Core–shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO 2

Das, Sonali; Pérez-Ramírez, Javier; Gong, Jinlong; Dewangan, Nikita; Hidajat, Kus; Gates, Bruce C.; Kawi, Sibudjing

doi:10.1039/C9CS00713J

Title: Core–shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO ₂

Journal Article · Tue May 26 00:00:00 EDT 2020 · Chemical Society Reviews

DOI:https://doi.org/10.1039/C9CS00713J· OSTI ID:1618782

^[1];

^[2];

^[3]; Dewangan, Nikita ^[1]; Hidajat, Kus ^[1];

^[4];

^[1]

Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore
Department of Chemical and Biomolecular Engineering, National University of Singapore, Singapore, Institute of Chemical and Bioengineering, Department of Chemistry and Applied Biosciences
Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering & Technology, Collaborative Innovation Center for Chemical Science & Engineering, Tianjin University, Tianjin
Department of Chemical Engineering, University of California, Davis, USA

Catalytic conversion of CO₂ to produce fuels and chemicals is attractive in prospect because it provides an alternative to fossil feedstocks and the benefit of converting and cycling the greenhouse gas CO₂ on a large scale. In today's technology, CO₂ is converted into hydrocarbon fuels in Fischer–Tropsch synthesis via the water gas shift reaction, but processes for direct conversion of CO₂ to fuels and chemicals such as methane, methanol, and C₂₊ hydrocarbons or syngas are still far from large-scale applications because of processing challenges that may be best addressed by the discovery of improved catalysts—those with enhanced activity, selectivity, and stability. Core–shell structured catalysts are a relatively new class of nanomaterials that allow a controlled integration of the functions of complementary materials with optimised compositions and morphologies. For CO₂ conversion, core–shell catalysts can provide distinctive advantages by addressing challenges such as catalyst sintering and activity loss in CO₂ reforming processes, insufficient product selectivity in thermocatalytic CO₂ hydrogenation, and low efficiency and selectivity in photocatalytic and electrocatalytic CO₂ hydrogenation. In the preceding decade, substantial progress has been made in the synthesis, characterization, and evaluation of core–shell catalysts for such potential applications. Nonetheless, challenges remain in the discovery of inexpensive, robust, regenerable catalysts in this class. This review provides an in-depth assessment of these materials for the thermocatalytic, photocatalytic, and electrocatalytic conversion of CO₂ into synthesis gas and valuable hydrocarbons.

View Journal Article

Cite

Export

Save

Research Organization:: Univ. of California, Davis, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-04ER15513

OSTI ID:: 1618782

Alternate ID(s):: OSTI ID: 1800146

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews Vol. 49 Journal Issue: 10; ISSN 0306-0012

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

Citation Metrics:

Cited by: 276 works

Citation information provided by
Web of Science

References (351)

A single Au nanoparticle anchored inside the porous shell of periodic mesoporous organosilica hollow spheres Yang, Ying; Zhang, Wen; Zhang, Ying Nano Research, Vol. 8, Issue 10 https://doi.org/10.1007/s12274-015-0840-9	journal	September 2015
Magnetic Hollow Spheres Assembled from Graphene-Encapsulated Nickel Nanoparticles for Efficient Photocatalytic CO ₂ Reduction Lin, Xiahui; Wang, Sibo; Tu, Wenguang ACS Applied Energy Materials, Vol. 2, Issue 10 https://doi.org/10.1021/acsaem.9b01673	journal	September 2019
SAPO-34 zeolite encapsulated Fe3C nanoparticles as highly selective Fischer-Tropsch catalysts for the production of light olefins Qiu, Tao; Wang, Li; Lv, Shuai Fuel, Vol. 203 https://doi.org/10.1016/j.fuel.2017.05.043	journal	September 2017
Facile Synthesis of Multi-shelled ZnS-CdS Cages with Enhanced Photoelectrochemical Performance for Solar Energy Conversion Zhang, Peng; Guan, Bu Yuan; Yu, Le Chem, Vol. 4, Issue 1 https://doi.org/10.1016/j.chempr.2017.10.018	journal	January 2018
Catalytic Activity and Product Selectivity Trends for Carbon Dioxide Electroreduction on Transition Metal-Coated Tungsten Carbides Wannakao, Sippakorn; Artrith, Nongnuch; Limtrakul, Jumras The Journal of Physical Chemistry C, Vol. 121, Issue 37 https://doi.org/10.1021/acs.jpcc.7b05741	journal	September 2017
Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO ₂ Hydrogenation Processes Álvarez, Andrea; Bansode, Atul; Urakawa, Atsushi Chemical Reviews, Vol. 117, Issue 14 https://doi.org/10.1021/acs.chemrev.6b00816	journal	May 2017
Highly active and stable nano NiO–MgO catalyst encapsulated by silica with a core–shell structure for CO ₂ methanation Li, Yanrong; Lu, Gongxuan; Ma, Jiantai RSC Adv., Vol. 4, Issue 34 https://doi.org/10.1039/C3RA46569A	journal	January 2014
Self-templated formation of ZnFe ₂ O ₄ double-shelled hollow microspheres for photocatalytic degradation of gaseous o-dichlorobenzene Liu, Baojun; Li, Xinyong; Zhao, Qidong Journal of Materials Chemistry A, Vol. 5, Issue 19 https://doi.org/10.1039/C7TA02048A	journal	January 2017
Electronic factors determining the reactivity of metal surfaces Hammer, B.; Nørskov, J. K. Surface Science, Vol. 343, Issue 3 https://doi.org/10.1016/0039-6028(96)80007-0	journal	December 1995
Efficient Reduction of CO ₂ to CO Using Cobalt-Cobalt Oxide Core-Shell Catalysts Yin, Guoheng; Yuan, Xiaotao; Du, Xianlong Chemistry - A European Journal, Vol. 24, Issue 9 https://doi.org/10.1002/chem.201704596	journal	January 2018
Highly Active and Stable Pt-Loaded Ce _0.75 Zr _0.25 O ₂ Yolk–Shell Catalyst for Water–Gas Shift Reaction Shim, Jae-Oh; Hong, Young Jun; Na, Hyun-Suk ACS Applied Materials & Interfaces, Vol. 8, Issue 27 https://doi.org/10.1021/acsami.6b03915	journal	June 2016
Towards sustainable fuels and chemicals through the electrochemical reduction of CO ₂ : lessons from water electrolysis Martín, Antonio J.; Larrazábal, Gastón O.; Pérez-Ramírez, Javier Green Chemistry, Vol. 17, Issue 12 https://doi.org/10.1039/C5GC01893E	journal	January 2015
Robust Multimetallic Plasmonic Core–Satellite Nanodendrites: Highly Effective Visible-Light-Induced Colloidal CO ₂ Photoconversion System Kumar, Dinesh; Park, Chan Hee; Kim, Cheol Sang ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 7 https://doi.org/10.1021/acssuschemeng.8b00924	journal	May 2018
Au@TiO2 yolk-shell nanostructures for enhanced performance in both photoelectric and photocatalytic solar conversion He, Qinrong; Sun, Hang; Shang, Yinxing Applied Surface Science, Vol. 441 https://doi.org/10.1016/j.apsusc.2018.02.062	journal	May 2018
Hierarchical NiCo2O4 hollow nanocages for photoreduction of diluted CO2: Adsorption and active sites engineering Han, Bin; Song, Jianing; Liang, Shujie Applied Catalysis B: Environmental, Vol. 260 https://doi.org/10.1016/j.apcatb.2019.118208	journal	January 2020
Methanation of Carbon Dioxide over Zeolite-Encapsulated Nickel Nanoparticles Goodarzi, Farnoosh; Kang, Liqun; Wang, Feng Ryan ChemCatChem, Vol. 10, Issue 7 https://doi.org/10.1002/cctc.201701946	journal	February 2018
Progress in Synthesis of Highly Active and Stable Nickel-Based Catalysts for Carbon Dioxide Reforming of Methane Kawi, Sibudjing; Kathiraser, Yasotha; Ni, Jun ChemSusChem, Vol. 8, Issue 21 https://doi.org/10.1002/cssc.201500390	journal	October 2015
Rational design of yolk–shell nanostructures for photocatalysis Li, Ang; Zhu, Wenjin; Li, Chengcheng Chemical Society Reviews, Vol. 48, Issue 7 https://doi.org/10.1039/C8CS00711J	journal	January 2019
Hetero-nanostructured suspended photocatalysts for solar-to-fuel conversion Yuan, Yu-Peng; Ruan, Lin-Wei; Barber, James Energy Environ. Sci., Vol. 7, Issue 12 https://doi.org/10.1039/C4EE02914C	journal	January 2014
Product Selectivity Controlled by Nanoporous Environments in Zeolite Crystals Enveloping Rhodium Nanoparticle Catalysts for CO ₂ Hydrogenation Wang, Chengtao; Guan, Erjia; Wang, Liang Journal of the American Chemical Society, Vol. 141, Issue 21 https://doi.org/10.1021/jacs.9b01555	journal	May 2019
Raspberry‐Like Microspheres of Core–Shell Cr ₂ O ₃ @TiO ₂ Nanoparticles for CO ₂ Photoreduction Tan, Jeannie Z. Y.; Xia, Fang; Maroto‐Valer, M. Mercedes ChemSusChem, Vol. 12, Issue 24 https://doi.org/10.1002/cssc.201901712	journal	October 2019
Sandwich-Like Silica@Ni@Silica Multicore-Shell Catalyst for the Low-Temperature Dry Reforming of Methane: Confinement Effect Against Carbon Formation Bian, Zhoufeng; Kawi, Sibudjing ChemCatChem, Vol. 10, Issue 1 https://doi.org/10.1002/cctc.201701024	journal	December 2017
Sulfur-Modified Copper Catalysts for the Electrochemical Reduction of Carbon Dioxide to Formate Shinagawa, Tatsuya; Larrazábal, Gastón O.; Martín, Antonio J. ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03161	journal	January 2018
Thermal and Hydrothermal Stability of Hierarchical Porous Silica Materials: Thermal and Hydrothermal Stability of Hierarchical Porous Silica Materials Blin, Jean-Luc; Riachy, Philippe; Carteret, Cédric European Journal of Inorganic Chemistry, Vol. 2019, Issue 27 https://doi.org/10.1002/ejic.201900228	journal	May 2019
Design and Modification of Zeolite Capsule Catalyst, A Confined Reaction Field, and its Application in One-Step Isoparaffin Synthesis from Syngas Yang, Guohui; He, Jingjiang; Zhang, Yi Energy & Fuels, Vol. 22, Issue 3 https://doi.org/10.1021/ef700682y	journal	May 2008
Ag–Sn Bimetallic Catalyst with a Core–Shell Structure for CO ₂ Reduction Luc, Wesley; Collins, Charles; Wang, Siwen Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b10435	journal	January 2017
Tuning Sn-Catalysis for Electrochemical Reduction of CO ₂ to CO via the Core/Shell Cu/SnO ₂ Structure Li, Qing; Fu, Jiaju; Zhu, Wenlei Journal of the American Chemical Society, Vol. 139, Issue 12 https://doi.org/10.1021/jacs.7b00261	journal	March 2017
Designing a Capsule Catalyst and Its Application for Direct Synthesis of Middle Isoparaffins He, Jingjiang; Yoneyama, Yoshiharu; Xu, Bolian Langmuir, Vol. 21, Issue 5 https://doi.org/10.1021/la047217h	journal	March 2005
Recent advances in micro-/nano-structured hollow spheres for energy applications: From simple to complex systems Lai, Xiaoyong; Halpert, Jonathan E.; Wang, Dan Energy Environ. Sci., Vol. 5, Issue 2 https://doi.org/10.1039/C1EE02426D	journal	January 2012
Selective electrochemical reduction of CO ₂ to different alcohol products by an organically doped alloy catalyst Yang, Heng-Pan; Yue, Ying-Na; Qin, Sen Green Chemistry, Vol. 18, Issue 11 https://doi.org/10.1039/C6GC00091F	journal	January 2016
Au/Pt Nanoparticle-Decorated TiO ₂ Nanofibers with Plasmon-Enhanced Photocatalytic Activities for Solar-to-Fuel Conversion Zhang, Zhenyi; Wang, Zheng; Cao, Shao-Wen The Journal of Physical Chemistry C, Vol. 117, Issue 49 https://doi.org/10.1021/jp409311x	journal	November 2013
Sandwiched SiO2@Ni@ZrO2 as a coke resistant nanocatalyst for dry reforming of methane Dou, Jian; Zhang, Riguang; Hao, Xiaobin Applied Catalysis B: Environmental, Vol. 254 https://doi.org/10.1016/j.apcatb.2019.05.021	journal	October 2019
Mechanisms and kinetics of CO 2 hydrogenation to value-added products: A detailed review on current status and future trends Saeidi, Samrand; Najari, Sara; Fazlollahi, Farhad Renewable and Sustainable Energy Reviews, Vol. 80 https://doi.org/10.1016/j.rser.2017.05.204	journal	December 2017
State of the art and perspectives in catalytic processes for CO2 conversion into chemicals and fuels: The distinctive contribution of chemical catalysis and biotechnology Aresta, Michele; Dibenedetto, Angela; Quaranta, Eugenio Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2016.04.003	journal	November 2016
Fischer-Tropsch synthesis over methyl modified Fe2O3@SiO2 catalysts with low CO2 selectivity Yu, Xufei; Zhang, Jianli; Wang, Xu Applied Catalysis B: Environmental, Vol. 232 https://doi.org/10.1016/j.apcatb.2018.03.048	journal	September 2018
Ordered bilayer ruthenium–platinum core-shell nanoparticles as carbon monoxide-tolerant fuel cell catalysts Hsieh, Yu-Chi; Zhang, Yu; Su, Dong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3466	journal	September 2013
A short review of recent advances in CO 2 hydrogenation to hydrocarbons over heterogeneous catalysts Li, Wenhui; Wang, Haozhi; Jiang, Xiao RSC Advances, Vol. 8, Issue 14 https://doi.org/10.1039/C7RA13546G	journal	January 2018
Synthesis and multiple reuse of eccentric Au@TiO2 nanostructures as catalysts Seh, Zhi Wei; Liu, Shuhua; Zhang, Shuang-Yuan Chemical Communications, Vol. 47, Issue 23 https://doi.org/10.1039/c1cc11729g	journal	January 2011
Confinement of Ultrasmall Cu/ZnO _x Nanoparticles in Metal–Organic Frameworks for Selective Methanol Synthesis from Catalytic Hydrogenation of CO ₂ An, Bing; Zhang, Jingzheng; Cheng, Kang Journal of the American Chemical Society, Vol. 139, Issue 10 https://doi.org/10.1021/jacs.7b00058	journal	March 2017
Effects of Fe partial substitution of La 2 NiO 4 /LaNiO 3 catalyst precursors prepared by wet impregnation method for the dry reforming of methane Song, Xiao; Dong, Xiaolei; Yin, Shiliu Applied Catalysis A: General, Vol. 526 https://doi.org/10.1016/j.apcata.2016.07.024	journal	September 2016
Spherical Sandwich Au@Pd@UIO-67/Pt@UIO- n ( n = 66, 67, 69) Core–Shell Catalysts: Zr-Based Metal–Organic Frameworks for Effectively Regulating the Reverse Water–Gas Shift Reaction Xu, Haitao; Luo, Xikuo; Wang, Jiajia ACS Applied Materials & Interfaces, Vol. 11, Issue 22 https://doi.org/10.1021/acsami.9b04748	journal	May 2019
Alumina coated nickel nanoparticles as a highly active catalyst for dry reforming of methane Baktash, Elham; Littlewood, Patrick; Schomäcker, Reinhard Applied Catalysis B: Environmental, Vol. 179 https://doi.org/10.1016/j.apcatb.2015.05.018	journal	December 2015
Efficient Conversion of CO ₂ to Methane Photocatalyzed by Conductive Black Titania Yin, Guoheng; Bi, Qingyuan; Zhao, Wei ChemCatChem, Vol. 9, Issue 23 https://doi.org/10.1002/cctc.201701130	journal	November 2017
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al ₂ O ₃ Catalysts Induced by Strong Metal-Support Interactions Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte Angewandte Chemie International Edition, Vol. 54, Issue 15 https://doi.org/10.1002/anie.201411581	journal	February 2015
Noble metal–metal oxide nanohybrids with tailored nanostructures for efficient solar energy conversion, photocatalysis and environmental remediation Liu, Xueqin; Iocozzia, James; Wang, Yang Energy & Environmental Science, Vol. 10, Issue 2 https://doi.org/10.1039/C6EE02265K	journal	January 2017
Tunable Cu Enrichment Enables Designer Syngas Electrosynthesis from CO ₂ Ross, Michael B.; Dinh, Cao Thang; Li, Yifan Journal of the American Chemical Society, Vol. 139, Issue 27 https://doi.org/10.1021/jacs.7b04892	journal	June 2017
Construction of ZnIn ₂ S ₄ –In ₂ O ₃ Hierarchical Tubular Heterostructures for Efficient CO ₂ Photoreduction Wang, Sibo; Guan, Bu Yuan; Lou, Xiong Wen David Journal of the American Chemical Society, Vol. 140, Issue 15 https://doi.org/10.1021/jacs.8b02200	journal	March 2018
Hydrocarbon steam reforming using Silicalite-1 zeolite encapsulated Ni-based catalyst Cimenler, Ummuhan; Joseph, Babu; Kuhn, John N. AIChE Journal, Vol. 63, Issue 1 https://doi.org/10.1002/aic.15521	journal	October 2016
Low Overpotential for Electrochemically Reducing CO ₂ to CO on Nitrogen-Doped Graphene Quantum Dots-Wrapped Single-Crystalline Gold Nanoparticles Fu, Jiaju; Wang, Yu; Liu, Juan ACS Energy Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsenergylett.8b00261	journal	March 2018
Design of spatially separated Au and CoO dual cocatalysts on hollow TiO2 for enhanced photocatalytic activity towards the reduction of CO2 to CH4 Zhu, Shuying; Liao, Wanru; Zhang, Mingyi Chemical Engineering Journal, Vol. 361 https://doi.org/10.1016/j.cej.2018.12.095	journal	April 2019
Porosity effect on ZrO ₂ hollow shells and hydrothermal stability for catalytic steam reforming of methane Lim, Zi-Yian; Wu, Chunzheng; Wang, Wei Guo Journal of Materials Chemistry A, Vol. 4, Issue 1 https://doi.org/10.1039/C5TA07015E	journal	January 2016
Enhanced visible light responsive MWCNT/TiO2 core–shell nanocomposites as the potential photocatalyst for reduction of CO2 into methane Gui, Meei Mei; Chai, Siang-Piao; Xu, Bo-Qing Solar Energy Materials and Solar Cells, Vol. 122 https://doi.org/10.1016/j.solmat.2013.11.034	journal	March 2014
The effect of lattice strain on catalytic activity Westsson, Emma; Picken, Stephen; Koper, Ger Chemical Communications, Vol. 55, Issue 9 https://doi.org/10.1039/C8CC09063G	journal	January 2019
Complete encapsulation of zeolite supported Co based core with silicalite-1 shell to achieve high gasoline selectivity in Fischer-Tropsch synthesis Javed, Mudassar; Cheng, Shilin; Zhang, Guihua Fuel, Vol. 215 https://doi.org/10.1016/j.fuel.2017.10.042	journal	March 2018
New insights into working nanostructured electrocatalysts through operando spectroscopy and microscopy Choi, Y. -W.; Mistry, H.; Roldan Cuenya, B. Current Opinion in Electrochemistry, Vol. 1, Issue 1 https://doi.org/10.1016/j.coelec.2017.01.004	journal	February 2017
High Carbon-Resistance Ni@CeO2 Core–Shell Catalysts for Dry Reforming of Methane Tang, Chengli; Liping, Lv; Zhang, Limei Kinetics and Catalysis, Vol. 58, Issue 6 https://doi.org/10.1134/S0023158418010123	journal	November 2017
Bimetallic Surface Chemistry Campbell, C. T. Annual Review of Physical Chemistry, Vol. 41, Issue 1 https://doi.org/10.1146/annurev.pc.41.100190.004015	journal	October 1990
Highly Coke-Resistant Ni Nanoparticle Catalysts with Minimal Sintering in Dry Reforming of Methane Han, Joung Woo; Kim, Chanyeon; Park, Jun Seong ChemSusChem, Vol. 7, Issue 2 https://doi.org/10.1002/cssc.201301134	journal	January 2014
In Situ Grown Monolayer N‐Doped Graphene on CdS Hollow Spheres with Seamless Contact for Photocatalytic CO ₂ Reduction Bie, Chuanbiao; Zhu, Bicheng; Xu, Feiyan Advanced Materials, Vol. 31, Issue 42 https://doi.org/10.1002/adma.201902868	journal	September 2019
Homogeneously Catalyzed Electroreduction of Carbon Dioxide—Methods, Mechanisms, and Catalysts Francke, Robert; Schille, Benjamin; Roemelt, Michael Chemical Reviews, Vol. 118, Issue 9 https://doi.org/10.1021/acs.chemrev.7b00459	journal	January 2018
Unexpectedly efficient CO2 hydrogenation to higher hydrocarbons over non-doped Fe2O3 Albrecht, Matthias; Rodemerck, Uwe; Schneider, Matthias Applied Catalysis B: Environmental, Vol. 204 https://doi.org/10.1016/j.apcatb.2016.11.017	journal	May 2017
Core-shell Ni/NiO grafted cobalt (II) complex: An efficient inorganic nanocomposite for photocatalytic reduction of CO2 under visible light irradiation Prajapati, Pankaj K.; Singh, Hari; Yadav, Rajkumar Applied Surface Science, Vol. 467-468 https://doi.org/10.1016/j.apsusc.2018.10.159	journal	February 2019
Core-shell LaPO4/g-C3N4 nanowires for highly active and selective CO2 reduction Li, Mengli; Zhang, Lingxia; Fan, Xiangqian Applied Catalysis B: Environmental, Vol. 201 https://doi.org/10.1016/j.apcatb.2016.09.004	journal	February 2017
Yolk-shell structured Pt-CeO 2 @Ni-SiO 2 as an efficient catalyst for enhanced hydrogen production from ethanol steam reforming Sun, Chen; Zheng, Ziliang; Wang, Shiyao Ceramics International, Vol. 44, Issue 2 https://doi.org/10.1016/j.ceramint.2017.09.248	journal	February 2018
Anchoring ultrafine metallic and oxidized Pt nanoclusters on yolk-shell TiO 2 for unprecedentedly high photocatalytic hydrogen production Jin, Jun; Wang, Chao; Ren, Xiao-Ning Nano Energy, Vol. 38 https://doi.org/10.1016/j.nanoen.2017.05.025	journal	August 2017
Bimetallic Pd–Cu catalysts for selective CO2 hydrogenation to methanol Jiang, Xiao; Koizumi, Naoto; Guo, Xinwen Applied Catalysis B: Environmental, Vol. 170-171 https://doi.org/10.1016/j.apcatb.2015.01.010	journal	July 2015
CO ₂ conversion to synthesis gas via DRM on the durable Al ₂ O ₃ /Ni/Al ₂ O ₃ sandwich catalyst with high activity and stability Zhao, Yu; Kang, Yunqing; Li, Hui Green Chemistry, Vol. 20, Issue 12 https://doi.org/10.1039/C8GC00743H	journal	January 2018
Spatial Confinement Effects of Microcapsule Catalyst for Improved Coking‐ and Sintering‐Resistant Behaviors Toward CO ₂ Reforming of Methane Reaction Han, Bing; Amoo, Cederick Cyril; Zhang, Guihua Energy Technology, Vol. 7, Issue 4 https://doi.org/10.1002/ente.201801033	journal	March 2019
Facile One-Pot Synthesis of Pd@Pt _1L Octahedra with Enhanced Activity and Durability toward Oxygen Reduction Zhou, Ming; Wang, Helan; Elnabawy, Ahmed O. Chemistry of Materials, Vol. 31, Issue 4 https://doi.org/10.1021/acs.chemmater.8b04756	journal	January 2019
Progression of Photocatalytic reactors and it’s comparison: A Review Sundar, Kaviya Piriyah; Kanmani, S. Chemical Engineering Research and Design, Vol. 154 https://doi.org/10.1016/j.cherd.2019.11.035	journal	February 2020
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
High sintering-/coke-resistance Ni@SiO ₂ /Al ₂ O ₃ /FeCrAl-fiber catalyst for dry reforming of methane: one-step, macro-to-nano organization via cross-linking molecules Chai, Ruijuan; Zhao, Guofeng; Zhang, Zhiqiang Catalysis Science & Technology, Vol. 7, Issue 23 https://doi.org/10.1039/C7CY01491K	journal	January 2017
Pd-Containing Nanostructures for Electrochemical CO ₂ Reduction Reaction Gao, Dunfeng; Zhou, Hu; Cai, Fan ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03612	journal	January 2018
A Review on Bimetallic Nickel-Based Catalysts for CO ₂ Reforming of Methane Bian, Zhoufeng; Das, Sonali; Wai, Ming Hui ChemPhysChem, Vol. 18, Issue 22 https://doi.org/10.1002/cphc.201700529	journal	August 2017
Catalysis for CO2 conversion: a key technology for rapid introduction of renewable energy in the value chain of chemical industries Centi, Gabriele; Quadrelli, Elsje Alessandra; Perathoner, Siglinda Energy & Environmental Science, Vol. 6, Issue 6 https://doi.org/10.1039/c3ee00056g	journal	January 2013
Porous TiO ₂ Nanotubes with Spatially Separated Platinum and CoO _x Cocatalysts Produced by Atomic Layer Deposition for Photocatalytic Hydrogen Production Zhang, Jiankang; Yu, Zhuobin; Gao, Zhe Angewandte Chemie International Edition, Vol. 56, Issue 3 https://doi.org/10.1002/anie.201611137	journal	December 2016
Recent Advances on the Design of Group VIII Base-Metal Catalysts with Encapsulated Structures Tian, Hao; Li, Xinyu; Zeng, Liang ACS Catalysis, Vol. 5, Issue 8 https://doi.org/10.1021/acscatal.5b01221	journal	July 2015
Ultrathin Co ₃ O ₄ Layers Realizing Optimized CO ₂ Electroreduction to Formate Gao, Shan; Jiao, Xingchen; Sun, Zhongti Angewandte Chemie International Edition, Vol. 55, Issue 2 https://doi.org/10.1002/anie.201509800	journal	November 2015
Core/Shell Nanocomposites Produced by Superfast Sequential Microfluidic Nanoprecipitation Liu, Dongfei; Zhang, Hongbo; Cito, Salvatore Nano Letters, Vol. 17, Issue 2 https://doi.org/10.1021/acs.nanolett.6b03251	journal	January 2017
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Qiao, Jinli; Liu, Yuyu; Hong, Feng Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60323G	journal	January 2014
Photocatalytic CO2 reduction using an internally illuminated monolith photoreactor Liou, Pei-Yin; Chen, Shang-Chien; Wu, Jeffrey C. S. Energy & Environmental Science, Vol. 4, Issue 4 https://doi.org/10.1039/c0ee00609b	journal	January 2011
Microfluidic synthesis of Ag@Cu2O core-shell nanoparticles with enhanced photocatalytic activity Tao, Sha; Yang, Mei; Chen, Huihui Journal of Colloid and Interface Science, Vol. 486 https://doi.org/10.1016/j.jcis.2016.09.051	journal	January 2017
Tailored synthesis of mesoporous TiO2 hollow nanostructures for catalytic applications Joo, Ji Bong; Dahl, Michael; Li, Na Energy & Environmental Science, Vol. 6, Issue 7 https://doi.org/10.1039/c3ee41155a	journal	January 2013
CO ₂ photo-reduction: insights into CO ₂ activation and reaction on surfaces of photocatalysts Chang, Xiaoxia; Wang, Tuo; Gong, Jinlong Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE00383D	journal	January 2016
Silica-coated LaNiO3 nanoparticles for non-thermal plasma assisted dry reforming of methane: Experimental and kinetic studies Zheng, Xiaogang; Tan, Shiyu; Dong, Lichun Chemical Engineering Journal, Vol. 265 https://doi.org/10.1016/j.cej.2014.12.035	journal	April 2015
Sintering and coking resistant core–shell microporous silica–nickel nanoparticles for CO methanation: Towards advanced catalysts production Lucchini, Mattia A.; Testino, Andrea; Kambolis, Anastasios Applied Catalysis B: Environmental, Vol. 182 https://doi.org/10.1016/j.apcatb.2015.09.012	journal	March 2016
The stability of Cu/ZnO-based catalysts in methanol synthesis from a CO2-rich feed and from a CO-rich feed Wu, Jingang; Saito, Masahiro; Takeuchi, Masami Applied Catalysis A: General, Vol. 218, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)00650-0	journal	September 2001
Hollow ZSM-5 with Silicon-Rich Surface, Double Shells, and Functionalized Interior with Metallic Nanoparticles and Carbon Nanotubes Dai, Chengyi; Zhang, Anfeng; Liu, Min Advanced Functional Materials, Vol. 25, Issue 48 https://doi.org/10.1002/adfm.201502980	journal	November 2015
Computational screening of M/Cu core/shell nanoparticles and their applications for the electro-chemical reduction of CO ₂ and CO Dong, Huilong; Liu, Cheng; Li, Youyong Nanoscale, Vol. 11, Issue 23 https://doi.org/10.1039/C9NR01936G	journal	January 2019
Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839 https://doi.org/10.1016/0013-4686(94)85172-7	journal	August 1994
Hollow Multi-Shelled Structures of Co ₃ O ₄ Dodecahedron with Unique Crystal Orientation for Enhanced Photocatalytic CO ₂ Reduction Wang, Li; Wan, Jiawei; Zhao, Yasong Journal of the American Chemical Society, Vol. 141, Issue 6 https://doi.org/10.1021/jacs.8b13528	journal	January 2019
Coke-resistant Ni@SiO2 catalyst for dry reforming of methane Zhang, Junshe; Li, Fanxing Applied Catalysis B: Environmental, Vol. 176-177 https://doi.org/10.1016/j.apcatb.2015.04.039	journal	October 2015
A multifunctional platform by controlling of carbon nitride in the core-shell structure: From design to construction, and catalysis applications He, Donghui; Zhang, Chen; Zeng, Guangming Applied Catalysis B: Environmental, Vol. 258 https://doi.org/10.1016/j.apcatb.2019.117957	journal	December 2019
Double-cocatalysts promote charge separation efficiency in CO ₂ photoreduction: spatial location matters Dong, Chunyang; Xing, Mingyang; Zhang, Jinlong Materials Horizons, Vol. 3, Issue 6 https://doi.org/10.1039/C6MH00210B	journal	January 2016
Tuning Selectivity of CO ₂ Hydrogenation Reactions at the Metal/Oxide Interface Kattel, Shyam; Liu, Ping; Chen, Jingguang G. Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b05362	journal	July 2017
Stepwise tuning of metal-oxide and acid sites of CuZnZr-MFI hybrid catalysts for the direct DME synthesis by CO2 hydrogenation Frusteri, F.; Bonura, G.; Cannilla, C. Applied Catalysis B: Environmental, Vol. 176-177 https://doi.org/10.1016/j.apcatb.2015.04.032	journal	October 2015
Stabilization and compressive strain effect of AuCu core on Pt shell for oxygen reduction reaction Yang, Jinhua; Chen, Xiaojun; Yang, Xianfeng Energy & Environmental Science, Vol. 5, Issue 10 https://doi.org/10.1039/c2ee22172a	journal	January 2012
Copper and iodine co-modified TiO2 nanoparticles for improved activity of CO2 photoreduction with water vapor Zhang, Qianyi; Gao, Tingting; Andino, Jean M. Applied Catalysis B: Environmental, Vol. 123-124 https://doi.org/10.1016/j.apcatb.2012.04.035	journal	July 2012
Hydrothermally stable heterogeneous catalysts for conversion of biorenewables Xiong, Haifeng; Pham, Hien N.; Datye, Abhaya K. Green Chem., Vol. 16, Issue 11 https://doi.org/10.1039/C4GC01152J	journal	January 2014
From Hollow Olive-Shaped BiVO ₄ to n−p Core−Shell BiVO ₄ @Bi ₂ O ₃ Microspheres: Controlled Synthesis and Enhanced Visible-Light-Responsive Photocatalytic Properties Guan, Mei-Li; Ma, De-Kun; Hu, Sheng-Wei Inorganic Chemistry, Vol. 50, Issue 3 https://doi.org/10.1021/ic101961z	journal	February 2011
Synthesis of a core–shell–shell structured acid–base bifunctional mesoporous silica nanoreactor (MS-SO3H@MS@MS-NH2) and its application in tandem catalysis Li, Ping; Cao, Chang-Yan; Liu, Hua Journal of Materials Chemistry A, Vol. 1, Issue 41 https://doi.org/10.1039/c3ta13185h	journal	January 2013
A highly selective Raney Fe@HZSM-5 Fischer–Tropsch synthesis catalyst for gasoline production: one-pot synthesis and unexpected effect of zeolites Sun, Bo; Yu, Guobin; Lin, Jun Catalysis Science & Technology, Vol. 2, Issue 8 https://doi.org/10.1039/c2cy20155k	journal	January 2012
Highly carbon resistant multicore-shell catalyst derived from Ni-Mg phyllosilicate nanotubes@silica for dry reforming of methane Bian, Zhoufeng; Suryawinata, Ivan Yulian; Kawi, Sibudjing Applied Catalysis B: Environmental, Vol. 195 https://doi.org/10.1016/j.apcatb.2016.05.001	journal	October 2016
Concentric Hollow Nanospheres of Mesoporous Silica Shell-Titania Core from Combined Inorganic and Polymer Syntheses Li, Guoliang; Kang, E. T.; Neoh, K. G. Langmuir, Vol. 25, Issue 8 https://doi.org/10.1021/la900756u	journal	April 2009
Rationally designed hierarchical N-doped carbon@NiCo ₂ O ₄ double-shelled nanoboxes for enhanced visible light CO ₂ reduction Wang, Sibo; Guan, Bu Yuan; Lou, Xiong Wen (David) Energy & Environmental Science, Vol. 11, Issue 2 https://doi.org/10.1039/C7EE02934A	journal	January 2018
CO2 reforming with methane reaction over Ni@SiO2 catalysts coupled by size effect and metal-support interaction Zhang, Linjia; Wang, Fagen; Zhu, Jiayin Fuel, Vol. 256 https://doi.org/10.1016/j.fuel.2019.115954	journal	November 2019
Sintering of Catalytic Nanoparticles: Particle Migration or Ostwald Ripening? Hansen, Thomas W.; DeLaRiva, Andrew T.; Challa, Sivakumar R. Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar3002427	journal	April 2013
Engineering Coexposed {001} and {101} Facets in Oxygen-Deficient TiO ₂ Nanocrystals for Enhanced CO ₂ Photoreduction under Visible Light Liu, Lianjun; Jiang, Yuqiu; Zhao, Huilei ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02098	journal	January 2016
Scale-Up Process of Core@Shell Monolayer Catalyst without Active Potential Control through Electroless Underpotential Deposition Galvanic Replacement Mahesh, Ijjada; Sarkar, A. ChemistrySelect, Vol. 3, Issue 41 https://doi.org/10.1002/slct.201801616	journal	November 2018
One-step synthesis of H–β zeolite-enwrapped Co/Al2O3 Fischer–Tropsch catalyst with high spatial selectivity Li, Xingang; He, Jingjiang; Meng, Ming Journal of Catalysis, Vol. 265, Issue 1 https://doi.org/10.1016/j.jcat.2009.04.009	journal	July 2009
CoZr/H-ZSM-5 hybrid catalysts for synthesis of gasoline-range isoparaffins from syngas Huang, Xing; Hou, Bo; Wang, Jungang Applied Catalysis A: General, Vol. 408, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.09.004	journal	November 2011
Shape-controlled fabrication of TiO 2 hollow shells toward photocatalytic application Eskandarloo, Hamed; Zaferani, Meisam; Kierulf, Arkaye Applied Catalysis B: Environmental, Vol. 227 https://doi.org/10.1016/j.apcatb.2018.01.059	journal	July 2018
Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO ₂ Hydrogenation Martin, Oliver; Martín, Antonio J.; Mondelli, Cecilia Angewandte Chemie International Edition, Vol. 55, Issue 21 https://doi.org/10.1002/anie.201600943	journal	March 2016
Engineering operando methodology: Understanding catalysis in time and space Portela, Raquel; Perez-Ferreras, Susana; Serrano-Lotina, Ana Frontiers of Chemical Science and Engineering, Vol. 12, Issue 3 https://doi.org/10.1007/s11705-018-1740-9	journal	September 2018
Recent Advances in Heterogeneous Photocatalytic CO ₂ Conversion to Solar Fuels Li, Kan; Peng, Bosi; Peng, Tianyou ACS Catalysis, Vol. 6, Issue 11 https://doi.org/10.1021/acscatal.6b02089	journal	October 2016
Building premium secondary reaction field with a miniaturized capsule catalyst to realize efficient synthesis of a liquid fuel directly from syngas Yamane, Noriyuki; Wang, Yang; Li, Jie Catalysis Science & Technology, Vol. 7, Issue 10 https://doi.org/10.1039/C7CY00224F	journal	January 2017
NiCo@NiCo phyllosilicate@CeO2 hollow core shell catalysts for steam reforming of toluene as biomass tar model compound Li, Ziwei; Li, Min; Ashok, Jangam Energy Conversion and Management, Vol. 180 https://doi.org/10.1016/j.enconman.2018.11.034	journal	January 2019
Facile Route for Synthesizing Ordered Mesoporous Ni–Ce–Al Oxide Materials and Their Catalytic Performance for Methane Dry Reforming to Hydrogen and Syngas Wang, Ning; Shen, Kui; Huang, Lihong ACS Catalysis, Vol. 3, Issue 7 https://doi.org/10.1021/cs4003113	journal	June 2013
Formation of Hierarchical In ₂ S ₃ –CdIn ₂ S ₄ Heterostructured Nanotubes for Efficient and Stable Visible Light CO ₂ Reduction Wang, Sibo; Guan, Bu Yuan; Lu, Yan Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b10733	journal	November 2017
Nanostructured Ru-Co@SiO 2 : Highly efficient yet durable for CO 2 reforming of methane with a desirable H 2 /CO ratio Pang, Yijun; Dou, Yixuan; Zhong, Aihua Applied Catalysis A: General, Vol. 555 https://doi.org/10.1016/j.apcata.2018.02.003	journal	April 2018
Nanoreactor of MOF-Derived Yolk–Shell Co@C–N: Precisely Controllable Structure and Enhanced Catalytic Activity Chen, Huirong; Shen, Kui; Mao, Qing ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03270	journal	January 2018
Facile one-pot synthesis of Ni@HSS as a novel yolk-shell structure catalyst for dry reforming of methane Lu, Yao; Guo, Dan; Ruan, Yongzhe Journal of CO2 Utilization, Vol. 24 https://doi.org/10.1016/j.jcou.2018.01.003	journal	March 2018
Active and durable alkaline earth metal substituted perovskite catalysts for dry reforming of methane Dama, Srikanth; Ghodke, Seema R.; Bobade, Richa Applied Catalysis B: Environmental, Vol. 224 https://doi.org/10.1016/j.apcatb.2017.10.048	journal	May 2018
Photon upconversion based on sensitized triplet–triplet annihilation Singh-Rachford, Tanya N.; Castellano, Felix N. Coordination Chemistry Reviews, Vol. 254, Issue 21-22 https://doi.org/10.1016/j.ccr.2010.01.003	journal	November 2010
Organic functionalization of metal catalysts: Enhanced activity towards electroreduction of carbon dioxide Wang, Jigang; Zhang, Fengqi; Kang, Xiongwu Current Opinion in Electrochemistry, Vol. 13 https://doi.org/10.1016/j.coelec.2018.10.010	journal	February 2019
Rational Design of a Hierarchical Tin Dendrite Electrode for Efficient Electrochemical Reduction of CO ₂ Won, Da Hye; Choi, Chang Hyuck; Chung, Jaehoon ChemSusChem, Vol. 8, Issue 18 https://doi.org/10.1002/cssc.201500694	journal	July 2015
ZnO Hollow Spheres with Double-Yolk Egg Structure for High-Performance Photocatalysts and Photodetectors Wang, Xi; Liao, Meiyong; Zhong, Yeteng Advanced Materials, Vol. 24, Issue 25 https://doi.org/10.1002/adma.201201139	journal	June 2012
Core–shell structured Cu@m-SiO 2 and Cu/ZnO@m-SiO 2 catalysts for methanol synthesis from CO 2 hydrogenation Yang, Haiyan; Gao, Peng; Zhang, Chen Catalysis Communications, Vol. 84 https://doi.org/10.1016/j.catcom.2016.06.010	journal	September 2016
Recent advances in catalytic hydrogenation of carbon dioxide Wang, Wei; Wang, Shengping; Ma, Xinbin Chemical Society Reviews, Vol. 40, Issue 7 https://doi.org/10.1039/c1cs15008a	journal	January 2011
Design of modular catalysts derived from NiMgAl-LDH@m-SiO2 with dual confinement effects for dry reforming of methane Du, Xianjun; Zhang, Dengsong; Gao, Ruihua Chemical Communications, Vol. 49, Issue 60 https://doi.org/10.1039/c3cc42418a	journal	January 2013
Tandem Catalysis for CO ₂ Hydrogenation to C ₂ –C ₄ Hydrocarbons Xie, Chenlu; Chen, Chen; Yu, Yi Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01139	journal	May 2017
Stability of complex catalyst with NiO@TiO2 core-shell structure for hydrogen production Xu, Jia Yan; Wu, Su Fang International Journal of Hydrogen Energy, Vol. 43, Issue 22 https://doi.org/10.1016/j.ijhydene.2018.04.095	journal	May 2018
Cocatalysts in Semiconductor-based Photocatalytic CO ₂ Reduction: Achievements, Challenges, and Opportunities Ran, Jingrun; Jaroniec, Mietek; Qiao, Shi-Zhang Advanced Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adma.201704649	journal	January 2018
Applying Nanoscale Kirkendall Diffusion for Template-Free, Kilogram-Scale Production of SnO2 Hollow Nanospheres via Spray Drying System Cho, Jung Sang; Ju, Hyeon Seok; Kang, Yun Chan Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23915	journal	April 2016
Graphene-based materials for electrochemical CO2 reduction Ma, Tao; Fan, Qun; Li, Xin Journal of CO2 Utilization, Vol. 30 https://doi.org/10.1016/j.jcou.2019.02.001	journal	March 2019
How do Core-Shell Structure Features Impact on the Activity/Stability of the Co-based Catalyst in Dry Reforming of Methane? Pang, Yijun; Zhong, Aihua; Xu, Zhijia ChemCatChem, Vol. 10, Issue 13 https://doi.org/10.1002/cctc.201800327	journal	May 2018
Building Blocks for High Performance in Electrocatalytic CO ₂ Reduction: Materials, Optimization Strategies, and Device Engineering Larrazábal, Gastón O.; Martín, Antonio J.; Pérez-Ramírez, Javier The Journal of Physical Chemistry Letters, Vol. 8, Issue 16 https://doi.org/10.1021/acs.jpclett.7b01380	journal	August 2017
Effect of Surface Composition on Electronic Structure, Stability, and Electrocatalytic Properties of Pt-Transition Metal Alloys: Pt-Skin versus Pt-Skeleton Surfaces Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Mayrhofer, Karl J. J. Journal of the American Chemical Society, Vol. 128, Issue 27 https://doi.org/10.1021/ja0600476	journal	July 2006
Tuning Structural and Compositional Effects in Pd-Au Nanowires for Highly Selective and Active CO ₂ Electrochemical Reduction Reaction Zhu, Shangqian; Wang, Qi; Qin, Xueping Advanced Energy Materials, Vol. 8, Issue 32 https://doi.org/10.1002/aenm.201802238	journal	October 2018
Shape-selective FeMnK/Al2O3@Silicalite-2 core-shell catalyst for Fischer-Tropsch synthesis to lower olefins Wang, Hongyu; Wang, Jian; Yuan, Yong Catalysis Today, Vol. 314 https://doi.org/10.1016/j.cattod.2018.01.006	journal	September 2018
Pt/CeO ₂ @MOF Core@Shell Nanoreactor for Selective Hydrogenation of Furfural via the Channel Screening Effect Long, Yan; Song, Shuyan; Li, Jian ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b01851	journal	August 2018
Core/Shell Nanoparticles: Classes, Properties, Synthesis Mechanisms, Characterization, and Applications Ghosh Chaudhuri, Rajib; Paria, Santanu Chemical Reviews, Vol. 112, Issue 4 https://doi.org/10.1021/cr100449n	journal	December 2011
Size-dependent plasmonic effects of Au and Au@SiO 2 nanoparticles in photocatalytic CO 2 conversion reaction of Pt/TiO 2 Bera, Sandipan; Lee, Ji Eun; Rawal, Sher Bahadur Applied Catalysis B: Environmental, Vol. 199 https://doi.org/10.1016/j.apcatb.2016.06.025	journal	December 2016
Recent advances in direct catalytic hydrogenation of carbon dioxide to valuable C 2+ hydrocarbons Guo, Lisheng; Sun, Jian; Ge, Qingjie Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/C8TA05377D	journal	January 2018
Enhanced Surface Reaction Kinetics and Charge Separation of p–n Heterojunction Co ₃ O ₄ /BiVO ₄ Photoanodes Chang, Xiaoxia; Wang, Tuo; Zhang, Peng Journal of the American Chemical Society, Vol. 137, Issue 26 https://doi.org/10.1021/jacs.5b04186	journal	June 2015
Robust Hollow Spheres Consisting of Alternating Titania Nanosheets and Graphene Nanosheets with High Photocatalytic Activity for CO2 Conversion into Renewable Fuels Tu, Wenguang; Zhou, Yong; Liu, Qi Advanced Functional Materials, Vol. 22, Issue 6 https://doi.org/10.1002/adfm.201102566	journal	January 2012
Surface-Atom Dependence of ZnO-Supported Ag@Pd Core@Shell Nanocatalysts in CO ₂ Hydrogenation to CH ₃ OH Li, Xinliang; Zeng, Ziyan; Hu, Bing ChemCatChem, Vol. 9, Issue 6 https://doi.org/10.1002/cctc.201601119	journal	February 2017
Electrochemical Activation of CO ₂ through Atomic Ordering Transformations of AuCu Nanoparticles Kim, Dohyung; Xie, Chenlu; Becknell, Nigel Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b03516	journal	June 2017
Controlling Catalytic Selectivities during CO ₂ Electroreduction on Thin Cu Metal Overlayers Reske, Rulle; Duca, Matteo; Oezaslan, Mehtap The Journal of Physical Chemistry Letters, Vol. 4, Issue 15 https://doi.org/10.1021/jz401087q	journal	July 2013
Synthesis of a Highly Active and Stable Nickel-Embedded Alumina Catalyst for Methane Dry Reforming: On the Confinement Effects of Alumina Shells for Nickel Nanoparticles Huang, Qiong; Fang, Xiuzhong; Cheng, Qinzhen ChemCatChem, Vol. 9, Issue 18 https://doi.org/10.1002/cctc.201700490	journal	August 2017
Dispersed Nickel Cobalt Oxyphosphide Nanoparticles Confined in Multichannel Hollow Carbon Fibers for Photocatalytic CO ₂ Reduction Wang, Yan; Wang, Sibo; Lou, Xiong Wen (David) Angewandte Chemie International Edition, Vol. 58, Issue 48 https://doi.org/10.1002/anie.201909707	journal	November 2019
Boosting Tunable Syngas Formation via Electrochemical CO ₂ Reduction on Cu/In ₂ O ₃ Core/Shell Nanoparticles Xie, Huan; Chen, Shaoqing; Ma, Feng ACS Applied Materials & Interfaces, Vol. 10, Issue 43 https://doi.org/10.1021/acsami.8b12747	journal	October 2018
Carbon-Incorporated NiO/TiO ₂ Mesoporous Shells with p–n Heterojunctions for Efficient Visible Light Photocatalysis Wang, Minggui; Han, Jie; Hu, Yimin ACS Applied Materials & Interfaces, Vol. 8, Issue 43 https://doi.org/10.1021/acsami.6b10480	journal	October 2016
The intrinsic effects of shell thickness on the Fischer–Tropsch synthesis over core–shell structured catalysts Zeng, Bo; Hou, Bo; Jia, Litao Catalysis Science & Technology, Vol. 3, Issue 12 https://doi.org/10.1039/c3cy00665d	journal	January 2013
Au@TiO ₂ yolk–shell hollow spheres for plasmon-induced photocatalytic reduction of CO ₂ to solar fuel via a local electromagnetic field Tu, Wenguang; Zhou, Yong; Li, Haijin Nanoscale, Vol. 7, Issue 34 https://doi.org/10.1039/C5NR02943K	journal	January 2015
Hollow Alveolus-Like Nanovesicle Assembly with Metal-Encapsulated Hollow Zeolite Nanocrystals Dai, Chengyi; Zhang, Anfeng; Liu, Min ACS Nano, Vol. 10, Issue 8 https://doi.org/10.1021/acsnano.6b00888	journal	July 2016
Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO2 conversion catalysts Han, Yuqing; Xu, Haitao; Su, Yuqun Journal of Catalysis, Vol. 370 https://doi.org/10.1016/j.jcat.2018.12.005	journal	February 2019
CO ₂ Electroreduction with Enhanced Ethylene and Ethanol Selectivity by Nanostructuring Polycrystalline Copper Kwon, Youngkook; Lum, Yanwei; Clark, Ezra L. ChemElectroChem, Vol. 3, Issue 6 https://doi.org/10.1002/celc.201600068	journal	April 2016
Progress in catalyst exploration for heterogeneous CO ₂ reduction and utilization: a critical review Zhao, Guixia; Huang, Xiubing; Wang, Xiangxue J. Mater. Chem. A, Vol. 5, Issue 41 https://doi.org/10.1039/C7TA07290B	journal	January 2017
A new strategy for utilization of NIR from solar energy—Promotion effect generated from photothermal effect of Fe3O4@SiO2 for photocatalytic oxidation of NO Hu, Jing; Wang, Haiqiang; Dong, Fan Applied Catalysis B: Environmental, Vol. 204 https://doi.org/10.1016/j.apcatb.2016.12.009	journal	May 2017
Controlled assemble of hollow heterostructured g-C3N4@CeO2 with rich oxygen vacancies for enhanced photocatalytic CO2 reduction Liang, Mengfang; Borjigin, Timur; Zhang, Yuhao Applied Catalysis B: Environmental, Vol. 243 https://doi.org/10.1016/j.apcatb.2018.11.010	journal	April 2019
Reversible surface structural changes in Pt-based bimetallic nanoparticles during oxidation and reduction cycles Mu, Rentao; Fu, Qiang; Liu, Hongyang Applied Surface Science, Vol. 255, Issue 16 https://doi.org/10.1016/j.apsusc.2009.03.086	journal	May 2009
Fine Tuning the Composition and Nanostructure of Fe-Based Core-Shell Nanocatalyst for Efficient CO ₂ Hydrogenation Gupta, Sharad; Jain, Vivek K.; Jagadeesan, Dinesh ChemNanoMat, Vol. 2, Issue 10 https://doi.org/10.1002/cnma.201600234	journal	September 2016
Cocatalysts for Selective Photoreduction of CO ₂ into Solar Fuels Li, Xin; Yu, Jiaguo; Jaroniec, Mietek Chemical Reviews, Vol. 119, Issue 6 https://doi.org/10.1021/acs.chemrev.8b00400	journal	January 2019
Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction Whipple, Devin T.; Kenis, Paul J. A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458 https://doi.org/10.1021/jz1012627	journal	December 2010
The Cu–ZnO synergy in methanol synthesis from CO2, Part 1: Origin of active site explained by experimental studies and a sphere contact quantification model on Cu + ZnO mechanical mixtures Le Valant, Anthony; Comminges, Clément; Tisseraud, Céline Journal of Catalysis, Vol. 324 https://doi.org/10.1016/j.jcat.2015.01.021	journal	April 2015
Enhanced Reduction of CO ₂ to CO over Cu–In Electrocatalysts: Catalyst Evolution Is the Key Larrazábal, Gastón O.; Martín, Antonio J.; Mitchell, Sharon ACS Catalysis, Vol. 6, Issue 9 https://doi.org/10.1021/acscatal.6b02067	journal	August 2016
Synthesis of Visible-Light Responsive Graphene Oxide/TiO ₂ Composites with p/n Heterojunction Chen, Chao; Cai, Weimin; Long, Mingce ACS Nano, Vol. 4, Issue 11 https://doi.org/10.1021/nn102130m	journal	October 2010
Visible-light driven heterojunction photocatalysts for water splitting – a critical review Moniz, Savio J. A.; Shevlin, Stephen A.; Martin, David James Energy & Environmental Science, Vol. 8, Issue 3 https://doi.org/10.1039/C4EE03271C	journal	January 2015
Entrapment of a pyridine derivative within a copper–palladium alloy: a bifunctional catalyst for electrochemical reduction of CO ₂ to alcohols with excellent selectivity and reusability Yang, Heng-Pan; Qin, Sen; Yue, Ying-Na Catalysis Science & Technology, Vol. 6, Issue 17 https://doi.org/10.1039/C6CY00971A	journal	January 2016
Tunable syngas production from photocatalytic CO ₂ reduction with mitigated charge recombination driven by spatially separated cocatalysts Li, Ang; Wang, Tuo; Chang, Xiaoxia Chemical Science, Vol. 9, Issue 24 https://doi.org/10.1039/C8SC01812J	journal	January 2018
New horizon in C1 chemistry: breaking the selectivity limitation in transformation of syngas and hydrogenation of CO ₂ into hydrocarbon chemicals and fuels Zhou, Wei; Cheng, Kang; Kang, Jincan Chemical Society Reviews, Vol. 48, Issue 12 https://doi.org/10.1039/C8CS00502H	journal	January 2019
Synergistic core–shell interactions enable ultra-low overpotentials for enhanced CO ₂ electro-reduction activity Ahmad, Rafia; Singh, Abhishek Kumar Journal of Materials Chemistry A, Vol. 6, Issue 42 https://doi.org/10.1039/C8TA06587J	journal	January 2018
Ultra-Small Platinum Nanoparticles Encapsulated in Sub-50 nm Hollow Titania Nanospheres for Low-Temperature Water–Gas Shift Reaction Zhao, Hongyu; Yao, Siyu; Zhang, Mengtao ACS Applied Materials & Interfaces, Vol. 10, Issue 43 https://doi.org/10.1021/acsami.8b12192	journal	October 2018
Thermally stable core–shell Ni/nanorod-CeO ₂ @SiO ₂ catalyst for partial oxidation of methane at high temperatures Zhu, Shaohong; Lian, Xinyi; Fan, Tingting Nanoscale, Vol. 10, Issue 29 https://doi.org/10.1039/C8NR02588F	journal	January 2018
Metal–Organic Frameworks and Their Derived Materials as Electrocatalysts and Photocatalysts for CO ₂ Reduction: Progress, Challenges, and Perspectives Zhang, Hanguang; Li, Jiazhan; Tan, Qiang Chemistry – A European Journal, Vol. 24, Issue 69 https://doi.org/10.1002/chem.201803083	journal	June 2018
The catalytic stability of TiO 2 -shell/Ni-core catalysts for CO 2 reforming of CH 4 Kim, Dae Han; Kim, Soong Yeon; Han, Sang Wook Applied Catalysis A: General, Vol. 495 https://doi.org/10.1016/j.apcata.2015.02.015	journal	April 2015
Graphene-wrapped Pt/TiO2 photocatalysts with enhanced photogenerated charges separation and reactant adsorption for high selective photoreduction of CO2 to CH4 Zhao, Yilong; Wei, Yuechang; Wu, Xingxing Applied Catalysis B: Environmental, Vol. 226 https://doi.org/10.1016/j.apcatb.2017.12.071	journal	June 2018
Hydrogenation of CO ₂ to Methanol on CeO _x /Cu(111) and ZnO/Cu(111) Catalysts: Role of the Metal–Oxide Interface and Importance of Ce ³⁺ Sites Senanayake, Sanjaya D.; Ramírez, Pedro J.; Waluyo, Iradwikanari The Journal of Physical Chemistry C, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcc.5b12012	journal	January 2016
Hollow zeolite encapsulated Ni–Pt bimetals for sintering and coking resistant dry reforming of methane Dai, Chengyi; Zhang, Shaohua; Zhang, Anfeng Journal of Materials Chemistry A, Vol. 3, Issue 32 https://doi.org/10.1039/C5TA03565A	journal	January 2015
Core-shell structured ZnO@Cu-Zn–Al layered double hydroxides with enhanced photocatalytic efficiency for CO 2 reduction Guo, Qiangsheng; Zhang, Qinghong; Wang, Hongzhi Catalysis Communications, Vol. 77 https://doi.org/10.1016/j.catcom.2016.01.019	journal	March 2016
Cu ₂ O/Reduced Graphene Oxide Composites for the Photocatalytic Conversion of CO ₂ An, Xiaoqiang; Li, Kimfung; Tang, Junwang ChemSusChem, Vol. 7, Issue 4 https://doi.org/10.1002/cssc.201301194	journal	February 2014
Uncoupling the size and support effects of Ni catalysts for dry reforming of methane Han, Joung Woo; Park, Jun Seong; Choi, Min Suk Applied Catalysis B: Environmental, Vol. 203 https://doi.org/10.1016/j.apcatb.2016.10.069	journal	April 2017
Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals Nielsen, Dennis U.; Hu, Xin-Ming; Daasbjerg, Kim Nature Catalysis, Vol. 1, Issue 4 https://doi.org/10.1038/s41929-018-0051-3	journal	April 2018
Synthesis of M@TiO ₂ (M = Au, Pd, Pt) Core–Shell Nanocomposites with Tunable Photoreactivity Zhang, Nan; Liu, Siqi; Fu, Xianzhi The Journal of Physical Chemistry C, Vol. 115, Issue 18 https://doi.org/10.1021/jp2009989	journal	April 2011
Effect of Mn loading onto MnFeO nanocomposites for the CO2 hydrogenation reaction Al-Dossary, M.; Ismail, Adel A.; Fierro, J. L. G. Applied Catalysis B: Environmental, Vol. 165 https://doi.org/10.1016/j.apcatb.2014.10.064	journal	April 2015
Photocatalytic Reduction of Carbon Dioxide over Ag Cocatalyst-Loaded ALa ₄ Ti ₄ O ₁₅ (A = Ca, Sr, and Ba) Using Water as a Reducing Reagent Iizuka, Kosuke; Wato, Tomoaki; Miseki, Yugo Journal of the American Chemical Society, Vol. 133, Issue 51 https://doi.org/10.1021/ja207586e	journal	December 2011
Strain and Ligand Effects on CO ₂ Reduction Reactions over Cu–Metal Heterostructure Catalysts Liu, Fuzhu; Wu, Chao; Yang, Shengchun The Journal of Physical Chemistry C, Vol. 121, Issue 40 https://doi.org/10.1021/acs.jpcc.7b07081	journal	September 2017
Aggregation- and Leaching-Resistant, Reusable, and Multifunctional Pd@CeO ₂ as a Robust Nanocatalyst Achieved by a Hollow Core–Shell Strategy Zhang, Nan; Xu, Yi-Jun Chemistry of Materials, Vol. 25, Issue 9 https://doi.org/10.1021/cm400750c	journal	April 2013
Catalytic performance for CO2 conversion to methanol of gallium-promoted copper-based catalysts: influence of metallic precursors Toyir, Jamil; Ramı́rez de la Piscina, Pilar; Fierro, José Luis G. Applied Catalysis B: Environmental, Vol. 34, Issue 4 https://doi.org/10.1016/S0926-3373(01)00203-X	journal	November 2001
Single-Step Fabrication of Monodisperse TiO ₂ Hollow Spheres with Embedded Nanoparticles in Microfluidic Devices Eun, Tai Hee; Kim, Se-Hoon; Jeong, Won-Jong Chemistry of Materials, Vol. 21, Issue 2 https://doi.org/10.1021/cm8017133	journal	January 2009
Ni@NiO Core–Shell Structure-Modified Nitrogen-Doped InTaO ₄ for Solar-Driven Highly Efficient CO ₂ Reduction to Methanol Tsai, Chi-Wen; Chen, Hao Ming; Liu, Ru-Shi The Journal of Physical Chemistry C, Vol. 115, Issue 20 https://doi.org/10.1021/jp2020534	journal	May 2011
Preparation of CdS@CeO2 core/shell composite for photocatalytic reduction of CO2 under visible-light irradiation Ijaz, Sana; Ehsan, Muhammad Fahad; Ashiq, Muhammad Naeem Applied Surface Science, Vol. 390 https://doi.org/10.1016/j.apsusc.2016.08.098	journal	December 2016
Design of a core–shell Pt–SiO2 catalyst in a reverse microemulsion system: Distinctive kinetics on CO oxidation at low temperature Almana, Noor; Phivilay, Somphonh Peter; Laveille, Paco Journal of Catalysis, Vol. 340 https://doi.org/10.1016/j.jcat.2016.06.002	journal	August 2016
High carbon resistant Ni@Ni phyllosilicate@SiO2 core shell hollow sphere catalysts for low temperature CH4 dry reforming Li, Ziwei; Jiang, Bo; Wang, Zhigang Journal of CO2 Utilization, Vol. 27 https://doi.org/10.1016/j.jcou.2018.07.017	journal	October 2018
CeF3/TiO2 composite as a novel visible-light-driven photocatalyst based on upconversion emission and its application for photocatalytic reduction of CO2 Tang, Chunni; Hou, Wenqian; Liu, Enzhou Journal of Luminescence, Vol. 154 https://doi.org/10.1016/j.jlumin.2014.04.040	journal	October 2014
Two-dimensional g-C ₃ N ₄ : an ideal platform for examining facet selectivity of metal co-catalysts in photocatalysis Bai, Song; Wang, Xijun; Hu, Canyu Chem. Commun., Vol. 50, Issue 46 https://doi.org/10.1039/C4CC00745J	journal	January 2014
Status and perspectives of CO2 conversion into fuels and chemicals by catalytic, photocatalytic and electrocatalytic processes Kondratenko, Evgenii V.; Mul, Guido; Baltrusaitis, Jonas Energy & Environmental Science, Vol. 6, Issue 11 https://doi.org/10.1039/c3ee41272e	journal	January 2013
Controllable Hydrocarbon Formation from the Electrochemical Reduction of CO ₂ over Cu Nanowire Arrays Ma, Ming; Djanashvili, Kristina; Smith, Wilson A. Angewandte Chemie International Edition, Vol. 55, Issue 23 https://doi.org/10.1002/anie.201601282	journal	April 2016
Active sites for CO ₂ hydrogenation to methanol on Cu/ZnO catalysts Kattel, Shyam; Ramírez, Pedro J.; Chen, Jingguang G. Science, Vol. 355, Issue 6331 https://doi.org/10.1126/science.aal3573	journal	March 2017
Active and Selective Conversion of CO ₂ to CO on Ultrathin Au Nanowires Zhu, Wenlei; Zhang, Yin-Jia; Zhang, Hongyi Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja5095099	journal	November 2014
Hydrogenation of CO ₂ to Methanol: Importance of Metal–Oxide and Metal–Carbide Interfaces in the Activation of CO ₂ Rodriguez, José A.; Liu, Ping; Stacchiola, Dario J. ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01755	journal	October 2015
Dry reforming of methane to syngas: a potential alternative process for value added chemicals—a techno-economic perspective Mondal, Kartick; Sasmal, Sankar; Badgandi, Srikant Environmental Science and Pollution Research, Vol. 23, Issue 22 https://doi.org/10.1007/s11356-016-6310-4	journal	March 2016
Design and synthesis of NiCe@m-SiO 2 yolk-shell framework catalysts with improved coke- and sintering-resistance in dry reforming of methane Zhao, Xiaoyuan; Li, Hongrui; Zhang, Jianping International Journal of Hydrogen Energy, Vol. 41, Issue 4 https://doi.org/10.1016/j.ijhydene.2015.10.111	journal	January 2016
Facile synthesis of Au@TiO2 core–shell hollow spheres for dye-sensitized solar cells with remarkably improved efficiency Du, Jiang; Qi, Jian; Wang, Dan Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21264a	journal	January 2012
Properties of yolk–shell structured Ni@SiO 2 nanocatalyst and its catalytic performance in carbon dioxide reforming of methane to syngas Yang, Weiwei; Liu, Huimin; Li, Yuming Catalysis Today, Vol. 259 https://doi.org/10.1016/j.cattod.2015.04.012	journal	January 2016
The Cu–ZnO synergy in methanol synthesis Part 3: Impact of the composition of a selective Cu@ZnO core–shell catalyst on methanol rate explained by experimental studies and a concentric spheres model Tisseraud, Céline; Comminges, Clément; Pronier, Stéphane Journal of Catalysis, Vol. 343 https://doi.org/10.1016/j.jcat.2015.12.005	journal	November 2016
Robust mesoporous bimetallic yolk–shell catalysts for chemical CO ₂ upgrading via dry reforming of methane Price, Cameron-Alexander Hurd; Pastor-Pérez, Laura; Ramirez Reina, Tomas Reaction Chemistry & Engineering, Vol. 3, Issue 4 https://doi.org/10.1039/C8RE00058A	journal	January 2018
Effect of alloy composition on catalytic performance and coke-resistance property of Ni-Cu/Mg(Al)O catalysts for dry reforming of methane Song, Kai; Lu, Miaomiao; Xu, Shuping Applied Catalysis B: Environmental, Vol. 239 https://doi.org/10.1016/j.apcatb.2018.08.023	journal	December 2018
Fischer-Tropsch Catalysts for the Production of Hydrocarbon Fuels with High Selectivity Zhang, Qinghong; Cheng, Kang; Kang, Jincan ChemSusChem, Vol. 7, Issue 5 https://doi.org/10.1002/cssc.201300797	journal	December 2013
One-Pot Facile Fabrication of Multiple Nickel Nanoparticles Confined in Microporous Silica Giving a Multiple-Cores@Shell Structure as a Highly Efficient Catalyst for Methane Dry Reforming Peng, Honggen; Zhang, Xianhua; Zhang, Li ChemCatChem, Vol. 9, Issue 1 https://doi.org/10.1002/cctc.201601263	journal	December 2016
NiCo@SiO2 core-shell catalyst with high activity and long lifetime for CO2 conversion through DRM reaction Zhao, Yu; Li, Hui; Li, Hexing Nano Energy, Vol. 45 https://doi.org/10.1016/j.nanoen.2017.12.023	journal	March 2018
A core-shell structured Fe 2 O 3 /ZrO 2 @ZrO 2 nanomaterial with enhanced redox activity and stability for CO 2 conversion Hu, Jiawei; Galvita, Vladimir V.; Poelman, Hilde Journal of CO2 Utilization, Vol. 17 https://doi.org/10.1016/j.jcou.2016.11.003	journal	January 2017
Plasma-assisted catalytic dry reforming of methane: Highly catalytic performance of nickel ferrite nanoparticles embedded in silica Zheng, Xiaogang; Tan, Shiyu; Dong, Lichun Journal of Power Sources, Vol. 274 https://doi.org/10.1016/j.jpowsour.2014.10.065	journal	January 2015
Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research Yang, Dong; Gates, Bruce C. ACS Catalysis, Vol. 9, Issue 3 https://doi.org/10.1021/acscatal.8b04515	journal	January 2019
Cu–Ni@SiO2 alloy nanocomposites for methane dry reforming catalysis Wu, Tao; Cai, Weiye; Zhang, Peng RSC Advances, Vol. 3, Issue 46 https://doi.org/10.1039/c3ra43203c	journal	January 2013
Atomic-scale engineering of indium oxide promotion by palladium for methanol production via CO2 hydrogenation Frei, Matthias S.; Mondelli, Cecilia; García-Muelas, Rodrigo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11349-9	journal	July 2019
Facile synthesis of core–shell Au@CeO2 nanocomposites with remarkably enhanced catalytic activity for CO oxidation Qi, Jian; Chen, Jie; Li, Guodong Energy & Environmental Science, Vol. 5, Issue 10 https://doi.org/10.1039/c2ee22600f	journal	January 2012
Progress and Perspectives of Electrochemical CO ₂ Reduction on Copper in Aqueous Electrolyte Nitopi, Stephanie; Bertheussen, Erlend; Scott, Soren B. Chemical Reviews, Vol. 119, Issue 12 https://doi.org/10.1021/acs.chemrev.8b00705	journal	April 2019
Emerging Carbon‐Based Heterogeneous Catalysts for Electrochemical Reduction of Carbon Dioxide into Value‐Added Chemicals Wu, Jingjie; Sharifi, Tiva; Gao, Ying Advanced Materials, Vol. 31, Issue 13 https://doi.org/10.1002/adma.201804257	journal	December 2018
Chainmail co-catalyst of NiO shell-encapsulated Ni for improving photocatalytic CO ₂ reduction over g-C ₃ N ₄ Han, Chunqiu; Zhang, Rumeng; Ye, Yinghao Journal of Materials Chemistry A, Vol. 7, Issue 16 https://doi.org/10.1039/C9TA01061K	journal	January 2019
Dry reforming of methane over Ni/La2O3 nanorod catalysts with stabilized Ni nanoparticles Li, Xinyu; Li, Di; Tian, Hao Applied Catalysis B: Environmental, Vol. 202 https://doi.org/10.1016/j.apcatb.2016.09.071	journal	March 2017
Solution-processed yolk–shell-shaped WO ₃ /BiVO ₄ heterojunction photoelectrodes for efficient solar water splitting Jin, Bingjun; Jung, Eunji; Ma, Ming Journal of Materials Chemistry A, Vol. 6, Issue 6 https://doi.org/10.1039/C7TA08452H	journal	January 2018
Organically doped palladium: a highly efficient catalyst for electroreduction of CO ₂ to methanol Yang, Heng-Pan; Qin, Sen; Wang, Huan Green Chemistry, Vol. 17, Issue 12 https://doi.org/10.1039/C5GC01504A	journal	January 2015
Effect of Au surface plasmon nanoparticles on the selective CO2 photoreduction to CH4 Collado, L.; Reynal, A.; Coronado, J. M. Applied Catalysis B: Environmental, Vol. 178 https://doi.org/10.1016/j.apcatb.2014.09.032	journal	November 2015
Three-Dimensional Ordered Assembly of Thin-Shell Au/TiO ₂ Hollow Nanospheres for Enhanced Visible-Light-Driven Photocatalysis Dinh, Cao-Thang; Yen, Hoang; Kleitz, Freddy Angewandte Chemie International Edition, Vol. 53, Issue 26 https://doi.org/10.1002/anie.201400966	journal	April 2014
Mechanism of CO ₂ Reduction at Copper Surfaces: Pathways to C ₂ Products Garza, Alejandro J.; Bell, Alexis T.; Head-Gordon, Martin ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03477	journal	January 2018
Photo-induced reduction of CO 2 to CO with hydrogen over plasmonic Ag-NPs/TiO 2 NWs core/shell hetero-junction under UV and visible light Tahir, Muhammad; Tahir, Beenish; Amin, Nor Aishah Saidina Journal of CO2 Utilization, Vol. 18 https://doi.org/10.1016/j.jcou.2017.02.002	journal	March 2017
NiO-MgO nanoparticles confined inside SiO 2 frameworks to achieve highly catalytic performance for CO 2 reforming of methane Xu, Jiayu; Xiao, Qinglin; Zhang, Jun Molecular Catalysis, Vol. 432 https://doi.org/10.1016/j.mcat.2017.02.019	journal	May 2017
Mechanism and microkinetics of methanol synthesis via CO2 hydrogenation on indium oxide Frei, M. S.; Capdevila-Cortada, M.; García-Muelas, R. Journal of Catalysis, Vol. 361 https://doi.org/10.1016/j.jcat.2018.03.014	journal	May 2018
Electrochemical Reduction of CO at a Copper Electrode Hori, Yoshio; Takahashi, Ryutaro; Yoshinami, Yuzuru The Journal of Physical Chemistry B, Vol. 101, Issue 36 https://doi.org/10.1021/jp970284i	journal	September 1997
Conversion of CO2 to C1 chemicals: Catalyst design, kinetics and mechanism aspects of the reactions Jangam, Ashok; Das, Sonali; Dewangan, Nikita Catalysis Today https://doi.org/10.1016/j.cattod.2019.08.049	journal	August 2019
Hydrogenated Blue Titania for Efficient Solar to Chemical Conversions: Preparation, Characterization, and Reaction Mechanism of CO ₂ Reduction Yin, Guoheng; Huang, Xieyi; Chen, Tianyuan ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03473	journal	January 2018
Selectivity of CO ₂ Reduction on Copper Electrodes: The Role of the Kinetics of Elementary Steps Nie, Xiaowa; Esopi, Monica R.; Janik, Michael J. Angewandte Chemie International Edition, Vol. 52, Issue 9 https://doi.org/10.1002/anie.201208320	journal	January 2013
Simultaneous Tuning Porosity and Basicity of Nickel@Nickel–Magnesium Phyllosilicate Core–Shell Catalysts for CO ₂ Reforming of CH ₄ Li, Ziwei; Kathiraser, Yasotha; Ashok, Jangam Langmuir, Vol. 30, Issue 48 https://doi.org/10.1021/la503340s	journal	November 2014
Au@TiO ₂ Core-Shell Composites for the Photocatalytic Reduction of CO ₂ Pougin, Anna; Dodekatos, Georgios; Dilla, Martin Chemistry - A European Journal, Vol. 24, Issue 47 https://doi.org/10.1002/chem.201801796	journal	June 2018
Metallic tin quantum sheets confined in graphene toward high-efficiency carbon dioxide electroreduction Lei, Fengcai; Liu, Wei; Sun, Yongfu Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12697	journal	September 2016
Integration of an Inorganic Semiconductor with a Metal-Organic Framework: A Platform for Enhanced Gaseous Photocatalytic Reactions Li, Rui; Hu, Jiahua; Deng, Mingsen Advanced Materials, Vol. 26, Issue 28 https://doi.org/10.1002/adma.201400428	journal	May 2014
Silica–Ceria sandwiched Ni core–shell catalyst for low temperature dry reforming of biogas: Coke resistance and mechanistic insights Das, S.; Ashok, J.; Bian, Z. Applied Catalysis B: Environmental, Vol. 230 https://doi.org/10.1016/j.apcatb.2018.02.041	journal	August 2018
LaNiO3 nanocube embedded in mesoporous silica for dry reforming of methane with enhanced coking resistance Zhang, Li; Lian, Jie; Li, Le Microporous and Mesoporous Materials, Vol. 266 https://doi.org/10.1016/j.micromeso.2018.02.021	journal	August 2018
A Core/Shell Catalyst Produces a Spatially Confined Effect and Shape Selectivity in a Consecutive Reaction Bao, Jun; He, Jingjiang; Zhang, Yi Angewandte Chemie International Edition, Vol. 47, Issue 2 https://doi.org/10.1002/anie.200703335	journal	January 2008
Si and Ge based metallic core/shell nanowires for nano-electronic device applications Bhuyan, Prabal Dev; Kumar, Ashok; Sonvane, Yogesh Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-35225-6	journal	November 2018
The technological and economic prospects for CO2 utilization and removal Hepburn, Cameron; Adlen, Ella; Beddington, John Nature, Vol. 575, Issue 7781 https://doi.org/10.1038/s41586-019-1681-6	journal	November 2019
One-pot synthesis of Ag-MWCNT@TiO2 core–shell nanocomposites for photocatalytic reduction of CO2 with water under visible light irradiation Gui, Meei Mei; Wong, William Ming Ping; Chai, Siang-Piao Chemical Engineering Journal, Vol. 278 https://doi.org/10.1016/j.cej.2014.09.022	journal	October 2015
Thin Heterojunctions and Spatially Separated Cocatalysts To Simultaneously Reduce Bulk and Surface Recombination in Photocatalysts Li, Ang; Chang, Xiaoxia; Huang, Zhiqi Angewandte Chemie International Edition, Vol. 55, Issue 44 https://doi.org/10.1002/anie.201605666	journal	July 2016
Immobilizing Ni nanoparticles to mesoporous silica with size and location control via a polyol-assisted route for coking- and sintering-resistant dry reforming of methane Xie, Ting; Shi, Liyi; Zhang, Jianping Chem. Commun., Vol. 50, Issue 55 https://doi.org/10.1039/C4CC01441C	journal	January 2014
A Core-Shell-Structured Silver Nanowire/Nitrogen-Doped Carbon Catalyst for Enhanced and Multifunctional Electrofixation of CO ₂ Yang, Heng-Pan; Zhang, Han-Wen; Wu, Yu ChemSusChem, Vol. 11, Issue 22 https://doi.org/10.1002/cssc.201801612	journal	September 2018
Structure engineering of Cu-based nanoparticles for electrochemical reduction of CO2 Liu, Shangguo; Huang, Shiping Journal of Catalysis, Vol. 375 https://doi.org/10.1016/j.jcat.2019.05.035	journal	July 2019
Facile tailoring of Co-based spinel hierarchical hollow microspheres for highly efficient catalytic conversion of CO2 Li, Yaxuan; Li, Xinyong; Fan, Shiying Journal of Colloid and Interface Science, Vol. 552 https://doi.org/10.1016/j.jcis.2019.05.054	journal	September 2019
Controlled synthesis of upconverting nanoparticles/ZnxCd1-xS yolk-shell nanoparticles for efficient photocatalysis driven by NIR light Wang, Wan-Ni; Huang, Chen-Xi; Zhang, Chen-Yang Applied Catalysis B: Environmental, Vol. 224 https://doi.org/10.1016/j.apcatb.2017.11.037	journal	May 2018
Ligand and ensemble effects in adsorption on alloy surfaces Liu, P.; Nørskov, J. K. Physical Chemistry Chemical Physics, Vol. 3, Issue 17 https://doi.org/10.1039/b103525h	journal	January 2001
Design of Heterostructured Hollow Photocatalysts for Solar‐to‐Chemical Energy Conversion Zhang, Peng; Lou, Xiong Wen (David) Advanced Materials, Vol. 31, Issue 29 https://doi.org/10.1002/adma.201900281	journal	May 2019
Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles Kim, Dohyung; Resasco, Joaquin; Yu, Yi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5948	journal	September 2014
HKUST‐1 Derived Hollow C‐Cu _{2− x} S Nanotube/g‐C ₃ N ₄ Composites for Visible‐Light CO ₂ Photoreduction with H ₂ O Vapor Hu, Cheng‐Ying; Zhou, Jie; Sun, Chun‐Yi Chemistry – A European Journal, Vol. 25, Issue 1 https://doi.org/10.1002/chem.201804925	journal	December 2018
Electrocatalysts based on metal@carbon core@shell nanocomposites: An overview Peng, Yi; Chen, Shaowei Green Energy & Environment, Vol. 3, Issue 4 https://doi.org/10.1016/j.gee.2018.07.006	journal	October 2018
Strain-Induced Band Gap Modification in Coherent Core/Shell Nanostructures Yang, Shenyuan; Prendergast, David; Neaton, Jeffrey B. Nano Letters, Vol. 10, Issue 8 https://doi.org/10.1021/nl101999p	journal	August 2010
Ultrahigh Mass Activity for Carbon Dioxide Reduction Enabled by Gold–Iron Core–Shell Nanoparticles Sun, Kun; Cheng, Tao; Wu, Lina Journal of the American Chemical Society, Vol. 139, Issue 44 https://doi.org/10.1021/jacs.7b09251	journal	October 2017
One-Step Preparation of Pd-SiO ₂ Composite Microspheres by the Sol–Gel Process in a Microchannel Li, Jiahui; Yao, Hongbao; Wang, Yujun Industrial & Engineering Chemistry Research, Vol. 53, Issue 26 https://doi.org/10.1021/ie5009458	journal	June 2014
Steering post-C–C coupling selectivity enables high efficiency electroreduction of carbon dioxide to multi-carbon alcohols Zhuang, Tao-Tao; Liang, Zhi-Qin; Seifitokaldani, Ali Nature Catalysis, Vol. 1, Issue 6 https://doi.org/10.1038/s41929-018-0084-7	journal	June 2018
Silica-based micro- and mesoporous catalysts for dry reforming of methane Li, Ziwei; Das, Sonali; Hongmanorom, Plaifa Catalysis Science & Technology, Vol. 8, Issue 11 https://doi.org/10.1039/C8CY00622A	journal	January 2018
A promising low pressure methanol synthesis route from CO ₂ hydrogenation over Pd@Zn core–shell catalysts Liao, Fenglin; Wu, Xin-Ping; Zheng, Jianwei Green Chemistry, Vol. 19, Issue 1 https://doi.org/10.1039/C6GC02366E	journal	January 2017
Bimetallic Electrocatalysts for CO2 Reduction Zhu, Wenlei; Tackett, Brian M.; Chen, Jingguang G. Topics in Current Chemistry, Vol. 376, Issue 6 https://doi.org/10.1007/s41061-018-0220-5	journal	October 2018
Sintering resistant Ni nanoparticles exclusively confined within SiO ₂ nanotubes for CH ₄ dry reforming Li, Ziwei; Wang, Zhigang; Jiang, Bo Catalysis Science & Technology, Vol. 8, Issue 13 https://doi.org/10.1039/C8CY00767E	journal	January 2018
Enhancing activity for carbon dioxide methanation by encapsulating (1 1 1) facet Ni particle in metal–organic frameworks at low temperature Zhen, Wenlong; Gao, Feng; Tian, Bin Journal of Catalysis, Vol. 348 https://doi.org/10.1016/j.jcat.2017.02.031	journal	April 2017
Photocatalytic Conversion of Carbon Dioxide with Water into Methane: Platinum and Copper(I) Oxide Co-catalysts with a Core-Shell Structure Zhai, Qingge; Xie, Shunji; Fan, Wenqing Angewandte Chemie International Edition, Vol. 52, Issue 22 https://doi.org/10.1002/anie.201301473	journal	April 2013
Yolk–Satellite–Shell Structured Ni–Yolk@Ni@SiO ₂ Nanocomposite: Superb Catalyst toward Methane CO ₂ Reforming Reaction Li, Ziwei; Mo, Liuye; Kathiraser, Yasotha ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs401027p	journal	April 2014
Recent advances in platinum monolayer electrocatalysts for oxygen reduction reaction: Scale-up synthesis, structure and activity of Pt shells on Pd cores Sasaki, K.; Wang, J. X.; Naohara, H. Electrochimica Acta, Vol. 55, Issue 8 https://doi.org/10.1016/j.electacta.2009.11.106	journal	March 2010
Correlation between the work function of Au–Ag nanoalloys and their electrocatalytic activity in carbon dioxide reduction Ismail, Ahmed Mohsen; Csapó, Edit; Janáky, Csaba Electrochimica Acta, Vol. 313 https://doi.org/10.1016/j.electacta.2019.05.016	journal	August 2019
An electrochemical study of carbon dioxide electroreduction on gold-based nanoparticle catalysts Lates, V.; Falch, A.; Jordaan, A. Electrochimica Acta, Vol. 128 https://doi.org/10.1016/j.electacta.2013.10.162	journal	May 2014
A Sinter-Resistant Catalytic System Fabricated by Maneuvering the Selectivity of SiO ₂ Deposition onto the TiO ₂ Surface versus the Pt Nanoparticle Surface Lu, Ping; Campbell, Charles T.; Xia, Younan Nano Letters, Vol. 13, Issue 10 https://doi.org/10.1021/nl4029973	journal	September 2013
Design of highly stable and selective core/yolk–shell nanocatalysts—A review Li, Ziwei; Li, Min; Bian, Zhoufeng Applied Catalysis B: Environmental, Vol. 188 https://doi.org/10.1016/j.apcatb.2016.01.067	journal	July 2016
Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles Gao, Dunfeng; Zhou, Hu; Cai, Fan Nano Research, Vol. 10, Issue 6 https://doi.org/10.1007/s12274-017-1514-6	journal	April 2017
Dendritic porous yolk@ordered mesoporous shell structured heterogeneous nanocatalysts with enhanced stability Du, Xin; Zhao, Caixia; Luan, Yi J. Mater. Chem. A, Vol. 5, Issue 40 https://doi.org/10.1039/C7TA07271F	journal	January 2017
The Synthesis and Application of CuO-ZnO/HZSM-5 Catalyst With Core-shell Structure Li, Q.; Xin, C.; Lian, P. Petroleum Science and Technology, Vol. 30, Issue 21 https://doi.org/10.1080/10916466.2010.512883	journal	November 2012
Single Atom Catalysts: Carbon-Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage(Adv. Mater. 48/2018) Peng, Yi; Lu, Bingzhang; Chen, Shaowei Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201870370	journal	November 2018
Core–shell structured reduced graphene oxide wrapped magnetically separable rGO@CuZnO@Fe3O4 microspheres as superior photocatalyst for CO2 reduction under visible light Kumar, Pawan; Joshi, Chetan; Barras, Alexandre Applied Catalysis B: Environmental, Vol. 205 https://doi.org/10.1016/j.apcatb.2016.11.060	journal	May 2017
Hydrogenation of CO2 to light olefins on CuZnZr@(Zn-)SAPO-34 catalysts: Strategy for product distribution Chen, Jingyu; Wang, Xu; Wu, Dakai Fuel, Vol. 239 https://doi.org/10.1016/j.fuel.2018.10.148	journal	March 2019
Tuning CO2 electroreduction efficiency at Pd shells on Au nanocores Plana, Daniela; Flórez-Montaño, Jonathan; Celorrio, Veronica Chemical Communications, Vol. 49, Issue 93 https://doi.org/10.1039/c3cc46543h	journal	January 2013
Insight into the effects of the oxygen species over Ni/ZrO2 catalyst surface on methane reforming with carbon dioxide Zhang, Meng; Zhang, Junfeng; Wu, Yingquan Applied Catalysis B: Environmental, Vol. 244 https://doi.org/10.1016/j.apcatb.2018.11.068	journal	May 2019
Preparation, characterization and reaction performance of H-ZSM-5/cobalt/silica capsule catalysts with different sizes for direct synthesis of isoparaffins Yang, Guohui; He, Jingjiang; Yoneyama, Yoshiharu Applied Catalysis A: General, Vol. 329 https://doi.org/10.1016/j.apcata.2007.06.028	journal	October 2007
Confinement Effect and Synergistic Function of H-ZSM-5/Cu-ZnO-Al ₂ O ₃ Capsule Catalyst for One-Step Controlled Synthesis Yang, Guohui; Tsubaki, Noritatsu; Shamoto, Jun Journal of the American Chemical Society, Vol. 132, Issue 23 https://doi.org/10.1021/ja101882a	journal	June 2010
Incorporation of Nitrogen Defects for Efficient Reduction of CO ₂ via Two-Electron Pathway on Three-Dimensional Graphene Foam Wu, Jingjie; Liu, Mingjie; Sharma, Pranav P. Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04123	journal	December 2015
The Cu–ZnO synergy in methanol synthesis from CO2, Part 2: Origin of the methanol and CO selectivities explained by experimental studies and a sphere contact quantification model in randomly packed binary mixtures on Cu–ZnO coprecipitate catalysts Tisseraud, Céline; Comminges, Clément; Belin, Thomas Journal of Catalysis, Vol. 330 https://doi.org/10.1016/j.jcat.2015.04.035	journal	October 2015
Synthesis of Dispersible Pd@CeO ₂ Core−Shell Nanostructures by Self-Assembly Cargnello, Matteo; Wieder, Noah L.; Montini, Tiziano Journal of the American Chemical Society, Vol. 132, Issue 4 https://doi.org/10.1021/ja909131k	journal	February 2010
Bimetallic IrNi core platinum monolayer shell electrocatalysts for the oxygen reduction reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Choi, YongMan Energy Environ. Sci., Vol. 5, Issue 1 https://doi.org/10.1039/C1EE02067F	journal	January 2012
Mono and Bifunctional Pathways of CO2/CH4Reforming over Pt and Rh Based Catalysts Bitter, J. H.; Seshan, K.; Lercher, J. A. Journal of Catalysis, Vol. 176, Issue 1 https://doi.org/10.1006/jcat.1998.2022	journal	May 1998
(Ni/MgAl2O4)@SiO2 core–shell catalyst with high coke-resistance for the dry reforming of methane Wang, Yousen; Fang, Qiong; Shen, Weihua Reaction Kinetics, Mechanisms and Catalysis, Vol. 125, Issue 1 https://doi.org/10.1007/s11144-018-1404-2	journal	March 2018
The Tunable and Highly Selective Reduction Products on Ag@Cu Bimetallic Catalysts Toward CO ₂ Electrochemical Reduction Reaction Chang, Zhiyuan; Huo, Shengjuan; Zhang, Wei The Journal of Physical Chemistry C, Vol. 121, Issue 21 https://doi.org/10.1021/acs.jpcc.7b01586	journal	May 2017
Carbon-Supported Single Atom Catalysts for Electrochemical Energy Conversion and Storage Peng, Yi; Lu, Bingzhang; Chen, Shaowei Advanced Materials, Vol. 30, Issue 48 https://doi.org/10.1002/adma.201801995	journal	August 2018
LaNiO3@SiO2 core–shell nano-particles for the dry reforming of CH4 in the dielectric barrier discharge plasma Zheng, Xiaogang; Tan, Shiyu; Dong, Lichun International Journal of Hydrogen Energy, Vol. 39, Issue 22 https://doi.org/10.1016/j.ijhydene.2014.05.083	journal	July 2014
Electrochemical Carbon Dioxide Splitting Xie, Jiafang; Huang, Yiyin; Wu, Maoxiang ChemElectroChem, Vol. 6, Issue 6 https://doi.org/10.1002/celc.201801716	journal	February 2019
Synergistic effect in plasmonic Au/Ag alloy NPs co-coated TiO2 NWs toward visible-light enhanced CO2 photoreduction to fuels Tahir, Muhammad; Tahir, Beenish; Amin, Nor Aishah Saidina Applied Catalysis B: Environmental, Vol. 204 https://doi.org/10.1016/j.apcatb.2016.11.062	journal	May 2017
Direct synthesis of dimethyl ether from CO ₂ hydrogenation over Cu–ZnO–ZrO ₂ /SO ₄ ²⁻ –ZrO ₂ hybrid catalysts: effects of sulfur-to-zirconia ratios Witoon, Thongthai; Permsirivanich, Tinnavat; Kanjanasoontorn, Nawapon Catalysis Science & Technology, Vol. 5, Issue 4 https://doi.org/10.1039/C4CY01568A	journal	January 2015
Selective carbon dioxide electroreduction to ethylene and ethanol by core-shell copper/cuprous oxide Shang, Longmei; Lv, Ximeng; Shen, Hao Journal of Colloid and Interface Science, Vol. 552 https://doi.org/10.1016/j.jcis.2019.05.073	journal	September 2019
Facile Synthesis of High Surface Area Yolk-Shell Ni@Ni Embedded SiO ₂ via Ni Phyllosilicate with Enhanced Performance for CO ₂ Reforming of CH ₄ Li, Ziwei; Kathiraser, Yasotha; Kawi, Sibudjing ChemCatChem, Vol. 7, Issue 1 https://doi.org/10.1002/cctc.201402673	journal	December 2014
Controlled Synthesis of Monodisperse SiO ₂ TiO ₂ Microspheres with a Yolk-Shell Structure as Effective Photocatalysts Yoo, Jung Bo; Yoo, Hyo Jin; Lim, Byung Wook ChemSusChem, Vol. 5, Issue 12 https://doi.org/10.1002/cssc.201200463	journal	November 2012
Synthesis of multi-shelled ZnO hollow microspheres and their improved photocatalytic activity Zeng, Xiangyun; Yang, Jiao; Shi, Liuxue Nanoscale Research Letters, Vol. 9, Issue 1 https://doi.org/10.1186/1556-276X-9-468	journal	January 2014
Poly(l-lysine)-modified silica nanoparticles for the delivery of antisense oligonucleotides Zhu, Shi-Guo; Xiang, Juan-Juan; Li, Xiao-Ling Biotechnology and Applied Biochemistry, Vol. 39, Issue 2 https://doi.org/10.1042/BA20030077	journal	April 2004
Design of Ni-ZrO2@SiO2 catalyst with ultra-high sintering and coking resistance for dry reforming of methane to prepare syngas Liu, Wenming; Li, Le; Zhang, Xianhua Journal of CO2 Utilization, Vol. 27 https://doi.org/10.1016/j.jcou.2018.08.003	journal	October 2018
Encapsulation of Iron Nitride by Fe–N–C Shell Enabling Highly Efficient Electroreduction of CO ₂ to CO Cheng, Qingqing; Mao, Kun; Ma, Lushan ACS Energy Letters, Vol. 3, Issue 5 https://doi.org/10.1021/acsenergylett.8b00474	journal	April 2018
Highly Active and Stable Bimetallic Nickel-Copper Core-Ceria Shell Catalyst for High-Temperature Water-Gas Shift Reaction Saw, Eng Toon; Oemar, Usman; Ang, Ming Li ChemCatChem, Vol. 7, Issue 20 https://doi.org/10.1002/cctc.201500481	journal	August 2015
Engineering Metal–Organic Frameworks for the Electrochemical Reduction of CO ₂ : A Minireview Wang, Riming; Kapteijn, Freek; Gascon, Jorge Chemistry – An Asian Journal, Vol. 14, Issue 20 https://doi.org/10.1002/asia.201900710	journal	July 2019
Cu/Zn/Al/Zr catalysts via phase-pure hydrotalcite-like compounds for methanol synthesis from carbon dioxide Gao, Peng; Xie, Rongyong; Wang, Hui Journal of CO2 Utilization, Vol. 11 https://doi.org/10.1016/j.jcou.2014.12.008	journal	September 2015
(Gold core)/(titania shell) nanostructures for plasmon-enhanced photon harvesting and generation of reactive oxygen species Fang, Caihong; Jia, Henglei; Chang, Shuai Energy Environ. Sci., Vol. 7, Issue 10 https://doi.org/10.1039/C4EE01787K	journal	January 2014
Thermal-stable Pd@mesoporous silica core-shell nanocatalysts for dry reforming of methane with good coke-resistant performance Yue, Lei; Li, Jiamao; Chen, Chao Fuel, Vol. 218 https://doi.org/10.1016/j.fuel.2018.01.052	journal	April 2018
Pd/CNT-promoted CuZrO2/HZSM-5 hybrid catalysts for direct synthesis of DME from CO2/H2 Zhang, Meng-Hui; Liu, Zhi-Ming; Lin, Guo-Dong Applied Catalysis A: General, Vol. 451 https://doi.org/10.1016/j.apcata.2012.10.038	journal	January 2013
Towards full one-pass conversion of carbon dioxide to methanol and methanol-derived products Bansode, Atul; Urakawa, Atsushi Journal of Catalysis, Vol. 309 https://doi.org/10.1016/j.jcat.2013.09.005	journal	January 2014
Transition-Metal Nanoparticles in Hollow Zeolite Single Crystals as Bifunctional and Size-Selective Hydrogenation Catalysts Li, Shiwen; Tuel, Alain; Laprune, David Chemistry of Materials, Vol. 27, Issue 1 https://doi.org/10.1021/cm503921f	journal	December 2014
Photoreduction of CO2 on ZIF-8/TiO2 nanocomposites in a gaseous photoreactor under pressure swing Pipelzadeh, Ehsan; Rudolph, Victor; Hanson, Graeme Applied Catalysis B: Environmental, Vol. 218 https://doi.org/10.1016/j.apcatb.2017.06.054	journal	December 2017
Recent developments on heterogeneous catalytic CO2 reduction to methanol Din, Israf Ud; Shaharun, Maizatul S.; Alotaibi, Mshari A. Journal of CO2 Utilization, Vol. 34 https://doi.org/10.1016/j.jcou.2019.05.036	journal	December 2019
Preparation of HZSM-5 membrane packed CuO–ZnO–Al 2 O 3 nanoparticles for catalysing carbon dioxide hydrogenation to dimethyl ether Liu, Rong; Tian, Haifeng; Yang, Aimei Applied Surface Science, Vol. 345 https://doi.org/10.1016/j.apsusc.2015.03.125	journal	August 2015
Bimetallic Fe–Co catalysts for CO2 hydrogenation to higher hydrocarbons Satthawong, Ratchprapa; Koizumi, Naoto; Song, Chunshan Journal of CO2 Utilization, Vol. 3-4 https://doi.org/10.1016/j.jcou.2013.10.002	journal	December 2013
Hybrid carbon@TiO ₂ hollow spheres with enhanced photocatalytic CO ₂ reduction activity Wang, Weikang; Xu, Difa; Cheng, Bei Journal of Materials Chemistry A, Vol. 5, Issue 10 https://doi.org/10.1039/C6TA11121A	journal	January 2017
Au@Cu2O core@shell nanocrystals as dual-functional catalysts for sustainable environmental applications Kuo, Ming-Yu; Hsiao, Chih-Feng; Chiu, Yi-Hsuan Applied Catalysis B: Environmental, Vol. 242 https://doi.org/10.1016/j.apcatb.2018.09.075	journal	March 2019
Origin of Enhancing the Photocatalytic Performance of TiO ₂ for Artificial Photoreduction of CO ₂ through a SiO ₂ Coating Strategy Yuan, Lan; Han, Chuang; Pagliaro, Mario The Journal of Physical Chemistry C, Vol. 120, Issue 1 https://doi.org/10.1021/acs.jpcc.5b08893	journal	December 2015
Sodium-Containing Spinel Zinc Ferrite as a Catalyst Precursor for the Selective Synthesis of Liquid Hydrocarbon Fuels Choi, Yo Han; Ra, Eun Cheol; Kim, Eun Hyup ChemSusChem, Vol. 10, Issue 23 https://doi.org/10.1002/cssc.201701437	journal	October 2017
TiO ₂ /NiO hybrid shells: p–n junction photocatalysts with enhanced activity under visible light Wang, Minggui; Hu, Yimin; Han, Jie Journal of Materials Chemistry A, Vol. 3, Issue 41 https://doi.org/10.1039/C5TA05839B	journal	January 2015
Fe ₂ O ₃ @La _x Sr _{1− x} FeO ₃ Core-Shell Redox Catalyst for Methane Partial Oxidation Shafiefarhood, Arya; Galinsky, Nathan; Huang, Yan ChemCatChem, Vol. 6, Issue 3 https://doi.org/10.1002/cctc.201301104	journal	February 2014
New and revisited insights into the promotion of methanol synthesis catalysts by CO2 Martin, Oliver; Pérez-Ramírez, Javier Catalysis Science & Technology, Vol. 3, Issue 12 https://doi.org/10.1039/c3cy00573a	journal	January 2013
Cu–Sn Bimetallic Catalyst for Selective Aqueous Electroreduction of CO ₂ to CO Sarfraz, Saad; Garcia-Esparza, Angel T.; Jedidi, Abdesslem ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00269	journal	April 2016
Stabilization of Pt at the inner wall of hollow spherical SiO2 generated from Pt/hollow spherical SiC for sulfuric acid decomposition Khan, Hassnain Abbas; Natarajan, Prakash; Jung, Kwang-Deog Applied Catalysis B: Environmental, Vol. 231 https://doi.org/10.1016/j.apcatb.2018.03.013	journal	September 2018
Amine-Functionalized Titanate Nanosheet-Assembled Yolk@Shell Microspheres for Efficient Cocatalyst-Free Visible-Light Photocatalytic CO ₂ Reduction Liu, Shengwei; Xia, Jiaqiu; Yu, Jiaguo ACS Applied Materials & Interfaces, Vol. 7, Issue 15 https://doi.org/10.1021/acsami.5b00982	journal	April 2015
Enhanced electrocatalytic activity of Au@Cu core@shell nanoparticles towards CO ₂ reduction Monzó, J.; Malewski, Y.; Kortlever, R. Journal of Materials Chemistry A, Vol. 3, Issue 47 https://doi.org/10.1039/C5TA06804E	journal	January 2015
A novel Core–Shell structured CuIn@SiO ₂ catalyst for CO ₂ hydrogenation to methanol Shi, Zhisheng; Tan, Qingqing; Wu, Dongfang AIChE Journal, Vol. 65, Issue 3 https://doi.org/10.1002/aic.16490	journal	December 2018
Fabrication of cubic Zn ₂ SnO ₄ /SnO ₂ complex hollow structures and their sunlight-driven photocatalytic activity Sun, Linqiang; Han, Xiao; Jiang, Zhe Nanoscale, Vol. 8, Issue 26 https://doi.org/10.1039/C5NR08004E	journal	January 2016
Size-dependent activity and selectivity of carbon dioxide photocatalytic reduction over platinum nanoparticles Dong, Chunyang; Lian, Cheng; Hu, Songchang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03666-2	journal	March 2018
Visible-light-driven MWCNT@TiO ₂ core–shell nanocomposites and the roles of MWCNTs on the surface chemistry, optical properties and reactivity in CO ₂ photoreduction Gui, Meei Mei; Chai, Siang-Piao; Xu, Bo-Qing RSC Adv., Vol. 4, Issue 46 https://doi.org/10.1039/C4RA02561J	journal	January 2014
Enhancing catalytic activity and stability for CO ₂ methanation on Ni@MOF-5 via control of active species dispersion Zhen, Wenlong; Li, Bo; Lu, Gongxuan Chemical Communications, Vol. 51, Issue 9 https://doi.org/10.1039/C4CC08733J	journal	January 2015
1D carbon nanofibers@TiO2 core-shell nanocomposites with enhanced photocatalytic activity toward CO2 reduction Zhang, Jinfeng; Fu, Junwei; Chen, Shifu Journal of Alloys and Compounds, Vol. 746 https://doi.org/10.1016/j.jallcom.2018.02.265	journal	May 2018
Crystal-plane effect of nanoscale CeO ₂ on the catalytic performance of Ni/CeO ₂ catalysts for methane dry reforming Wang, Ning; Qian, Weizhong; Chu, Wei Catalysis Science & Technology, Vol. 6, Issue 10 https://doi.org/10.1039/C5CY01790D	journal	January 2016
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene Mistry, Hemma; Varela, Ana Sofia; Bonifacio, Cecile S. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12123	journal	June 2016
Effect of metal particle size on coking during CO2 reforming of CH4 over Ni–alumina aerogel catalysts Kim, Jin-Hong; Suh, Dong Jin; Park, Tae-Jin Applied Catalysis A: General, Vol. 197, Issue 2 https://doi.org/10.1016/S0926-860X(99)00487-1	journal	May 2000
Critical Aspects and Recent Advances in Structural Engineering of Photocatalysts for Sunlight‐Driven Photocatalytic Reduction of CO ₂ into Fuels Vu, Nhu‐Nang; Kaliaguine, Serge; Do, Trong‐On Advanced Functional Materials, Vol. 29, Issue 31 https://doi.org/10.1002/adfm.201901825	journal	April 2019
3D ordered macroporous TiO ₂ -supported Pt@CdS core–shell nanoparticles: design, synthesis and efficient photocatalytic conversion of CO ₂ with water to methane Wei, Yuechang; Jiao, Jinqing; Zhao, Zhen Journal of Materials Chemistry A, Vol. 3, Issue 20 https://doi.org/10.1039/C5TA00444F	journal	January 2015
Influence of preparation method on activity and stability of Ni catalysts supported on Gd doped ceria in dry reforming of methane Gurav, Hanmant R.; Dama, Srikanth; Samuel, Violet Journal of CO2 Utilization, Vol. 20 https://doi.org/10.1016/j.jcou.2017.06.014	journal	July 2017
Ni-SiO2 Catalysts for the Carbon Dioxide Reforming of Methane: Varying Support Properties by Flame Spray Pyrolysis Lovell, Emma; Scott, Jason; Amal, Rose Molecules, Vol. 20, Issue 3 https://doi.org/10.3390/molecules20034594	journal	March 2015
A review of the catalytic hydrogenation of carbon dioxide into value-added hydrocarbons Yang, Haiyan; Zhang, Chen; Gao, Peng Catalysis Science & Technology, Vol. 7, Issue 20 https://doi.org/10.1039/C7CY01403A	journal	January 2017
A review on photochemical, biochemical and electrochemical transformation of CO2 into value-added products Yaashikaa, P. R.; Senthil Kumar, P.; Varjani, Sunita J. Journal of CO2 Utilization, Vol. 33 https://doi.org/10.1016/j.jcou.2019.05.017	journal	October 2019
Photocatalytic reduction of carbon dioxide with water using InNbO4 catalyst with NiO and Co3O4 cocatalysts Lee, Der-Shing; Chen, Hsin-Ju; Chen, Yu-Wen Journal of Physics and Chemistry of Solids, Vol. 73, Issue 5 https://doi.org/10.1016/j.jpcs.2012.01.005	journal	May 2012
The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol Bonura, G.; Cordaro, M.; Cannilla, C. Applied Catalysis B: Environmental, Vol. 152-153 https://doi.org/10.1016/j.apcatb.2014.01.035	journal	June 2014
Controlling upconversion nanocrystals for emerging applications Zhou, Bo; Shi, Bingyang; Jin, Dayong Nature Nanotechnology, Vol. 10, Issue 11 https://doi.org/10.1038/nnano.2015.251	journal	November 2015
Selective photocatalytic carbon dioxide conversion with Pt@Ag-TiO2 nanoparticles Wang, Yan; Lai, Qinghua; He, Yiming Catalysis Communications, Vol. 108 https://doi.org/10.1016/j.catcom.2018.02.004	journal	April 2018
Synthesis of isoalkanes over a core (Fe–Zn–Zr)–shell (zeolite) catalyst by CO ₂ hydrogenation Wang, Xiaoxing; Yang, Guohui; Zhang, Junfeng Chemical Communications, Vol. 52, Issue 46 https://doi.org/10.1039/C6CC01965J	journal	January 2016
A Rational Design of Cu ₂ O−SnO ₂ Core‐Shell Catalyst for Highly Selective CO ₂ ‐to‐CO Conversion Zhang, Sheng‐Nian; Li, Meng; Hua, Bin ChemCatChem, Vol. 11, Issue 16 https://doi.org/10.1002/cctc.201900395	journal	May 2019
Tin Oxide Dependence of the CO ₂ Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts Chen, Yihong; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja2108799	journal	January 2012
Effective nonmetal incorporation in black titania with enhanced solar energy utilization Lin, Tianquan; Yang, Chongyin; Wang, Zhou Energy & Environmental Science, Vol. 7, Issue 3 https://doi.org/10.1039/c3ee42708k	journal	January 2014
Palladium nanoparticle's surface structure and morphology effect on the catalytic activity for dry reforming of methane Costilla, Ignacio O.; Sánchez, Miguel D.; Gigola, Carlos E. Applied Catalysis A: General, Vol. 478 https://doi.org/10.1016/j.apcata.2014.03.030	journal	May 2014
A review of dry (CO ₂ ) reforming of methane over noble metal catalysts Pakhare, Devendra; Spivey, James Chem. Soc. Rev., Vol. 43, Issue 22 https://doi.org/10.1039/C3CS60395D	journal	January 2014
Overcoating the Surface of Fe-Based Catalyst with ZnO and Nitrogen-Doped Carbon toward High Selectivity of Light Olefins in CO ₂ Hydrogenation Liu, Junhui; Zhang, Anfeng; Jiang, Xiao Industrial & Engineering Chemistry Research, Vol. 58, Issue 10 https://doi.org/10.1021/acs.iecr.8b05478	journal	February 2019
Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide Kortlever, Ruud; Shen, Jing; Schouten, Klaas Jan P. The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01559	journal	September 2015
CO 2 reforming with methane over small-sized Ni@SiO 2 catalysts with unique features of sintering-free and low carbon Wang, Fagen; Han, Bolin; Zhang, Linjia Applied Catalysis B: Environmental, Vol. 235 https://doi.org/10.1016/j.apcatb.2018.04.069	journal	November 2018

Similar Records

Wet Chemical Growth and Thermocatalytic Activity of Cu-Based Nanoparticles Supported on TiO₂ Nanoparticles/HOPG: In Situ Ambient Pressure XPS Study of the CO₂ Hydrogenation Reaction

Journal Article · Tue Jun 18 00:00:00 EDT 2019 · ACS Catalysis · OSTI ID:1618782

Ferrah, Djawhar; Haines, Amanda R.; Galhenage, Randima P.; +5 more

Direct synthesis of branched hydrocarbons from CO₂ over composite catalysts in a single reactor

Journal Article · Fri Oct 21 00:00:00 EDT 2022 · Journal of CO2 Utilization · OSTI ID:1618782

To, Anh T.; Arellano-Treviño, Martha A.; Nash, Connor P.; +1 more

Roundtable on Foundational Science for Carbon-Neutral Hydrogen Technologies (Technology Status Document)

Technical Report · Wed Sep 01 00:00:00 EDT 2021 · OSTI ID:1618782

Myers, Deborah J.; Ahluwalia, Rajesh K.; Allendorf, Mark D.; +21 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Core–shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO 2

Citation Formats

References (351)

Similar Records

Related Subjects

Title: Core–shell structured catalysts for thermocatalytic, photocatalytic, and electrocatalytic conversion of CO ₂