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Photolysis of Tp'Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C–H bonds

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/c9dt01802f· OSTI ID:1610060
 [1];  [2]
  1. Department of Chemistry; University of Rochester; Rochester; USA; DOE/OSTI
  2. Department of Chemistry; University of Rochester; Rochester; USA
+ Show Author Affiliations

The competitive activation of the various C–H bonds found in ketones and esters by a trispyrazolylborate rhodium complex are compared.

Research Organization:
Univ. of Rochester, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-86ER13569
OSTI ID:
1610060
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 29 Vol. 48; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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