Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate

Caravan, Rebecca L.; Vansco, Michael F.; Au, Kendrew; Khan, M. Anwar H.; Li, Yu-Lin; Winiberg, Frank A. F.; Zuraski, Kristen; Lin, Yen-Hsiu; Chao, Wen; Trongsiriwat, Nisalak; Walsh, Patrick J.; Osborn, David L.; Percival, Carl J.; Lin, Jim Jr-Min; Shallcross, Dudley E.; Sheps, Leonid; Klippenstein, Stephen J.; Taatjes, Craig A.; Lester, Marsha I.

doi:10.1073/pnas.1916711117

Title: Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate

Journal Article · Wed Apr 22 00:00:00 EDT 2020 · Proceedings of the National Academy of Sciences of the United States of America

DOI:https://doi.org/10.1073/pnas.1916711117· OSTI ID:1615850

;

; Au, Kendrew;

; Li, Yu-Lin;

;

; Lin, Yen-Hsiu; Chao, Wen;

;

Isoprene has the highest emission into Earth’s atmosphere of any nonmethane hydrocarbon. Atmospheric processing of alkenes, including isoprene, via ozonolysis leads to the formation of zwitterionic reactive intermediates, known as Criegee intermediates (CIs). Direct studies have revealed that reactions involving simple CIs can significantly impact the tropospheric oxidizing capacity, enhance particulate formation, and degrade local air quality. Methyl vinyl ketone oxide (MVK-oxide) is a four-carbon, asymmetric, resonance-stabilized CI, produced with 21 to 23% yield from isoprene ozonolysis, yet its reactivity has not been directly studied. We present direct kinetic measurements of MVK-oxide reactions with key atmospheric species using absorption spectroscopy. Direct UV-Vis absorption spectra from two independent flow cell experiments overlap with the molecular beam UV-Vis-depletion spectra reported recently [M. F. Vansco, B. Marchetti, M. I. Lester, J. Chem. Phys. 149, 44309 (2018)] but suggest different conformer distributions under jet-cooled and thermal conditions. Comparison of the experimental lifetime herein with theory indicates only the syn-conformers are observed; anti-conformers are calculated to be removed much more rapidly via unimolecular decay. We observe experimentally and predict theoretically fast reaction of syn-MVK-oxide with SO2 and formic acid, similar to smaller alkyl-substituted CIs, and by contrast, slow removal in the presence of water. We determine products through complementary multiplexed photoionization mass spectrometry, observing SO3 and identifying organic hydroperoxide formation from reaction with SO2 and formic acid, respectively. The tropospheric implications of these reactions are evaluated using a global chemistry and transport model.

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Research Organization:: Univ. of Pennsylvania, Philadelphia, PA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF); Academia Sinica and Ministry of Science and Technology

Grant/Contract Number:: FG02-87ER13792; NA0003525; AC02-06CH11357; AC02-05CH11231

OSTI ID:: 1615850

Alternate ID(s):: OSTI ID: 1632275; OSTI ID: 1633328; OSTI ID: 1782234

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Vol. 117 Journal Issue: 18; ISSN 0027-8424

Publisher:: National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 61 works

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Title: Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate

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