidazolate framework has been designed for the direct synthesis of dimethyl carbonate (DMC) from methanol and carbon dioxide. The developed catalyst activates carbon dioxide and delivers over 16% yield of DMC without the use of any dehydrating agent or requirement for azeotropic distillation.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge Institute for Science and Education (ORISE), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0014664

OSTI ID:: 1624283

Journal Information:: Scientific Reports, Journal Name: Scientific Reports Journal Issue: 1 Vol. 7; ISSN 2045-2322

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters Fang, Wei-Hui; Zhang, Lei; Zhang, Jian Chemical Society Reviews, Vol. 47, Issue 2 https://doi.org/10.1039/c7cs00511c	journal	January 2018
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