Ferroic twin domains in metal halide perovskites

Liu, Yongtao; Belianinov, Alex; Collins, Liam; Proksch, Roger; Ievlev, Anton; Hu, Bin; Kalinin, Sergei V.; Ovchinnikova, Olga S.

doi:10.1557/adv.2019.358

Ferroic twin domains in metal halide perovskites

Journal Article · Mon Sep 23 00:00:00 EDT 2019 · MRS Advances

DOI:https://doi.org/10.1557/adv.2019.358· OSTI ID:1606920

^[1]; ^[2]; ^[2]; Proksch, Roger ^[3]; ^[2]; Hu, Bin ^[4]; ^[2]; ^[2]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
Asylum Research, Santa Barbara, CA (United States)
Univ. of Tennessee, Knoxville, TN (United States)

An emerging family of materials—metal halide perovskites (MHPs)—have made incredible achievements in optoelectronics in the past decade. Owing to its potential role in optoelectronic properties, the ferroic state of MHPs has been investigated by lots of researchers. Here in this paper, we review the literature regarding investigations into possible ferroic behaviors in MHPs. We summarize the recent discoveries of ferroic twin domains in MHPs. We examine the ferroelasticity and the ferroelectricity of these twin domains. Several properties relevant to the twin domains are critically analyzed, including crystallographic structure, mechanical variation, chemical variation, etc. Finally, we discussed the effects of these domains on materials’ optoelectronic properties and their potential roles in photovoltaic action.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1606920

Journal Information:: MRS Advances, Journal Name: MRS Advances Journal Issue: 51-52 Vol. 4; ISSN 2059-8521

Publisher:: Materials Research Society (MRS)Copyright Statement

Country of Publication:: United States

Language:: English

References (54)

Photophysics of Organic-Inorganic Hybrid Lead Iodide Perovskite Single Crystals Fang, Hong-Hua; Raissa, Raissa; Abdu-Aguye, Mustapha Advanced Functional Materials, Vol. 25, Issue 16 https://doi.org/10.1002/adfm.201404421	journal	February 2015
Room-Temperature-Operated Ultrasensitive Broadband Photodetectors by Perovskite Incorporated with Conjugated Polymer and Single-Wall Carbon Nanotubes Xu, Wenzhan; Guo, Yikun; Zhang, Xiaotao Advanced Functional Materials, Vol. 28, Issue 7 https://doi.org/10.1002/adfm.201705541	journal	December 2017
Tailoring the Performances of Lead Halide Perovskite Devices with Electron-Beam Irradiation Yi, Ningbo; Wang, Shuai; Duan, Zonghui Advanced Materials, Vol. 29, Issue 34 https://doi.org/10.1002/adma.201701636	journal	July 2017
Exploring Anomalous Polarization Dynamics in Organometallic Halide Perovskites Ahmadi, Mahshid; Collins, Liam; Puretzky, Alexander Advanced Materials, Vol. 30, Issue 11 https://doi.org/10.1002/adma.201705298	journal	January 2018
Theoretical Prediction of Chiral 3D Hybrid Organic–Inorganic Perovskites Long, Guankui; Zhou, Yecheng; Zhang, Mingtao Advanced Materials, Vol. 31, Issue 17 https://doi.org/10.1002/adma.201807628	journal	March 2019
Highly Efficient and Stable Solar Cells Based on Crystalline Oriented 2D/3D Hybrid Perovskite Zhou, Tong; Lai, Hongtao; Liu, Tingting Advanced Materials https://doi.org/10.1002/adma.201901242	journal	June 2019
Light‐Ferroic Interaction in Hybrid Organic–Inorganic Perovskites Liu, Yongtao; Ievlev, Anton V.; Collins, Liam Advanced Optical Materials, Vol. 7, Issue 23 https://doi.org/10.1002/adom.201901451	journal	September 2019
Efficient Perovskite Solar Cells Fabricated by Co Partially Substituted Hybrid Perovskite Xu, Wenzhan; Zheng, Luyao; Zhang, Xiaotao Advanced Energy Materials, Vol. 8, Issue 14 https://doi.org/10.1002/aenm.201703178	journal	January 2018
Probing the Microstructure of Methylammonium Lead Iodide Perovskite Solar Cells Leonhard, Tobias; Schulz, Alexander D.; Röhm, Holger Energy Technology, Vol. 7, Issue 3 https://doi.org/10.1002/ente.201800989	journal	March 2019
Twinning in ferroelectric and ferroelastic ceramics: stress relief Arlt, G. Journal of Materials Science, Vol. 25, Issue 6 https://doi.org/10.1007/BF00584864	journal	June 1990
Mapping the domain distribution at ferroelectric surfaces by scanning force microscopy Abplanalp, M.; Eng, L. M.; Günter, P. Applied Physics A: Materials Science & Processing, Vol. 66, Issue 7 https://doi.org/10.1007/s003390051136	journal	March 1998
On the importance of ferroelectric domains for the performance of perovskite solar cells Rossi, Daniele; Pecchia, Alessandro; Maur, Matthias Auf der Nano Energy, Vol. 48 https://doi.org/10.1016/j.nanoen.2018.02.049	journal	June 2018
Multi-Model Imaging of Local Chemistry and Ferroic Properties of Hybrid Organic-Inorganic Perovskites Liu, Yongtao; Ievlev, Anton V.; Collins, Liam Microscopy and Microanalysis, Vol. 25, Issue S2 https://doi.org/10.1017/S1431927619011115	journal	August 2019
Cesium Halides-Assisted Crystal Growth of Perovskite Films for Efficient Planar Heterojunction Solar Cells Liu, Tingting; Lai, Hongtao; Wan, Xiangjian Chemistry of Materials, Vol. 30, Issue 15 https://doi.org/10.1021/acs.chemmater.8b02002	journal	July 2018
Ferroelastic Fingerprints in Methylammonium Lead Iodide Perovskite Hermes, Ilka M.; Bretschneider, Simon A.; Bergmann, Victor W. The Journal of Physical Chemistry C, Vol. 120, Issue 10 https://doi.org/10.1021/acs.jpcc.5b11469	journal	January 2016
Enhanced Photovoltaic Properties Induced by Ferroelectric Domain Structures in Organometallic Halide Perovskites Bi, Fuzhen; Markov, Stanislav; Wang, Rulin The Journal of Physical Chemistry C, Vol. 121, Issue 21 https://doi.org/10.1021/acs.jpcc.7b03091	journal	May 2017
Ferroelectric Domains May Lead to Two-Dimensional Confinement of Holes, but not of Electrons, in CH 3 NH 3 PbI 3 Perovskite Montero-Alejo, Ana L.; Menéndez-Proupin, E.; Palacios, P. The Journal of Physical Chemistry C, Vol. 121, Issue 48 https://doi.org/10.1021/acs.jpcc.7b09625	journal	November 2017
Probing Facet-Dependent Surface Defects in MAPbI ₃ Perovskite Single Crystals Kim, Dohyung; Yun, Jung-Ho; Lyu, Miaoqiang The Journal of Physical Chemistry C, Vol. 123, Issue 23 https://doi.org/10.1021/acs.jpcc.9b00943	journal	May 2019
Role of Ferroelectric Nanodomains in the Transport Properties of Perovskite Solar Cells Pecchia, Alessandro; Gentilini, Desirée; Rossi, Daniele Nano Letters, Vol. 16, Issue 2 https://doi.org/10.1021/acs.nanolett.5b03957	journal	January 2016
Orientation of Ferroelectric Domains and Disappearance upon Heating Methylammonium Lead Triiodide Perovskite from Tetragonal to Cubic Phase Vorpahl, Sarah M.; Giridharagopal, Rajiv; Eperon, Giles E. ACS Applied Energy Materials, Vol. 1, Issue 4 https://doi.org/10.1021/acsaem.7b00330	journal	March 2018
Determination of the True Lateral Grain Size in Organic–Inorganic Halide Perovskite Thin Films MacDonald, Gordon A.; Heveran, Chelsea M.; Yang, Mengjin ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b11434	journal	April 2017
Environmental Gating and Galvanic Effects in Single Crystals of Organic–Inorganic Halide Perovskites Ahmadi, Mahshid; Muckley, Eric S.; Ivanov, Ilia N. ACS Applied Materials & Interfaces, Vol. 11, Issue 16 https://doi.org/10.1021/acsami.8b21112	journal	April 2019
Differentiating Ferroelectric and Nonferroelectric Electromechanical Effects with Scanning Probe Microscopy Balke, Nina; Maksymovych, Petro; Jesse, Stephen ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b02227	journal	May 2015
Quantitative Electromechanical Atomic Force Microscopy Collins, Liam; Liu, Yongtao; Ovchinnikova, Olga S. ACS Nano, Vol. 13, Issue 7 https://doi.org/10.1021/acsnano.9b02883	journal	July 2019
Lattice Energies of Crystals with Multiple Ions: A Generalized Kapustinskii Equation Glasser, Leslie Inorganic Chemistry, Vol. 34, Issue 20 https://doi.org/10.1021/ic00124a003	journal	September 1995
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
Two-Dimensional Ruddlesden–Popper Perovskite with Nanorod-like Morphology for Solar Cells with Efficiency Exceeding 15% Lai, Hongtao; Kan, Bin; Liu, Tingting Journal of the American Chemical Society, Vol. 140, Issue 37 https://doi.org/10.1021/jacs.8b04604	journal	August 2018
Ferroelectric Domain Wall Induced Band Gap Reduction and Charge Separation in Organometal Halide Perovskites Liu, Shi; Zheng, Fan; Koocher, Nathan Z. The Journal of Physical Chemistry Letters, Vol. 6, Issue 4 https://doi.org/10.1021/jz502666j	journal	February 2015
Direct observation of intrinsic twin domains in tetragonal CH3NH3PbI3 Rothmann, Mathias Uller; Li, Wei; Zhu, Ye Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14547	journal	February 2017
The dynamics of methylammonium ions in hybrid organic–inorganic perovskite solar cells Leguy, Aurelien M. A.; Frost, Jarvist Moore; McMahon, Andrew P. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8124	journal	May 2015
Light- and bias-induced structural variations in metal halide perovskites Kim, Dohyung; Yun, Jae Sung; Sharma, Pankaj Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08364-1	journal	January 2019
Phase segregation due to ion migration in all-inorganic mixed-halide perovskite nanocrystals Zhang, Huichao; Fu, Xu; Tang, Ying Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09047-7	journal	March 2019
Ferroic domains regulate photocurrent in single-crystalline CH3NH3PbI3 films self-grown on FTO/TiO2 substrate Huang, Boyuan; Kong, Guoli; Esfahani, Ehsan Nasr npj Quantum Materials, Vol. 3, Issue 1 https://doi.org/10.1038/s41535-018-0104-5	journal	June 2018
Chemical nature of ferroelastic twin domains in CH3NH3PbI3 perovskite Liu, Yongtao; Collins, Liam; Proksch, Roger Nature Materials, Vol. 17, Issue 11 https://doi.org/10.1038/s41563-018-0152-z	journal	August 2018
Large electrostrictive response in lead halide perovskites Chen, Bo; Li, Tao; Dong, Qingfeng Nature Materials, Vol. 17, Issue 11 https://doi.org/10.1038/s41563-018-0170-x	journal	September 2018
Reply to: On the ferroelectricity of CH3NH3PbI3 perovskites Liu, Yongtao; Collins, Liam; Proksch, Roger Nature Materials, Vol. 18, Issue 10 https://doi.org/10.1038/s41563-019-0481-6	journal	September 2019
Spin control in reduced-dimensional chiral perovskites Long, Guankui; Jiang, Chongyun; Sabatini, Randy Nature Photonics, Vol. 12, Issue 9 https://doi.org/10.1038/s41566-018-0220-6	journal	August 2018
Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent Lin, Kebin; Xing, Jun; Quan, Li Na Nature, Vol. 562, Issue 7726 https://doi.org/10.1038/s41586-018-0575-3	journal	October 2018
Domain Walls Conductivity in Hybrid Organometallic Perovskites and Their Essential Role in CH3NH3PbI3 Solar Cell High Performance Rashkeev, Sergey N.; El-Mellouhi, Fedwa; Kais, Sabre Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep11467	journal	June 2015
Antiferroelectric Nature of CH3NH3PbI3−xClx Perovskite and Its Implication for Charge Separation in Perovskite Solar Cells Sewvandi, Galhenage A.; Kodera, Kei; Ma, Hao Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep30680	journal	July 2016
Complete structure and cation orientation in the perovskite photovoltaic methylammonium lead iodide between 100 and 352 K Weller, Mark T.; Weber, Oliver J.; Henry, Paul F. Chemical Communications, Vol. 51, Issue 20 https://doi.org/10.1039/C4CC09944C	journal	January 2015
Ferroelectric domains in methylammonium lead iodide perovskite thin-films Röhm, Holger; Leonhard, Tobias; Hoffmann, Michael J. Energy & Environmental Science, Vol. 10, Issue 4 https://doi.org/10.1039/C7EE00420F	journal	January 2017
Effect of phase transition on the surface potential of the BaTiO3 (100) surface by variable temperature scanning surface potential microscopy Kalinin, Sergei V.; Bonnell, Dawn A. Journal of Applied Physics, Vol. 87, Issue 8 https://doi.org/10.1063/1.372440	journal	April 2000
Ferroelectric or non-ferroelectric: Why so many materials exhibit “ferroelectricity” on the nanoscale Vasudevan, Rama K.; Balke, Nina; Maksymovych, Peter Applied Physics Reviews, Vol. 4, Issue 2 https://doi.org/10.1063/1.4979015	journal	June 2017
Dynamic behavior of CH ₃ NH ₃ PbI ₃ perovskite twin domains Liu, Yongtao; Collins, Liam; Belianinov, Alex Applied Physics Letters, Vol. 113, Issue 7 https://doi.org/10.1063/1.5041256	journal	August 2018
Ferroelasticity and related properties of crystals Wadhawan, Vinod K. Phase Transitions, Vol. 3, Issue 1 https://doi.org/10.1080/01411598208241323	journal	January 1982
Dynamic behaviour in piezoresponse force microscopy Jesse, Stephen; Baddorf, Arthur P.; Kalinin, Sergei V. Nanotechnology, Vol. 17, Issue 6 https://doi.org/10.1088/0957-4484/17/6/014	journal	February 2006
Time resolved surface photovoltage measurements using a big data capture approach to KPFM Collins, Liam; Ahmadi, Mahshid; Qin, Jiajun Nanotechnology, Vol. 29, Issue 44 https://doi.org/10.1088/1361-6528/aad873	journal	September 2018
Surface-screening mechanisms in ferroelectric thin films and their effect on polarization dynamics and domain structures Kalinin, Sergei V.; Kim, Yunseok; Fong, Dillon D. Reports on Progress in Physics, Vol. 81, Issue 3 https://doi.org/10.1088/1361-6633/aa915a	journal	January 2018
Thermodynamics of electromechanically coupled mixed ionic-electronic conductors: Deformation potential, Vegard strains, and flexoelectric effect Morozovska, A. N.; Eliseev, E. A.; Tagantsev, A. K. Physical Review B, Vol. 83, Issue 19 https://doi.org/10.1103/PhysRevB.83.195313	journal	May 2011
Local Polar Fluctuations in Lead Halide Perovskite Crystals Yaffe, Omer; Guo, Yinsheng; Tan, Liang Z. Physical Review Letters, Vol. 118, Issue 13 https://doi.org/10.1103/PhysRevLett.118.136001	journal	March 2017
A decade of piezoresponse force microscopy: progress, challenges, and opportunities Kalinin, Sergei; Rar, Andrei; Jesse, Stephen IEEE Transactions on Ultrasonics, Ferroelectrics and Frequency Control, Vol. 53, Issue 12 https://doi.org/10.1109/TUFFC.2006.169	journal	December 2006
CH ₃ NH ₃ PbI ₃ perovskites: Ferroelasticity revealed Strelcov, Evgheni; Dong, Qingfeng; Li, Tao Science Advances, Vol. 3, Issue 4 https://doi.org/10.1126/sciadv.1602165	journal	April 2017
Large polarons in lead halide perovskites Miyata, Kiyoshi; Meggiolaro, Daniele; Trinh, M. Tuan Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1701217	journal	August 2017

Cited By (1)

Twin domains modulate light-matter interactions in metal halide perovskites Liu, Yongtao; Li, Mingxing; Wang, Miaosheng APL Materials, Vol. 8, Issue 1 https://doi.org/10.1063/1.5127866	journal	January 2020

Similar Records

Ferroic Halide Perovskite Optoelectronics

Journal Article · Thu Jun 03 20:00:00 EDT 2021 · Advanced Functional Materials · OSTI ID:1819578

Correlating Crystallographic Orientation and Ferroic Properties of Twin Domains in Metal Halide Perovskites

Journal Article · Thu Mar 25 20:00:00 EDT 2021 · ACS Nano · OSTI ID:1819579

Twin domains modulate light-matter interactions in metal halide perovskites

Journal Article · Thu Jan 09 19:00:00 EST 2020 · APL Materials · OSTI ID:1606786

Related Subjects

36 MATERIALS SCIENCE

Ferroic twin domains in metal halide perovskites

Citation Formats

References (54)

Cited By (1)

Similar Records

Related Subjects