Templated nanofiber synthesis via chemical vapor polymerization into liquid crystalline films

Cheng, Kenneth C.  K.; Bedolla-Pantoja, Marco A.; Kim, Young-Ki; Gregory, Jason V.; Xie, Fan; de France, Alexander; Hussal, Christoph; Sun, Kai; Abbott, Nicholas L.; Lahann, Joerg

doi:10.1126/science.aar8449

Title: Templated nanofiber synthesis via chemical vapor polymerization into liquid crystalline films

Journal Article · Fri Nov 16 00:00:00 EST 2018 · Science

DOI:https://doi.org/10.1126/science.aar8449· OSTI ID:1616864

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Univ. of Michigan, Ann Arbor, MI (United States); IBM Research, Albany, NY (United States)
Univ. of Wisconsin, Madison, WI (United States)
Univ. of Wisconsin, Madison, WI (United States); Cornell Univ., Ithaca, NY (United States)
Univ. of Michigan, Ann Arbor, MI (United States)
Karlsruhe Inst. of Technology (Germany)
Univ. of Michigan, Ann Arbor, MI (United States); Karlsruhe Inst. of Technology (Germany)

Extrusion, electrospinning, and microdrawing are widely used to create fibrous polymer mats, but these approaches offer limited access to oriented arrays of nanometer-scale fibers with controlled size, shape, and lateral organization. We show that chemical vapor polymerization can be performed on surfaces coated with thin films of liquid crystals to synthesize organized assemblies of end-attached polymer nanofibers. The process uses low concentrations of radical monomers formed initially in the vapor phase and then diffused into the liquid-crystal template. This minimizes monomer-induced changes to the liquid-crystal phase and enables access to nanofiber arrays with complex yet precisely defined structures and compositions. Finally, the nanofiber arrays permit tailoring of a wide range of functional properties, including adhesion that depends on nanofiber chirality.

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Research Organization:: Univ. of Wisconsin, Madison, WI (United States); Univ. of Chicago, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Army Research Office (ARO)

Grant/Contract Number:: SC0004025; W911NF-11-1-0251; W911NF-17-1-0575; DMR-1720415

OSTI ID:: 1616864

Journal Information:: Science, Vol. 362, Issue 6416; ISSN 0036-8075

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 44 works

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A critical review of reactive vapor deposition for conjugated polymer synthesis Bilger, David; Homayounfar, S. Zohreh; Andrew, Trisha L. Journal of Materials Chemistry C, Vol. 7, Issue 24 https://doi.org/10.1039/c9tc01388a	journal	January 2019
Regioselective Functionalization of [2.2]Paracyclophanes: Recent Synthetic Progress and Perspectives Hassan, Zahid; Spuling, Eduard; Knoll, Daniel M. FID GEO https://doi.org/10.23689/fidgeo-4840	text	January 2019
Regioselektive Funktionalisierung von [2.2]Paracyclophanen: aktuelle Synthesefortschritte und Perspektiven Hassan, Zahid; Spuling, Eduard; Knoll, Daniel M. FID GEO https://doi.org/10.23689/fidgeo-4828	text	January 2019
Regioselective Functionalization of [2.2]Paracyclophanes: Recent Synthetic Progress and Perspectives Hassan, Zahid; Spuling, Eduard; Knoll, Daniel M. Karlsruhe https://doi.org/10.5445/ir/1000118463	text	January 2020
Regioselektive Funktionalisierung von [2.2]Paracyclophanen: aktuelle Synthesefortschritte und Perspektiven Hassan, Zahid; Spuling, Eduard; Knoll, Daniel M. Angewandte Chemie, Vol. 132, Issue 6 https://doi.org/10.1002/ange.201904863	journal	October 2019
Control of the Folding Dynamics of Self‐Reconfiguring Magnetic Microbots Using Liquid Crystallinity Shields, C. Wyatt; Kim, Young-Ki; Han, Koohee Advanced Intelligent Systems, Vol. 2, Issue 2 https://doi.org/10.1002/aisy.201900114	journal	January 2020
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