Hierarchical assembly of ZnO nanowire trunks decorated with ZnO nanosheets for lithium ion battery anodes

Kim, Dongheun; Shin, Sun Hae Ra; Kim, Yeonhoo; Crossley, Kenneth; Kim, Yerim; Han, Hyungkyu; Yoo, Jinkyoung

doi:10.1039/D0RA00372G

Title: Hierarchical assembly of ZnO nanowire trunks decorated with ZnO nanosheets for lithium ion battery anodes

Journal Article · Fri Apr 03 00:00:00 EDT 2020 · RSC Advances

DOI:https://doi.org/10.1039/D0RA00372G· OSTI ID:1608164

Kim, Dongheun ^[1]; Shin, Sun Hae Ra ^[1]; Kim, Yeonhoo ^[1];

^[1]; Kim, Yerim ^[1];

^[1];

^[1]

Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, USA

Hierarchical architectures composed of nanomaterials in different forms are essential to improve the performance of lithium-ion battery (LIB) anodes. Here, we systematically studied the effects of hierarchical ZnO nanostructures on the electrochemical performance of LIBs. ZnO nanowire (NW) trunks were decorated with ZnO NWs or ZnO nanosheets (NSs) by successive hydrothermal synthesis to create hierarchical three-dimensional nanostructures. The branched ZnO NSs on the ZnO NW trunk exhibited a two-fold higher specific gravimetric capacity compared to ZnO NWs and branched ZnO NWs on ZnO NW trunks after 100 cycles of charging–discharging at 0.2C (197.4 mA g^–1). The improvement in battery anode performance is attributable to the increased interfacial area between the electrodes and electrolyte, and the void space of the branched NSs that facilitates lithium ion transport and volume changes during cycling.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies (CINT)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: 89233218CNA000001; AC52-06NA25396

OSTI ID:: 1608164

Alternate ID(s):: OSTI ID: 1688746

Report Number(s):: LA-UR-19-28270; RSCACL

Journal Information:: RSC Advances, Journal Name: RSC Advances Vol. 10 Journal Issue: 23; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 7 works

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