Giant and reversible room-temperature magnetocaloric effect in Ti-doped Ni-Co-Mn-Sn magnetic shape memory alloys

Qu, Y. H.; Cong, D. Y.; Sun, X. M.; Nie, Z. H.; Gui, W. Y.; Li, R. G.; Ren, Y.; Wang, Y. D.

doi:10.1016/j.actamat.2017.06.010

Giant and reversible room-temperature magnetocaloric effect in Ti-doped Ni-Co-Mn-Sn magnetic shape memory alloys

Journal Article · Thu Jun 08 00:00:00 EDT 2017 · Acta Materialia

DOI:https://doi.org/10.1016/j.actamat.2017.06.010· OSTI ID:1616285

Qu, Y. H. ^[1]; Cong, D. Y. ^[1]; Sun, X. M. ^[1]; Nie, Z. H. ^[2]; Gui, W. Y. ^[1]; Li, R. G. ^[1]; Ren, Y. ^[3]; Wang, Y. D. ^[1]

Univ. of Science and Technology, Beijing (China)
Beijing Inst. of Technology (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

The practical applications of magnetocaloric materials for magnetic refrigeration require not only large magnitude but also reversibility, as well as room-temperature operating temperature, of the magneto caloric effect. However, it is a complex problem to simultaneously meet these demands in the Heusler-type Ni-(Co)-Mn-X (X = In, Sn, Sb, Ga) magnetic shape memory alloys which are a promising candidate for magnetocaloric materials, owing to the interdependence of magnetostructural transformation parameters. In this work, through synergic tuning of magnetostructural transformation parameters via alloying with Ti in Ni_42-xTi_xCo₉Mn₃₉Sn₁₀ alloys, we achieved a large reversible room-temperature magnetocaloric effect. By alloying with a proper amount of Ti, the martensitic transformation temperature was brought down to room temperature and the sensitivity of transformation temperature to magnetic field change was greatly enhanced with the transformation entropy change still remaining a large value, while the thermal hysteresis and the transformation interval only slightly increased. Thus, the field required to induce the complete and reversible transformation was significantly reduced. As a result, a large reversible room-temperature magnetic entropy change ΔS_m of 18.7 J kg^-1 K^-1 under 5 T was achieved in the Ni₄₁Ti₁Co₉Mn₃₉Sn₁₀ alloy. This is the first report on reversibleΔS_m in Ni-Mn-Sn-based Heusler alloys and the ΔS_m we achieved represents the highest reversible ΔS_m under 5 T reported heretofore in Ni-Mn-based Heusler alloys. Furthermore, the Ni₄₁Ti₁Co₉Mn₃₉Sn₁₀ alloy shows good compressive properties and stable martensitic transformation during thermal cycling, beneficial for potential magnetocaloric applications. This study is instructive for the development of high-performance magnetocaloric materials for room-temperature magnetic refrigeration.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); National High Technology Research and Development Program of China; Fundamental Research Funds for the Central Universities; Chinese Academy of Sciences (CAS). State Key Laboratory for Advanced Metals and Materials

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1616285

Alternate ID(s):: OSTI ID: 1550288

Journal Information:: Acta Materialia, Journal Name: Acta Materialia Vol. 134; ISSN 1359-6454

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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