Visualization of supercritical water pseudo-boiling at Widom line crossover

Maxim, Florentina; Contescu, Cristian; Boillat, Pierre; Niceno, Bojan; Karalis, Konstantinos; Testino, Andrea; Ludwig, Christian

doi:10.1038/s41467-019-12117-5

Title: Visualization of supercritical water pseudo-boiling at Widom line crossover

Journal Article · Tue Sep 17 00:00:00 EDT 2019 · Nature Communications

DOI:https://doi.org/10.1038/s41467-019-12117-5· OSTI ID:1606894

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Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Bioenergy and Catalysis (LBK), ENE Division; Inst. of Physical Chemistry "Ilie Murgulescu", Bucharest, (Romania)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Electrochemistry Lab. (LEC), ENE Division, and Lab. for Neutron Scattering and Imaging (LNS), NUM Division
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Scientific Computing and Modelling (LSM), NES Division; Federal Inst. of Technology, Zurich (Switzerland)
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Scientific Computing and Modelling (LSM), NES Division
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Bioenergy and Catalysis (LBK), ENE Division
Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Bioenergy and Catalysis (LBK), ENE Division; Ecole Polytechnique Federale Lausanne (Switzlerland)

Supercritical water is a green solvent used in many technological applications including materials synthesis, nuclear engineering, bioenergy, or waste treatment and it occurs in nature. Despite its relevance in natural systems and technical applications, the supercritical state of water is still not well understood. Recent theories predict that liquid-like (LL) and gas-like (GL) supercritical water are metastable phases, and that the so-called Widom line zone is marking the crossover between LL and GL behavior of water. With neutron imaging techniques, we succeed to monitor density fluctuations of supercritical water while the system evolves rapidly from LL to GL as the Widom line is crossed during isobaric heating. Our observations show that the Widom line of water can be identified experimentally and they are in agreement with the current theory of supercritical fluid pseudo-boiling. This fundamental understanding allows optimizing and developing new technologies using supercritical water as a solvent.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Swiss National Science Foundation (SNSF)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1606894

Journal Information:: Nature Communications, Vol. 10, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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References (46)

First developments towards closing the nutrient cycle in a biofuel production process Bagnoud-Velásquez, M.; Schmid-Staiger, U.; Peng, G. Algal Research, Vol. 8 https://doi.org/10.1016/j.algal.2014.12.012	journal	March 2015
Water adsorption in carbons described by the dubinin–astakhov and dubinin–serpinski equations Stoeckli, Fritz; Currit, Laurent; Laederach, Alain J. Chem. Soc., Faraday Trans., Vol. 90, Issue 24 https://doi.org/10.1039/ft9949003689	journal	January 1994
Surface Tension and Molecular Correlations near the Critical Point Widom, B. The Journal of Chemical Physics, Vol. 43, Issue 11 https://doi.org/10.1063/1.1696617	journal	December 1965
Relation between the Widom line and the dynamic crossover in systems with a liquid-liquid phase transition Xu, L.; Kumar, P.; Buldyrev, S. V. Proceedings of the National Academy of Sciences, Vol. 102, Issue 46 https://doi.org/10.1073/pnas.0507870102	journal	November 2005
Widom Delta of Supercritical Gas–Liquid Coexistence Ha, Min Young; Yoon, Tae Jun; Tlusty, Tsvi The Journal of Physical Chemistry Letters, Vol. 9, Issue 7 https://doi.org/10.1021/acs.jpclett.8b00430	journal	March 2018
Biofuels Production by Biomass Gasification: A Review Molino, Antonio; Larocca, Vincenzo; Chianese, Simeone Energies, Vol. 11, Issue 4 https://doi.org/10.3390/en11040811	journal	March 2018
Kinetically Forbidden Transformations of Water Molecular Assemblies in Hydrophobic Micropores Ohba, Tomonori; Kaneko, Katsumi Langmuir, Vol. 27, Issue 12 https://doi.org/10.1021/la201115s	journal	June 2011
Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies Peterson, Andrew A.; Vogel, Frédéric; Lachance, Russell P. Energy & Environmental Science, Vol. 1, Issue 1, p. 32-65 https://doi.org/10.1039/b810100k	journal	January 2008
The ICON beamline – A facility for cold neutron imaging at SINQ Kaestner, A. P.; Hartmann, S.; Kühne, G. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 659, Issue 1 https://doi.org/10.1016/j.nima.2011.08.022	journal	December 2011
Frame overlap Bragg edge imaging Busi, Matteo; Čapek, Jan; Polatidis, Efthymios Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-71705-4	journal	September 2020
The Potential Theory of Adsorption of Gases and Vapors for Adsorbents with Energetically Nonuniform Surfaces. Dubinin, M. M. Chemical Reviews, Vol. 60, Issue 2 https://doi.org/10.1021/cr60204a006	journal	April 1960
Supercritical Water as a Solvent Weingaertner, Hermann; Franck, Ernst Ulrich ChemInform, Vol. 36, Issue 31 https://doi.org/10.1002/chin.200531259	journal	August 2005
Widom delta of supercritical gas-liquid coexistence Ha, Min Young; Yoon, Tae Jun; Tlusty, Tsvi arXiv https://doi.org/10.48550/arxiv.1801.05557	text	January 2018
Equation of State in the Neighborhood of the Critical Point Widom, B. The Journal of Chemical Physics, Vol. 43, Issue 11 https://doi.org/10.1063/1.1696618	journal	December 1965
Water adsorption in active carbons described by the Dubinin–Astakhov equation Stoeckli, Fritz; Jakubov, Timur; Lavanchy, André J. Chem. Soc., Faraday Trans., Vol. 90, Issue 5 https://doi.org/10.1039/FT9949000783	journal	January 1994
Supercritical water gasification Kruse, Andrea Biofuels, Bioproducts and Biorefining, Vol. 2, Issue 5 https://doi.org/10.1002/bbb.93	journal	September 2008
Mechanism of heterogeneous adsorption in the storage of hydrogen in carbon fibers activated with supercritical water and steam Salvador, F.; Montero, J.; Sánchez-Montero, M. J. International Journal of Hydrogen Energy, Vol. 36, Issue 13 https://doi.org/10.1016/j.ijhydene.2011.03.079	journal	July 2011
Organic Chemical Reactions in Supercritical Water Savage, Phillip E. Chemical Reviews, Vol. 99, Issue 2 https://doi.org/10.1021/cr9700989	journal	February 1999
Treatment of municipal sewage sludge in supercritical water: A review Qian, Lili; Wang, Shuzhong; Xu, Donghai Water Research, Vol. 89 https://doi.org/10.1016/j.watres.2015.11.047	journal	February 2016
Understanding biomass fractionation in subcritical & supercritical water Cocero, María José; Cabeza, Álvaro; Abad, Nerea The Journal of Supercritical Fluids, Vol. 133 https://doi.org/10.1016/j.supflu.2017.08.012	journal	March 2018
The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use Wagner, W.; Pruß, A. Journal of Physical and Chemical Reference Data, Vol. 31, Issue 2 https://doi.org/10.1063/1.1461829	journal	June 2002
Chasing quantitative biases in neutron imaging with scintillator-camera detectors: a practical method with black body grids Boillat, P.; Carminati, C.; Schmid, F. Optics Express, Vol. 26, Issue 12 https://doi.org/10.1364/oe.26.015769	journal	January 2018
Membrane distillation: Perspectives for sustainable and improved desalination González, Daniel; Amigo, José; Suárez, Francisco Renewable and Sustainable Energy Reviews, Vol. 80 https://doi.org/10.1016/j.rser.2017.05.078	journal	December 2017
Structural mechanism of water adsorption in hydrophobic micropores from in situ small angle X-ray scattering Iiyama, T.; Ruike, M.; Kaneko, K. Chemical Physics Letters, Vol. 331, Issue 5-6 https://doi.org/10.1016/s0009-2614(00)01195-7	journal	December 2000
The Widom line as the crossover between liquid-like and gas-like behaviour in supercritical fluids Simeoni, G. G.; Bryk, T.; Gorelli, F. A. Nature Physics, Vol. 6, Issue 7 https://doi.org/10.1038/nphys1683	journal	June 2010
Production methods for nanodrug particles using the bottom-up approach Chan, Hak-Kim; Kwok, Philip Chi Lip Advanced Drug Delivery Reviews, Vol. 63, Issue 6 https://doi.org/10.1016/j.addr.2011.03.011	journal	May 2011
Total Neutron Cross Section of Water Neill, J. M.; Russell, J. L.; Brown, J. R. Nuclear Science and Engineering, Vol. 33, Issue 2 https://doi.org/10.13182/NSE68-A20669	journal	August 1968
Green materials synthesis with supercritical water Adschiri, Tadafumi; Lee, Youn-Woo; Goto, Motonobu Green Chemistry, Vol. 13, Issue 6 https://doi.org/10.1039/c1gc15158d	journal	January 2011
Geologic controls on supercritical geothermal resources above magmatic intrusions Scott, Samuel; Driesner, Thomas; Weis, Philipp Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8837	journal	July 2015
A novel process and material for the separation of carbon dioxide and hydrogen sulfide gas mixtures Burchell, T. D.; Judkins, R. R.; Rogers, M. R. Carbon, Vol. 35, Issue 9 https://doi.org/10.1016/S0008-6223(97)00077-8	journal	January 1997
Neutron radiography and numerical simulation of mixing behavior in a reactor for supercritical hydrothermal synthesis Sugioka, Ken-ichi; Ozawa, Kyohei; Tsukada, Takao AIChE Journal, Vol. 60, Issue 3 https://doi.org/10.1002/aic.14313	journal	December 2013
Properties of the Radiography Facility Neutra at sinq and its Potential for use as European Reference Facility Lehmann, E. H.; Vontobel, P.; Wiezel, L. Nondestructive Testing and Evaluation, Vol. 16, Issue 2-6 https://doi.org/10.1080/10589750108953075	journal	January 2001
Equilibration-time and pore-width dependent hysteresis of water adsorption isotherm on hydrophobic microporous carbons Nakamura, M.; Ohba, T.; Branton, P. Carbon, Vol. 48, Issue 1 https://doi.org/10.1016/j.carbon.2009.09.008	journal	January 2010
Widom line and dynamical crossovers as routes to understand supercritical water Gallo, P.; Corradini, D.; Rovere, M. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6806	journal	December 2014
Going supercritical McMillan, Paul F.; Stanley, H. Eugene Nature Physics, Vol. 6, Issue 7 https://doi.org/10.1038/nphys1711	journal	July 2010
Clustering of water molecules in ultramicroporous carbon: In-situ small-angle neutron scattering Bahadur, J.; Contescu, C. I.; Rai, D. K. Carbon, Vol. 111 https://doi.org/10.1016/j.carbon.2016.10.040	journal	January 2017
Seven questions about supercritical fluids - towards a new fluid state diagram Banuti, Daniel; Raju, Muralikrishna; Ma, Peter C. 55th AIAA Aerospace Sciences Meeting https://doi.org/10.2514/6.2017-1106	conference	January 2017
Supercritical water gasification of biomass for hydrogen production – Review Rodriguez Correa, Catalina; Kruse, Andrea The Journal of Supercritical Fluids, Vol. 133 https://doi.org/10.1016/j.supflu.2017.09.019	journal	March 2018
Steam tables for pure water as an ActiveX component in Visual Basic 6.0 Verma, Mahendra P. Computers & Geosciences, Vol. 29, Issue 9 https://doi.org/10.1016/S0098-3004(03)00136-5	journal	November 2003
Geologic controls on supercritical geothermal resources above magmatic intrusions Scott, Samuel; Driesner, Thomas; Weis, Philipp ETH Zurich https://doi.org/10.3929/ethz-b-000103244	text	January 2015
Crossing the Widom-line – Supercritical pseudo-boiling Banuti, D. T. The Journal of Supercritical Fluids, Vol. 98 https://doi.org/10.1016/j.supflu.2014.12.019	journal	March 2015
One-dimensional tomography: a comparison of Abel, onion-peeling, and filtered backprojection methods Dasch, Cameron J. Applied Optics, Vol. 31, Issue 8 https://doi.org/10.1364/ao.31.001146	journal	January 1992
Similarity law for Widom lines and coexistence lines Banuti, D. T.; Raju, M.; Ihme, M. Physical Review E, Vol. 95, Issue 5 https://doi.org/10.1103/physreve.95.052120	journal	May 2017
Supercritical Water as a Solvent Weingärtner, Hermann; Franck, Ernst Ulrich Angewandte Chemie International Edition, Vol. 44, Issue 18 https://doi.org/10.1002/anie.200462468	journal	April 2005
Applications of subcritical and supercritical water conditions for extraction, hydrolysis, gasification, and carbonization of biomass: a critical review Lachos-Perez, D.; Brown, A. B.; Mudhoo, A. Biofuel Research Journal, Vol. 4, Issue 2 https://doi.org/10.18331/BRJ2017.4.2.6	journal	June 2017
Dual Spectrum Neutron Radiography: Identification of Phase Transitions between Frozen and Liquid Water Biesdorf, J.; Oberholzer, P.; Bernauer, F. Physical Review Letters, Vol. 112, Issue 24 https://doi.org/10.1103/PhysRevLett.112.248301	journal	June 2014

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