Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage

Jie, Kecheng; Zhou, Yujuan; Sun, Qi; Li, Bo; Zhao, Run; Jiang, De-en; Guo, Wei; Chen, Hao; Yang, Zhenzhen; Huang, Feihe; Dai, Sheng

doi:10.1038/s41467-020-14892-y

Title: Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage

Journal Article · Thu Feb 27 00:00:00 EST 2020 · Nature Communications

DOI:https://doi.org/10.1038/s41467-020-14892-y· OSTI ID:1616810

Jie, Kecheng ^[1]; Zhou, Yujuan ^[2]; Sun, Qi ^[2]; Li, Bo ^[3]; Zhao, Run ^[2];

^[3]; Guo, Wei ^[1]; Chen, Hao ^[4]; Yang, Zhenzhen ^[1]; Huang, Feihe ^[2];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Zheijiang Univ., Hangzhou (China)
Univ. of California, Riverside, CA (United States)
Univ. of Tennessee, Knoxville, TN (United States); Zheijiang Univ., Hangzhou (China)

The incorporation of supramolecular macrocycles into porous organic polymers may endow the material with enhanced uptake of specific guests through host–guest interactions. Here we report a solvent and catalyst-free mechanochemical synthesis of pillar[5]quinone (P5Q) derived multi-microporous organic polymers with hydrophenazine linkages (MHP-P5Q), which show a unique 3-step N₂ adsorption isotherm. In comparison with analogous microporous hydrophenazine-linked organic polymers (MHPs) obtained using simple twofold benzoquinones, MHP-P5Q is demonstrated to have a superior performance in radioactive iodomethane (CH₃I) capture and storage. Mechanistic studies show that the rigid pillar[5]arene cavity has additional binding sites though host–guest interactions as well as the halogen bond (-I···N = C-) and chemical adsorption in the multi-microporous MHP-P5Q mainly account for the rapid and high-capacity adsorption and long-term storage of CH₃I.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1616810

Journal Information:: Nature Communications, Vol. 11, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 55 works

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Title: Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage

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