Structural transformation in GexS100–x (10 ≤ x ≤ 40) network glasses: Structural varieties in short-range, medium-range, and nanoscopic scale

Sakaguchi, Y.; Hanashima, T.; Ohara, K.; Simon, Al-Amin A.; Mitkova, M.

doi:10.1103/physrevmaterials.3.035601

Title: Structural transformation in Ge_xS_100–x (10 ≤ x ≤ 40) network glasses: Structural varieties in short-range, medium-range, and nanoscopic scale

Journal Article · Tue Mar 19 00:00:00 EDT 2019 · Physical Review Materials

DOI:https://doi.org/10.1103/physrevmaterials.3.035601· OSTI ID:1613954

Sakaguchi, Y. ^[1]; Hanashima, T. ^[1]; Ohara, K. ^[2]; Simon, Al-Amin A. ^[3]; Mitkova, M. ^[3]

Comprehensive Research Organization for Science and Society (CROSS), Tokai (Japan)
Japan Synchrotron Radiation Research Inst., Hyogo (Japan)
Boise State Univ., ID (United States)

Precise x-ray diffraction measurements using high-energy x rays of synchrotron radiation and systematic Raman scattering measurements were carried out for Ge_xS_100–x (10 ≤ x ≤ 40) network glasses. The structural models of the network glasses were proposed based on the results. In the stoichiometric composition Ge₃₃S₆₇, GeS₄ tetrahedral units are connected forming either corner-sharing or edge-sharing structures. In the S-rich glasses, S atoms are inserted between two neighboring GeS₄ tetrahedra, resulting in a flexible floppy network. In a much more S-rich region, some S₈ ring molecules are isolated from the network, and assemble to form a crystal in nanoscopic scale. In this respect, Ge₁₀S₉₀ samples are regarded as crystallized glasses. In the Ge-rich region, the GeS₄ tetrahedra are connected with bridging Ge atoms. The connection makes a new rigid network. Furthermore, the bridging Ge-S bond is weaker than the intratetrahedron bond, and this leads to drastic changes in the optical properties.

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Research Organization:: Boise State Univ., ID (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: NE0008691

OSTI ID:: 1613954

Alternate ID(s):: OSTI ID: 1546356

Journal Information:: Physical Review Materials, Vol. 3, Issue 3; ISSN 2475-9953

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 14 works

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Title: Structural transformation in GexS100–x (10 ≤ x ≤ 40) network glasses: Structural varieties in short-range, medium-range, and nanoscopic scale

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Title: Structural transformation in Ge_xS_100–x (10 ≤ x ≤ 40) network glasses: Structural varieties in short-range, medium-range, and nanoscopic scale