Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage

Lee, Juhoon; Brewster, James T.; Song, Bo; Lynch, Vincent M.; Hwang, Inhong; Li, Xiaopeng; Sessler, Jonathan L.

doi:10.1039/C8CC05160G

Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage

Journal Article · Tue Jul 31 04:00:00 EDT 2018 · ChemComm

DOI:https://doi.org/10.1039/C8CC05160G· OSTI ID:1615764

^[1]; ^[2]; ^[3]; ^[2]; ^[2]; Li, Xiaopeng ^[3]; ^[2]

Univ. of Texas, Austin, TX (United States); The University of Texas at Austin
Univ. of Texas, Austin, TX (United States)
Univ. of South Florida, Tampa, FL (United States)

A set of self-assembled tri- and tetrapodal metal coordination cage structures (cage-1 and cage-2, respectively) constructed from the uranyl dication (UO₂²⁺) and a dibenzoic acid functionalised cis-calix[4]pyrrole (1) are described. The inherent photochemical reactivity of the uranyl dication mediates the transformation of cage-1 to cage-2 via the activation of molecular oxygen here.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: FG02-01ER15186

OSTI ID:: 1615764

Alternate ID(s):: OSTI ID: 1463039

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 68 Vol. 54; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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