1,2-Propanediol as a Surrogate Molecule of Glycerol for Mechanistic Studies of Selective Hydrodeoxygenation Reactions over Mo 2 C and Cu/Mo 2 C Surfaces

Lin, Zhexi; Wan, Weiming; Chen, Jingguang G.

doi:10.1021/acssuschemeng.9b01051

1,2-Propanediol as a Surrogate Molecule of Glycerol for Mechanistic Studies of Selective Hydrodeoxygenation Reactions over Mo ₂ C and Cu/Mo ₂ C Surfaces

Journal Article · Wed Mar 20 04:00:00 EDT 2019 · ACS Sustainable Chemistry & Engineering

DOI:https://doi.org/10.1021/acssuschemeng.9b01051· OSTI ID:1610467

Lin, Zhexi ^[1]; Wan, Weiming ^[2]; ^[2]

Department of Chemical Engineering, Columbia University, 500 W. 120th Street, New York, New York 10027, United States; DOE/OSTI
Department of Chemical Engineering, Columbia University, 500 W. 120th Street, New York, New York 10027, United States

Not provided.

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Catalysis Center for Energy Innovation (CCEI); Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0001004

OSTI ID:: 1610467

Journal Information:: ACS Sustainable Chemistry & Engineering, Journal Name: ACS Sustainable Chemistry & Engineering Journal Issue: 9 Vol. 7; ISSN 2168-0485

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (41)

Glycerol fermentation in Klebsiella pneumoniae: functions of the coenzyme B12-dependent glycerol and diol dehydratases. Forage, R. G.; Foster, M. A. Journal of Bacteriology, Vol. 149, Issue 2 https://doi.org/10.1128/JB.149.2.413-419.1982	journal	January 1982
Promoting effect of boron oxide on Cu/SiO2 catalyst for glycerol hydrogenolysis to 1,2-propanediol Zhu, Shanhui; Gao, Xiaoqing; Zhu, Yulei Journal of Catalysis, Vol. 303 https://doi.org/10.1016/j.jcat.2013.03.018	journal	July 2013
Supported Cu catalysts for the selective hydrogenolysis of glycerol to propanediols Guo, Liyuan; Zhou, Jinxia; Mao, Jingbo Applied Catalysis A: General, Vol. 367, Issue 1-2 https://doi.org/10.1016/j.apcata.2009.07.040	journal	October 2009
Theoretical and Experimental Studies of C–C versus C–O Bond Scission of Ethylene Glycol Reaction Pathways via Metal-Modified Molybdenum Carbides Yu, Weiting; Salciccioli, Michael; Xiong, Ke ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs500124n	journal	April 2014
β-Hydroxypropionaldehyde, an intermediate in the formation of 1,3-propanediol by Aerobacter aerogenes Abeles, R. H.; Brownstein, A. M.; Randles, C. H. Biochimica et Biophysica Acta, Vol. 41, Issue 3 https://doi.org/10.1016/0006-3002(60)90054-8	journal	July 1960
Liquid-Phase Catalytic Processing of Biomass-Derived Oxygenated Hydrocarbons to Fuels and Chemicals Chheda, Juben N.; Huber, George W.; Dumesic, James A. Angewandte Chemie International Edition, Vol. 46, Issue 38, p. 7164-7183 https://doi.org/10.1002/anie.200604274	journal	September 2007
Understanding the Role of M/Pt(111) (M = Fe, Co, Ni, Cu) Bimetallic Surfaces for Selective Hydrodeoxygenation of Furfural Jiang, Zhifeng; Wan, Weiming; Lin, Zhexi ACS Catalysis, Vol. 7, Issue 9 https://doi.org/10.1021/acscatal.7b01682	journal	August 2017
Low-pressure hydrogenolysis of glycerol to propylene glycol Dasari, Mohanprasad A.; Kiatsimkul, Pim-Pahn; Sutterlin, Willam R. Applied Catalysis A: General, Vol. 281, Issue 1-2, p. 225-231 https://doi.org/10.1016/j.apcata.2004.11.033	journal	March 2005
Selective oxidation of glycerol to glyceric acid using a gold catalyst in aqueous sodium hydroxide Carrettin, Silvio; McMorn, Paul; Johnston, Peter Chemical Communications, Issue 7 https://doi.org/10.1039/b201112n	journal	March 2002
Reaction of Ethylene with Clean and Carbide-Modified Mo(110): Converting Surface Reactivities of Molybdenum to Pt-Group Metals Frühberger, B.; Chen, J. G. Journal of the American Chemical Society, Vol. 118, Issue 46 https://doi.org/10.1021/ja960656l	journal	January 1996
Bifunctional Catalysts for Upgrading of Biomass-Derived Oxygenates: A Review Robinson, Allison M.; Hensley, Jesse E.; Medlin, J. Will ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b00923	journal	July 2016
Dehydration of Glycerol to Acrolein over Hierarchical ZSM-5 Zeolites: Effects of Mesoporosity and Acidity Zhang, Hongbin; Hu, Zhijie; Huang, Liang ACS Catalysis, Vol. 5, Issue 4 https://doi.org/10.1021/cs5019953	journal	March 2015
Heterogeneous catalysis of the glycerol hydrogenolysis Nakagawa, Yoshinao; Tomishige, Keiichi Catalysis Science & Technology, Vol. 1, Issue 2 https://doi.org/10.1039/c0cy00054j	journal	January 2011
Controlling reaction pathways of selective C–O bond cleavage of glycerol Wan, Weiming; Ammal, Salai C.; Lin, Zhexi Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-07047-7	journal	November 2018
Optimization of Catalytic Glycerol Etherification with Ethanol in a Continuous Reactor Lemos, Caroline O. T.; Rade, Leticia L.; Barrozo, Marcos A. de S. Energy & Fuels, Vol. 31, Issue 5 https://doi.org/10.1021/acs.energyfuels.7b00194	journal	April 2017
Recent Advances in Hydrotreating of Pyrolysis Bio-Oil and Its Oxygen-Containing Model Compounds Wang, Huamin; Male, Jonathan; Wang, Yong ACS Catalysis, Vol. 3, Issue 5 https://doi.org/10.1021/cs400069z	journal	April 2013
Aqueous phase reforming of glycerol using doped graphenes as metal-free catalysts Esteve-Adell, Iván; Crapart, Bertrand; Primo, Ana Green Chemistry, Vol. 19, Issue 13 https://doi.org/10.1039/C7GC01058C	journal	January 2017
Biodiesel derived glycerol hydrogenolysis to 1,2-propanediol on Cu/MgO catalysts Yuan, Zhenle; Wang, Junhua; Wang, Lina Bioresource Technology, Vol. 101, Issue 18 https://doi.org/10.1016/j.biortech.2010.04.016	journal	September 2010
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering Huber, George W.; Iborra, Sara; Corma, Avelino Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098 https://doi.org/10.1021/cr068360d	journal	September 2006
Opportunities and challenges for biodiesel fuel Lin, Lin; Cunshan, Zhou; Vittayapadung, Saritporn Applied Energy, Vol. 88, Issue 4 https://doi.org/10.1016/j.apenergy.2010.09.029	journal	April 2011
Reactions of methanol and water over carbide-modified Mo() Hwu, Henry H.; Chen, Jingguang G. Surface Science, Vol. 536, Issue 1-3 https://doi.org/10.1016/S0039-6028(03)00607-1	journal	June 2003
Hydroxylated magnesium fluorides as environmentally friendly catalysts for glycerol acetylation Troncea, Simona B.; Wuttke, Stefan; Kemnitz, Erhard Applied Catalysis B: Environmental, Vol. 107, Issue 3-4 https://doi.org/10.1016/j.apcatb.2011.07.021	journal	September 2011
Selective hydrogenolysis of glycerol to propylene glycol on Cu–ZnO catalysts Wang, Shuai; Liu, Haichao Catalysis Letters, Vol. 117, Issue 1-2 https://doi.org/10.1007/s10562-007-9106-9	journal	April 2007
Enhancing H2 and CO Production from Glycerol Using Bimetallic Surfaces Skoplyak, Orest; Barteau, Mark A.; Chen, Jingguang G. ChemSusChem, Vol. 1, Issue 6 https://doi.org/10.1002/cssc.200800053	journal	June 2008
Ring‐Opening Reaction of Furfural and Tetrahydrofurfuryl Alcohol on Hydrogen‐Predosed Iridium(1 1 1) and Cobalt/Iridium(1 1 1) Surfaces Wan, Weiming; Jenness, Glen R.; Xiong, Ke ChemCatChem, Vol. 9, Issue 9 https://doi.org/10.1002/cctc.201601646	journal	March 2017
Highly Dispersed Silica-Supported Copper Nanoparticles Prepared by Precipitation−Gel Method: A Simple but Efficient and Stable Catalyst for Glycerol Hydrogenolysis Huang, Zhiwei; Cui, Fang; Kang, Haixiao Chemistry of Materials, Vol. 20, Issue 15 https://doi.org/10.1021/cm8006233	journal	August 2008
Novel biocatalysts for glycerol conversion into 2,3-butanediol Ripoll, Vanessa; de Vicente, Gonzalo; Morán, Bruno Process Biochemistry, Vol. 51, Issue 6 https://doi.org/10.1016/j.procbio.2016.03.006	journal	June 2016
Carbon Nanotube-Supported RuFe Bimetallic Nanoparticles as Efficient and Robust Catalysts for Aqueous-Phase Selective Hydrogenolysis of Glycerol to Glycols Li, Bodong; Wang, Juan; Yuan, Youzhu ACS Catalysis, Vol. 1, Issue 11 https://doi.org/10.1021/cs200386q	journal	October 2011
Screening of bacterial strains capable of converting biodiesel-derived raw glycerol into 1,3-propanediol, 2,3-butanediol and ethanol Metsoviti, Maria; Paramithiotis, Spiros; Drosinos, Eleftherios H. Engineering in Life Sciences, Vol. 12, Issue 1 https://doi.org/10.1002/elsc.201100058	journal	November 2011
Hydroxyacetone: A Glycerol-Based Platform for Electrocatalytic Hydrogenation and Hydrodeoxygenation Processes Sauter, Waldemar; Bergmann, Olaf L.; Schröder, Uwe ChemSusChem, Vol. 10, Issue 15 https://doi.org/10.1002/cssc.201700996	journal	July 2017
The adsorption and reaction of 1,2-propanediol on Ag(110) under oxygen lean conditions Ayre, Caroline R.; Madix, Robert J. Surface Science, Vol. 303, Issue 3 https://doi.org/10.1016/0039-6028(94)90776-5	journal	February 1994
Substrate specificity of coenzyme B12-dependent diol dehydrase: Glycerol as both a good substrate and a potent inactivator Toraya, Tetsuo; Shirakashi, Tadahiro; Kosuga, Tsunemitsu Biochemical and Biophysical Research Communications, Vol. 69, Issue 2 https://doi.org/10.1016/0006-291X(76)90546-5	journal	March 1976
A comparative study on catalytic properties of solid acid catalysts for glycerol acetylation at low temperatures Kim, Inbae; Kim, Jaesung; Lee, Doohwan Applied Catalysis B: Environmental, Vol. 148-149 https://doi.org/10.1016/j.apcatb.2013.11.008	journal	April 2014
Electrocatalytic selective oxidation of glycerol to tartronate on Au/C anode catalysts in anion exchange membrane fuel cells with electricity cogeneration Qi, Ji; Xin, Le; Chadderdon, David J. Applied Catalysis B: Environmental, Vol. 154-155 https://doi.org/10.1016/j.apcatb.2014.02.040	journal	July 2014
Cu:Al Nano Catalyst for Selective Hydrogenolysis of Glycerol to 1,2-Propanediol Mane, Rasika B.; Hengne, Amol M.; Ghalwadkar, Ajay A. Catalysis Letters, Vol. 135, Issue 1-2 https://doi.org/10.1007/s10562-010-0276-5	journal	January 2010
Recent Developments in the Field of Catalytic Dehydration of Glycerol to Acrolein Katryniok, Benjamin; Paul, Sébastien; Dumeignil, Franck ACS Catalysis, Vol. 3, Issue 8 https://doi.org/10.1021/cs400354p	journal	July 2013
In Situ X-ray Absorption Fine Structure Studies on the Effect of pH on Pt Electronic Density during Aqueous Phase Reforming of Glycerol Karim, Ayman M.; Howard, Christopher; Roberts, Benjamin ACS Catalysis, Vol. 2, Issue 11 https://doi.org/10.1021/cs3005049	journal	September 2012
Hydrodeoxygenation of biomass-derived oxygenates over metal carbides: from model surfaces to powder catalysts Lin, Zhexi; Chen, Rui; Qu, Zhenping Green Chemistry, Vol. 20, Issue 12 https://doi.org/10.1039/C8GC00239H	journal	January 2018
Etherification of glycerol with isobutene on sulfonated graphene: reaction and separation Zhou, Jinxia; Wang, Yu; Guo, Xinwen Green Chem., Vol. 16, Issue 11 https://doi.org/10.1039/C4GC01044B	journal	January 2014
Dehydration–hydrogenation of glycerol into 1,2-propanediol at ambient hydrogen pressure Akiyama, Masaki; Sato, Satoshi; Takahashi, Ryoji Applied Catalysis A: General, Vol. 371, Issue 1-2 https://doi.org/10.1016/j.apcata.2009.09.029	journal	December 2009
Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production Okoye, P. U.; Hameed, B. H. Renewable and Sustainable Energy Reviews, Vol. 53 https://doi.org/10.1016/j.rser.2015.08.064	journal	January 2016

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1,2-Propanediol as a Surrogate Molecule of Glycerol for Mechanistic Studies of Selective Hydrodeoxygenation Reactions over Mo ₂ C and Cu/Mo ₂ C Surfaces