Enhanced pyroelectric properties of Bi1-x La x FeO 3 thin films

Zhang, Lei; Huang, Yen-Lin; Velarde, Gabriel; Ghosh, Anirban; Pandya, Shishir; Garcia, David; Ramesh, Ramamoorthy; Martin, Lane W.

doi:10.1063/1.5128413

Enhanced pyroelectric properties of Bi_1-x La _x FeO ₃ thin films

Journal Article · Fri Nov 22 04:00:00 EST 2019 · APL Materials

DOI:https://doi.org/10.1063/1.5128413· OSTI ID:1619136

^[1]; Huang, Yen-Lin ^[2]; Velarde, Gabriel ^[3]; Ghosh, Anirban ^[3]; Pandya, Shishir ^[3]; Garcia, David ^[3]; Ramesh, Ramamoorthy ^[1]; ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States). Dept. of Materials Science and Engineering

There is growing interest in the study of thin-film pyroelectric materials because of their potential for high performance thermal-energy conversion, thermal sensing, and beyond. Electrothermal susceptibilities, such as pyroelectricity, are known to be enhanced in proximity to polar instabilities, and this is conventionally accomplished by positioning the material close to a temperature-driven ferroelectric-to-paraelectric phase transition. The high Curie temperature (T_C) for many ferroelectrics, however, limits the utility of these materials at room-temperature. Here, the nature of pyroelectric response in thin films of the widely studied multiferroic Bi_1-xLa_xFeO₃ (x = 0-0.45) is probed. While BiFeO₃ itself has a high T_C, lanthanum substitution results in a chemically induced lowering of the ferroelectric-to-paraelectric and structural-phase transition. The effect of isovalent lanthanum substitution on the structural, dielectric, ferroelectric, and pyroelectric response is investigated using reciprocal-space-mapping studies; field-, frequency-, and temperature-dependent electrical measurements; and phase-sensitive pyroelectric measurements, respectively. While BiFeO₃ itself has a rather small pyroelectric coefficient at room temperature (~-40 μC/m² K), 15% lanthanum substitution results in an enhancement of the pyroelectric coefficient by 100% which is found to arise from a systematic lowering of T_C.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1619136

Journal Information:: APL Materials, Journal Name: APL Materials Journal Issue: 11 Vol. 7; ISSN 2166-532X

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (57)

Finite-Temperature Properties of Rare-Earth-Substituted BiFeO ₃ Multiferroic Solid Solutions Xu, Bin; Wang, Dawei; Íñiguez, Jorge Advanced Functional Materials, Vol. 25, Issue 4 https://doi.org/10.1002/adfm.201403811	journal	December 2014
Frontiers in the Growth of Complex Oxide Thin Films: Past, Present, and Future of Hybrid MBE Brahlek, Matthew; Gupta, Arnab Sen; Lapano, Jason Advanced Functional Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adfm.201702772	journal	December 2017
Physics and Applications of Bismuth Ferrite Catalan, Gustau; Scott, James F. Advanced Materials, Vol. 21, Issue 24 https://doi.org/10.1002/adma.200802849	journal	June 2009
Chemical Substitution-Induced Ferroelectric Polarization Rotation in BiFeO3 Kan, Daisuke; Anbusathaiah, Varatharajan; Takeuchi, Ichiro Advanced Materials, Vol. 23, Issue 15 https://doi.org/10.1002/adma.201004503	journal	March 2011
Understanding the Role of Ferroelastic Domains on the Pyroelectric and Electrocaloric Effects in Ferroelectric Thin Films Pandya, Shishir; Velarde, Gabriel A.; Gao, Ran Advanced Materials, Vol. 31, Issue 5 https://doi.org/10.1002/adma.201803312	journal	December 2018
Pyroelectric properties of BiFeO3 ceramics prepared by a modified solid-state-reaction method Yao, Yingbang; Ploss, Bernd; Mak, C. L. Applied Physics A, Vol. 99, Issue 1 https://doi.org/10.1007/s00339-009-5499-1	journal	December 2009
Characterization of materials for integrated pyroelectric sensors Ploss, Bernd; Bauer, Siegfried Sensors and Actuators A: Physical, Vol. 26, Issue 1-3 https://doi.org/10.1016/0924-4247(91)87023-v	journal	March 1991
Lead-free Ba(1-x)SrxTiO3 ceramics for room-temperature pyroelectric energy conversion Fan, Baoyan; Yang, Guang; Li, Ming-Yu Ceramics International, Vol. 44, Issue 7 https://doi.org/10.1016/j.ceramint.2018.02.009	journal	May 2018
Advanced synthesis techniques and routes to new single-phase multiferroics Martin, Lane W.; Schlom, Darrell G. Current Opinion in Solid State and Materials Science, Vol. 16, Issue 5 https://doi.org/10.1016/j.cossms.2012.03.001	journal	October 2012
Pyroelectric properties and electrical conductivity in samarium doped BiFeO3 ceramics Yao, Y. B.; Liu, W. C.; Mak, C. L. Journal of Alloys and Compounds, Vol. 527 https://doi.org/10.1016/j.jallcom.2012.02.182	journal	June 2012
Advances in the growth and characterization of magnetic, ferroelectric, and multiferroic oxide thin films Martin, L. W.; Chu, Y. -H.; Ramesh, R. Materials Science and Engineering: R: Reports, Vol. 68, Issue 4-6 https://doi.org/10.1016/j.mser.2010.03.001	journal	May 2010
Atomic Visualization of the Phase Transition in Highly Strained BiFeO3 Thin Films with Excellent Pyroelectric Response Chiu, Chung-Hua; Liang, Wen-I; Huang, Chun-Wei Nano Energy, Vol. 17 https://doi.org/10.1016/j.nanoen.2015.08.001	journal	October 2015
Nonstoichiometry, Structure, and Properties of BiFeO ₃ Films Dedon, Liv R.; Saremi, Sahar; Chen, Zuhuang Chemistry of Materials, Vol. 28, Issue 16 https://doi.org/10.1021/acs.chemmater.6b02542	journal	August 2016
Improved Pyroelectric Figures of Merit in Compositionally Graded PbZr _{1– x} Ti _x O ₃ Thin Films Mangalam, R. V. K.; Agar, J. C.; Damodaran, A. R. ACS Applied Materials & Interfaces, Vol. 5, Issue 24 https://doi.org/10.1021/am404228c	journal	December 2013
Displacive Phase Transitions and Magnetic Structures in Nd-Substituted BiFeO ₃ Levin, I.; Tucker, M. G.; Wu, H. Chemistry of Materials, Vol. 23, Issue 8 https://doi.org/10.1021/cm1036925	journal	April 2011
Thin-film ferroelectric materials and their applications Martin, Lane W.; Rappe, Andrew M. Nature Reviews Materials, Vol. 2, Issue 2 https://doi.org/10.1038/natrevmats.2016.87	journal	November 2016
Electric-field-induced spin disorder-to-order transition near a multiferroic triple phase point Jang, Byung-Kweon; Lee, Jin Hong; Chu, Kanghyun Nature Physics, Vol. 13, Issue 2 https://doi.org/10.1038/nphys3902	journal	October 2016
New approach to waste-heat energy harvesting: pyroelectric energy conversion Pandya, Shishir; Velarde, Gabriel; Zhang, Lei NPG Asia Materials, Vol. 11, Issue 1 https://doi.org/10.1038/s41427-019-0125-y	journal	June 2019
Pyroelectric energy conversion with large energy and power density in relaxor ferroelectric thin films Pandya, Shishir; Wilbur, Joshua; Kim, Jieun Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0059-8	journal	April 2018
Pyroelectric and electrocaloric materials Li, Xinyu; Lu, Sheng-Guo; Chen, Xiang-Zhong J. Mater. Chem. C, Vol. 1, Issue 1 https://doi.org/10.1039/c2tc00283c	journal	January 2013
Pyroelectric materials and devices for energy harvesting applications Bowen, C. R.; Taylor, J.; LeBoulbar, E. Energy Environ. Sci., Vol. 7, Issue 12 https://doi.org/10.1039/c4ee01759e	journal	January 2014
Crystal structure and ferroelectric properties of rare-earth substituted BiFeO3 thin films Uchida, Hiroshi; Ueno, Risako; Funakubo, Hiroshi Journal of Applied Physics, Vol. 100, Issue 1 https://doi.org/10.1063/1.2210167	journal	July 2006
Leakage mechanisms in BiFeO3 thin films Pabst, Gary W.; Martin, Lane W.; Chu, Ying-Hao Applied Physics Letters, Vol. 90, Issue 7 https://doi.org/10.1063/1.2535663	journal	February 2007
Low voltage performance of epitaxial BiFeO3 films on Si substrates through lanthanum substitution Chu, Y. H.; Zhan, Q.; Yang, C. -H. Applied Physics Letters, Vol. 92, Issue 10 https://doi.org/10.1063/1.2897304	journal	March 2008
Combinatorial discovery of a lead-free morphotropic phase boundary in a thin-film piezoelectric perovskite Fujino, S.; Murakami, M.; Anbusathaiah, V. Applied Physics Letters, Vol. 92, Issue 20 https://doi.org/10.1063/1.2931706	journal	May 2008
Effect of domain structure on dielectric nonlinearity in epitaxial BiFeO3 films Ihlefeld, J. F.; Folkman, C. M.; Baek, S. H. Applied Physics Letters, Vol. 97, Issue 26 https://doi.org/10.1063/1.3533017	journal	December 2010
Electric field control of magnetism using BiFeO ₃ -based heterostructures Heron, J. T.; Schlom, D. G.; Ramesh, R. Applied Physics Reviews, Vol. 1, Issue 2 https://doi.org/10.1063/1.4870957	journal	June 2014
Effect of “symmetry mismatch” on the domain structure of rhombohedral BiFeO ₃ thin films Chen, Z. H.; Damodaran, A. R.; Xu, R. Applied Physics Letters, Vol. 104, Issue 18 https://doi.org/10.1063/1.4875801	journal	May 2014
Enhanced electrocaloric and pyroelectric response from ferroelectric multilayers Kesim, M. T.; Zhang, J.; Alpay, S. P. Applied Physics Letters, Vol. 105, Issue 5 https://doi.org/10.1063/1.4892455	journal	August 2014
High-frequency thermal-electrical cycles for pyroelectric energy conversion Bhatia, Bikram; Damodaran, Anoop R.; Cho, Hanna Journal of Applied Physics, Vol. 116, Issue 19 https://doi.org/10.1063/1.4901993	journal	November 2014
Pyroelectric response in crystalline hafnium zirconium oxide (Hf _1- _x Zr _x O ₂ ) thin films Smith, S. W.; Kitahara, A. R.; Rodriguez, M. A. Applied Physics Letters, Vol. 110, Issue 7 https://doi.org/10.1063/1.4976519	journal	February 2017
How to measure the pyroelectric coefficient? Jachalke, S.; Mehner, E.; Stöcker, H. Applied Physics Reviews, Vol. 4, Issue 2 https://doi.org/10.1063/1.4983118	journal	June 2017
A method of poling LiNbO ₃ and LiTaO ₃ below T _c Haycock, P. W.; Townsend, P. D. Applied Physics Letters, Vol. 48, Issue 11 https://doi.org/10.1063/1.96747	journal	March 1986
Epitaxial Multiferroic BiFeO ₃ Thin Films: Progress and Future Directions Chu, Y. H.; Martin, L. W.; Zhan, Q. Ferroelectrics, Vol. 354, Issue 1 https://doi.org/10.1080/00150190701454867	journal	August 2007
The pyroelectric properties of the lanthanum-doped ferroelectric plzt ceramics Liu, S. T.; Heaps, J. D.; Tufte, O. N. Ferroelectrics, Vol. 3, Issue 1 https://doi.org/10.1080/00150197208235319	journal	February 1972
Evaluation of curie constants of ferroelectric crystals from pyroelectric response Liu, S. T.; Zook, J. D. Ferroelectrics, Vol. 7, Issue 1 https://doi.org/10.1080/00150197408237985	journal	January 1974
Relationships between pyroelectric and ferroelectric parameters Liu, S. T.; Zook, J. D.; Long, D. Ferroelectrics, Vol. 9, Issue 1 https://doi.org/10.1080/00150197508240079	journal	January 1975
Pyroelectric ceramics and devices for thermal infra-red detection and imaging Whatmore, R. W. Ferroelectrics, Vol. 118, Issue 1 https://doi.org/10.1080/00150199108014764	journal	June 1991
Relations between curie temperature and chemical bond in octahedral monodimensional ferroelectrics Ravez, J. Phase Transitions, Vol. 33, Issue 1-4 https://doi.org/10.1080/01411599108207711	journal	April 1991
Pyroelectric devices and materials Whatmore, R. W. Reports on Progress in Physics, Vol. 49, Issue 12 https://doi.org/10.1088/0034-4885/49/12/002	journal	December 1986
Micromachined infrared detectors based on pyroelectric thin films Muralt, Paul Reports on Progress in Physics, Vol. 64, Issue 10 https://doi.org/10.1088/0034-4885/64/10/203	journal	September 2001
BiFeO ₃ epitaxial thin films and devices: past, present and future Sando, D.; Barthélémy, A.; Bibes, M. Journal of Physics: Condensed Matter, Vol. 26, Issue 47 https://doi.org/10.1088/0953-8984/26/47/473201	journal	October 2014
On thermoelectric and pyroelectric energy harvesting Sebald, Gael; Guyomar, Daniel; Agbossou, Amen Smart Materials and Structures, Vol. 18, Issue 12 https://doi.org/10.1088/0964-1726/18/12/125006	journal	September 2009
Pressure and Temperature Dependences of the Dielectric Properties of the Perovskites BaTi O 3 and SrTi O 3 Samara, G. A. Physical Review, Vol. 151, Issue 2 https://doi.org/10.1103/physrev.151.378	journal	November 1966
Dielectric, Thermal, and Pyroelectric Properties of Ferroelectric LiTa O 3 Glass, A. M. Physical Review, Vol. 172, Issue 2 https://doi.org/10.1103/physrev.172.564	journal	August 1968
Direct Measurement of Pyroelectric and Electrocaloric Effects in Thin Films Pandya, Shishir; Wilbur, Joshua D.; Bhatia, Bikram Physical Review Applied, Vol. 7, Issue 3 https://doi.org/10.1103/physrevapplied.7.034025	journal	March 2017
Large built-in electric fields due to flexoelectricity in compositionally graded ferroelectric thin films Karthik, J.; Mangalam, R. V. K.; Agar, J. C. Physical Review B, Vol. 87, Issue 2 https://doi.org/10.1103/physrevb.87.024111	journal	January 2013
Bridging Multiferroic Phase Transitions by Epitaxial Strain in BiFeO 3 Infante, I. C.; Lisenkov, S.; Dupé, B. Physical Review Letters, Vol. 105, Issue 5 https://doi.org/10.1103/physrevlett.105.057601	journal	July 2010
Effect of 90° Domain Walls and Thermal Expansion Mismatch on the Pyroelectric Properties of Epitaxial PbZr 0.2 Ti 0.8 O 3 Thin Films Karthik, J.; Agar, J. C.; Damodaran, A. R. Physical Review Letters, Vol. 109, Issue 25 https://doi.org/10.1103/physrevlett.109.257602	journal	December 2012
Pyroelectric and electrocaloric effects in ferroelectric silicon-doped hafnium oxide thin films Pandya, Shishir; Velarde, Gabriel; Zhang, Lei Physical Review Materials, Vol. 2, Issue 12 https://doi.org/10.1103/physrevmaterials.2.124405	journal	December 2018
The Pyroelectric Properties of the Lanthanum-Doped Ferroelectric PLZT Ceramics Liu, S. T.; Heaps, J. D.; Tufte, O. N. IEEE Transactions on Sonics and Ultrasonics, Vol. 19, Issue 2 https://doi.org/10.1109/t-su.1972.29672	journal	April 1972
Composition-driven structural phase transitions in rare-earth-doped bifeo₃ ceramics: a review Arnold, Donna IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control, Vol. 62, Issue 1 https://doi.org/10.1109/tuffc.2014.006668	journal	January 2015
Studies of Rare-Earth-Doped BiFeO3 Ceramics: Rare-Earth-Doped BiFeO3 Ceramics Yao, Yingbang; Liu, Wenchao; Chan, Yukkwan International Journal of Applied Ceramic Technology, Vol. 8, Issue 5 https://doi.org/10.1111/j.1744-7402.2010.02577.x	journal	September 2011
Enhancing ferroelectric photovoltaic effect by polar order engineering You, Lu; Zheng, Fan; Fang, Liang Science Advances, Vol. 4, Issue 7 https://doi.org/10.1126/sciadv.aat3438	journal	July 2018
Pyroelectric properties of bismuth ferrite in the low-temperature range Shaldin, Yu. V.; Matyjasik, S.; Bush, A. A. Crystallography Reports, Vol. 52, Issue 1 https://doi.org/10.1134/s1063774507010142	journal	February 2007
Next-generation electrocaloric and pyroelectric materials for solid-state electrothermal energy interconversion Alpay, S. Pamir; Mantese, Joseph; Trolier-McKinstry, Susan MRS Bulletin, Vol. 39, Issue 12 https://doi.org/10.1557/mrs.2014.256	journal	December 2014
Combinatorial discovery of a lead-free morphotropic phase boundary in a thin-film piezoelectric perovskite Fujino, S.; Murakami, M.; Varatharajan, A. arXiv https://doi.org/10.48550/arxiv.0803.0042	text	January 2008

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