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Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space

Journal Article · · CrystEngComm
DOI:https://doi.org/10.1039/D0CE00343C· OSTI ID:1615066
 [1];  [2];  [2];  [1]
  1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA, Center for Hierarchical Wasteform Materials (CHWM)
  2. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA
+ Show Author Affiliations

The flux synthesis of a uranium gallophosphate and a uranium gallate, Cs 4 [UO 2 Ga 2 (PO 4 ) 4 ] and Cs 2 UO 2 Ga 2 O 5 , and 4 uranium phosphates, [Rb 2 Rb 3.93 Cl 0.93 ][(UO 2 ) 5 (PO 4 ) 5 ], Rb 11 [(UO 2 ) 8 (PO 4 ) 9 ], Rb 7.6 [(UO 2 ) 8 O 8.6 F 0.4 (PO 4 ) 2 ], and Rb 6 [(UO 2 ) 5 O 2 (PO 4 ) 4 ], is reported.

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0016574
OSTI ID:
1615066
Alternate ID(s):
OSTI ID: 1767711
Journal Information:
CrystEngComm, Journal Name: CrystEngComm Journal Issue: 17 Vol. 22; ISSN CRECF4; ISSN 1466-8033
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space
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