A hydrated crystalline calcium carbonate phase: Calcium carbonate hemihydrate

Zou, Zhaoyong; Habraken, Wouter J.  E.  M.; Matveeva, Galina; Jensen, Anders C.  S.; Bertinetti, Luca; Hood, Matthew A.; Sun, Chang-yu; Gilbert, Pupa U.  P.  A.; Polishchuk, Iryna; Pokroy, Boaz; Mahamid, Julia; Politi, Yael; Weiner, Steve; Werner, Peter; Bette, Sebastian; Dinnebier, Robert; Kolb, Ute; Zolotoyabko, Emil; Fratzl, Peter

doi:10.1126/science.aav0210

Title: A hydrated crystalline calcium carbonate phase: Calcium carbonate hemihydrate

Journal Article · Thu Jan 24 00:00:00 EST 2019 · Science

DOI:https://doi.org/10.1126/science.aav0210· OSTI ID:1609807

;

; Bertinetti, Luca;

; Sun, Chang-yu;

;

; Weiner, Steve; Werner, Peter; Bette, Sebastian;

; Kolb, Ute; Zolotoyabko, Emil;

As one of the most abundant materials in the world, calcium carbonate, CaCO₃, is the main constituent of the skeletons and shells of various marine organisms. It is used in the cement industry and plays a crucial role in the global carbon cycle and formation of sedimentary rocks. For more than a century, only three polymorphs of pure CaCO₃—calcite, aragonite, and vaterite—were known to exist at ambient conditions, as well as two hydrated crystal phases, monohydrocalcite (CaCO₃·1H₂O) and ikaite (CaCO₃·6H₂O). While investigating the role of magnesium ions in crystallization pathways of amorphous calcium carbonate, we unexpectedly discovered an unknown crystalline phase, hemihydrate CaCO₃·½H₂O, with monoclinic structure. This discovery may have important implications in biomineralization, geology, and industrial processes based on hydration of CaCO₃.

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Research Organization:: Univ. of Wisconsin, Madison, WI (United States); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-07ER15899; AC02-05CH11231

OSTI ID:: 1609807

Journal Information:: Science, Vol. 363, Issue 6425; ISSN 0036-8075

Publisher:: AAAS

Country of Publication:: United States

Language:: English

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