Transformation of char carbon during bubbling fluidized bed gasification of biomass

Timmer, Kevin J.; Brown, Robert C.

doi:10.1016/j.fuel.2019.01.039

Transformation of char carbon during bubbling fluidized bed gasification of biomass

Journal Article · Tue Jan 29 00:00:00 EST 2019 · Fuel

DOI:https://doi.org/10.1016/j.fuel.2019.01.039· OSTI ID:1613526

Timmer, Kevin J. ^[1]; Brown, Robert C. ^[2]

Iowa State Univ., Ames, IA (United States); DOE/OSTI
Iowa State Univ., Ames, IA (United States)

This study focuses on the fate of carbon in the char generated by devolatilization of biomass during fluidized bed gasification. A carbon balance model was developed to distinguish between char transformed to carbon-bearing gases and its comminution and elutriation as fine char during gasification. The model accurately predicts the transient accumulation of char carbon in the reactor. Experiments revealed steady state reactor char carbon loadings were achieved after multiple hours of gasification. The model formed the basis of an experimental methodology that assesses the transformation of char carbon based on collection of elutriated solids from the reactor and assessment of the steady state char carbon loading in the reactor. Experiments were performed to distinguish the relative contributions of chemical reaction and physical comminution toward conversion of char to gaseous and solid products. The effects of equivalence ratio, gasification temperature, superficial gas velocity, biomass particle size, and the addition of steam on the partitioning of char carbon between gaseous and solid products during gasification of ground seed corn in a bubbling fluidized bed were investigated. This study revealed that char conversion during gasification of biomass was limited by elutriation of fine char particles arising from fragmentation or attrition of primary char product. Additionally, increased chemical reaction of char to form gases was usually accompanied by increased elutriation of fine char, which suggests that chemical reaction increased the porosity of the char and its susceptibility to fragmentation and attrition. Lastly, decreasing superficial gas velocity, increasing equivalence ratio, and decreasing particle size led to increased carbon conversion, while increasing temperature and steam concentration in the reactor had negligible effect.

View Accepted Manuscript (DOE)

Research Organization:: Iowa State University, Ames, IA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: FC36-01GO11091

OSTI ID:: 1613526

Alternate ID(s):: OSTI ID: 1547820

Journal Information:: Fuel, Journal Name: Fuel Journal Issue: C Vol. 242; ISSN 0016-2361

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Transformation of char carbon during bubbling fluidized bed gasification of biomass

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