Mechano-Electrochemical Interaction in Solid-State Lithium Batteries

Hao, Feng; Wang, Wenxiu; Mukherjee, Partha P.

doi:10.1149/1945-7111/ab8a98

Title: Mechano-Electrochemical Interaction in Solid-State Lithium Batteries

Journal Article · Mon Apr 27 00:00:00 EDT 2020 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/1945-7111/ab8a98· OSTI ID:1616217

Hao, Feng; Wang, Wenxiu;

A solid-state lithium (Li) battery primarily consists of Li metal anode, solid electrolyte separator, and cathode. The asymmetric volume changes, originating from ion transport and interfacial Li growth during plating, lead to significant stresses in the layered architecture. In this study, we develop a coupled mechanics-electrochemistry formalism for polymer electrolyte based solid-state batteries, in particular, focusing on the stress effect on electrochemical performance. By means of a coupling coefficient, it is found that stress-assisted ion transport in the electrolyte results in a delayed Sand’s time and increased critical current density of unstable electrodeposition, and consequently, alleviates the propensity of dendrite formation. Stress at the Li metal-electrolyte interface affects the electrochemical reaction kinetics, and the influences from the deviatoric stress and hydrostatic pressure vary with Li plating time. In addition, a low restraint stiffness to the layered structure could elastically buffer the volumetric changes and thus reduce the stress during Li plating. This fundamental study provides guidance for the design of solid-state batteries, aimed at stable electrodeposition and mechanical integrity.

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Research Organization:: Texas A & M Univ., College Station, TX (United States). Texas A & M Engineering Experiment Station

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0007766

OSTI ID:: 1616217

Alternate ID(s):: OSTI ID: 1799365

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 167 Journal Issue: 8; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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