Permeation of CO2 and N 2 through glassy poly(dimethyl phenylene) oxide under steady- and presteady-state conditions

Soniat, Marielle; Tesfaye, Meron; Mafi, Amirhossein; Brooks, Daniel J.; Humphrey, Nicholas D.; Weng, Lien‐Chun; Merinov, Boris; Goddard, William A.; Weber, Adam Z.; Houle, Frances A.

doi:10.1002/pol.20200053

Title: Permeation of CO₂ and N ₂ through glassy poly(dimethyl phenylene) oxide under steady- and presteady-state conditions

Journal Article · Fri Feb 28 00:00:00 EST 2020 · Journal of Polymer Science

DOI:https://doi.org/10.1002/pol.20200053· OSTI ID:1605273

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Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)
California Institute of Technology (CalTech), Pasadena, CA (United States). Beckman Inst.

Glassy polymers are often used for gas separations because of their high selectivity. Although the dual-mode permeation model correctly fits their sorption and permeation isotherms, its physical interpretation is disputed, and it does not describe permeation far from steady state, a condition expected when separations involve intermittent renewable energy sources. To develop a more comprehensive permeation model, we combine experiment, molecular dynamics, and multiscale reaction–diffusion modeling to characterize the time-dependent permeation of N₂ and CO₂ through a glassy poly(dimethyl phenylene oxide) membrane, a model system. Simulations of experimental time-dependent permeation data for both gases in the presteady-state and steady-state regimes show that both single- and dual-mode reaction–diffusion models reproduce the experimental observations, and that sorbed gas concentrations lag the external pressure rise. The results point to environment-sensitive diffusion coefficients as a vital characteristic of transport in glassy polymers.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC02-05CH11231; SC0004993; 07.23.CS.15; DGE 1106400

OSTI ID:: 1605273

Alternate ID(s):: OSTI ID: 1602092

Journal Information:: Journal of Polymer Science, Vol. 58, Issue 9; ISSN 2642-4150

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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References (77)

Molecular simulation of small molecule diffusion and solution in dense amorphous polysiloxanes and polyimides Hofmann, D.; Fritz, L.; Ulbrich, J. Computational and Theoretical Polymer Science, Vol. 10, Issue 5 https://doi.org/10.1016/S1089-3156(00)00007-6	journal	June 2000
Mass Accommodation of Water: Bridging the Gap Between Molecular Dynamics Simulations and Kinetic Condensation Models Julin, Jan; Shiraiwa, Manabu; Miles, Rachael E. H. The Journal of Physical Chemistry A, Vol. 117, Issue 2 https://doi.org/10.1021/jp310594e	journal	January 2013
Gas sorption and transport in poly(phenylene oxide) and comparisons with other glassy polymers Toi, K.; Morel, G.; Paul, D. R. Journal of Applied Polymer Science, Vol. 27, Issue 8 https://doi.org/10.1002/app.1982.070270823	journal	August 1982
Determination of coupled acid catalysis-diffusion processes in a positive-tone chemically amplified photoresist Houle, F. A.; Hinsberg, W. D.; Morrison, M. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 18, Issue 4 https://doi.org/10.1116/1.1303753	journal	January 2000
Powering the planet: Chemical challenges in solar energy utilization Lewis, N. S.; Nocera, D. G. Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735 https://doi.org/10.1073/pnas.0603395103	journal	October 2006
Inert Gas Scattering from Liquid Hydrocarbon Microjets Lancaster, Diane K.; Johnson, Alexis M.; Burden, Daniel K. The Journal of Physical Chemistry Letters, Vol. 4, Issue 18 https://doi.org/10.1021/jz4015212	journal	August 2013
Predictive simulation of non-steady-state transport of gases through rubbery polymer membranes Soniat, Marielle; Tesfaye, Meron; Brooks, Daniel Polymer, Vol. 134 https://doi.org/10.1016/j.polymer.2017.11.055	journal	January 2018
On pressure dependence of the parameters of the dual-mode sorption model Bondar, V. I.; Kamiya, Y.; Yampol'skii, Yu P. Journal of Polymer Science Part B: Polymer Physics, Vol. 34, Issue 2 https://doi.org/10.1002/(SICI)1099-0488(19960130)34:2<369::AID-POLB18>3.0.CO;2-H	journal	January 1996
Permeation and plasticization behavior of glassy polymers: a WAXD interpretation Houde, A. Y.; Kulkarni, S. S.; Kulkarni, M. G. Journal of Membrane Science, Vol. 71, Issue 1-2 https://doi.org/10.1016/0376-7388(92)85011-7	journal	July 1992
Sorption and transport of various gases in polycarbonate Koros, W. J.; Chan, A. H.; Paul, D. R. Journal of Membrane Science, Vol. 2 https://doi.org/10.1016/S0376-7388(00)83242-1	journal	January 1977
Effect of isopropylidene replacement on gas transport properties of polycarbonates McHattie, J. S.; Koros, W. J.; Paul, D. R. Journal of Polymer Science Part B: Polymer Physics, Vol. 29, Issue 6 https://doi.org/10.1002/polb.1991.090290612	journal	May 1991
Integrated Modeling Program, Applied Chemical Theory (IMPACT) Banks, Jay L.; Beard, Hege S.; Cao, Yixiang Journal of Computational Chemistry, Vol. 26, Issue 16 https://doi.org/10.1002/jcc.20292	journal	January 2005
Sorptive dilation and relaxational processes in glassy polymer/gas systems—I. Poly(sulfone) and poly(ether sulfone) Böhning, M.; Springer, J. Polymer, Vol. 39, Issue 21 https://doi.org/10.1016/S0032-3861(97)10114-8	journal	October 1998
Effect of structural symmetry on gas transport properties of polysulfones Aitken, C. L.; Koros, W. J.; Paul, D. R. Macromolecules, Vol. 25, Issue 13 https://doi.org/10.1021/ma00039a018	journal	June 1992
Polymer electrolyte membranes for the direct methanol fuel cell: A review DeLuca, Nicholas W.; Elabd, Yossef A. Journal of Polymer Science Part B: Polymer Physics, Vol. 44, Issue 16 https://doi.org/10.1002/polb.20861	journal	January 2006
Fast Parallel Algorithms for Short-Range Molecular Dynamics Plimpton, Steve Journal of Computational Physics, Vol. 117, Issue 1 https://doi.org/10.1006/jcph.1995.1039	journal	March 1995
Physical aging of thin glassy polymer films: Free volume interpretation Huang, Y.; Wang, X.; Paul, D. Journal of Membrane Science, Vol. 277, Issue 1-2 https://doi.org/10.1016/j.memsci.2005.10.032	journal	June 2006
P-LINCS: A Parallel Linear Constraint Solver for Molecular Simulation Hess, Berk Journal of Chemical Theory and Computation, Vol. 4, Issue 1 https://doi.org/10.1021/ct700200b	journal	December 2007
Molecular simulation of gas permeability: poly(2,6-dimethyl-1,4-phenylene oxide) Fried, J. R.; Sadat-Akhavi, M.; Mark, J. E. Journal of Membrane Science, Vol. 149, Issue 1 https://doi.org/10.1016/S0376-7388(98)00151-3	journal	October 1998
Transport of gases in unmodified and arylbrominated 2,6-dimethyl- 1,4-poly (phenylene oxide) Chern, R. T.; Sheu, F. R.; Jia, L. Journal of Membrane Science, Vol. 35, Issue 1 https://doi.org/10.1016/S0376-7388(00)80925-4	journal	December 1987
Gas separation using polymer membranes: an overview Ghosal, Kanchan; Freeman, Benny D. Polymers for Advanced Technologies, Vol. 5, Issue 11 https://doi.org/10.1002/pat.1994.220051102	journal	November 1994
Scalable Algorithms for Molecular Dynamics Simulations on Commodity Clusters Bowers, Kevin J.; Chow, David E.; Xu, Huafeng SC 2006 Proceedings Supercomputing 2006, ACM/IEEE SC 2006 Conference (SC'06) https://doi.org/10.1109/SC.2006.54	conference	November 2006
Near-Unity Mass Accommodation Coefficient of Organic Molecules of Varying Structure Julin, Jan; Winkler, Paul M.; Donahue, Neil M. Environmental Science & Technology, Vol. 48, Issue 20 https://doi.org/10.1021/es501816h	journal	October 2014
GROMACS: High performance molecular simulations through multi-level parallelism from laptops to supercomputers Abraham, Mark James; Murtola, Teemu; Schulz, Roland SoftwareX, Vol. 1-2 https://doi.org/10.1016/j.softx.2015.06.001	journal	September 2015
GROMACS 4.5: a high-throughput and highly parallel open source molecular simulation toolkit Pronk, Sander; Páll, Szilárd; Schulz, Roland Bioinformatics, Vol. 29, Issue 7 https://doi.org/10.1093/bioinformatics/btt055	journal	February 2013
Kinematics and dynamics of atomic-beam scattering on liquid and self-assembled monolayer surfaces Alexander, William A.; Zhang, Jianming; Murray, Vanessa J. Faraday Discussions, Vol. 157 https://doi.org/10.1039/c2fd20034a	journal	January 2012
Molecular Dynamics Study of Carbon Dioxide Sorption and Plasticization at the Interface of a Glassy Polymer Membrane Neyertz, Sylvie; Brown, David Macromolecules, Vol. 46, Issue 6 https://doi.org/10.1021/ma302073u	journal	March 2013
Permeability and solubility of carbon dioxide in different glassy polymer systems with and without plasticization Minelli, Matteo; Sarti, Giulio C. Journal of Membrane Science, Vol. 444 https://doi.org/10.1016/j.memsci.2013.04.007	journal	October 2013
Oxygen Sorption in Glassy Polymers Studied at the Molecular Level Neyertz, Sylvie; Brown, David Macromolecules, Vol. 42, Issue 21 https://doi.org/10.1021/ma901478d	journal	November 2009
Plasticization behavior in polymers of intrinsic microporosity (PIM-1): A simulation study from combined Monte Carlo and molecular dynamics Kupgan, Grit; Demidov, Alexander G.; Colina, Coray M. Journal of Membrane Science, Vol. 565 https://doi.org/10.1016/j.memsci.2018.08.004	journal	November 2018
Prediction of Absolute Solvation Free Energies using Molecular Dynamics Free Energy Perturbation and the OPLS Force Field Shivakumar, Devleena; Williams, Joshua; Wu, Yujie Journal of Chemical Theory and Computation, Vol. 6, Issue 5 https://doi.org/10.1021/ct900587b	journal	April 2010
PLUMED 2: New feathers for an old bird Tribello, Gareth A.; Bonomi, Massimiliano; Branduardi, Davide Computer Physics Communications, Vol. 185, Issue 2 https://doi.org/10.1016/j.cpc.2013.09.018	journal	February 2014
Water sorption, desorption and transport in Nafion membranes Majsztrik, Paul W.; Satterfield, M. Barclay; Bocarsly, Andrew B. Journal of Membrane Science, Vol. 301, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.06.022	journal	September 2007
Sorption and partial molar volume of small molecules in glassy polymers Kirchheim, R. Macromolecules, Vol. 25, Issue 25 https://doi.org/10.1021/ma00051a036	journal	December 1992
Gas permeation properties of phenylene oxide polymers Alentiev, A.; Drioli, E.; Gokzhaev, M. Journal of Membrane Science, Vol. 138, Issue 1 https://doi.org/10.1016/S0376-7388(97)00219-6	journal	January 1998
Sorption in glassy polymers Vrentas, J. S.; Vrentas, C. M. Macromolecules, Vol. 24, Issue 9 https://doi.org/10.1021/ma00009a043	journal	April 1991
Diffusion and Sorption of Methanol and Water in Nafion Using Time-Resolved Fourier Transform Infrared−Attenuated Total Reflectance Spectroscopy Hallinan, Daniel T.; Elabd, Yossef A. The Journal of Physical Chemistry B, Vol. 111, Issue 46 https://doi.org/10.1021/jp075178n	journal	November 2007
Monitoring multicomponent transport using in situ ATR FTIR spectroscopy Beckingham, Bryan S.; Lynd, Nathaniel A.; Miller, Daniel J. Journal of Membrane Science, Vol. 550 https://doi.org/10.1016/j.memsci.2017.12.072	journal	March 2018
Gas sorption and transport in UV-irradiated poly(2,6-dimethyl-1,4-phenylene oxide) films Wright, C. T.; Paul, D. R. Journal of Applied Polymer Science, Vol. 67, Issue 5 https://doi.org/10.1002/(SICI)1097-4628(19980131)67:5<875::AID-APP13>3.0.CO;2-N	journal	January 1998
Analysis of dual-mode model parameters for gas sorption in glassy polymers Kanehashi, Shinji; Nagai, Kazukiyo Journal of Membrane Science, Vol. 253, Issue 1-2 https://doi.org/10.1016/j.memsci.2005.01.003	journal	May 2005
CO ₂ Sorption Induced Dilation in Polysulfone: Comparative Analysis of Experimental and Molecular Modeling Results Hölck, Ole; Siegert, Martin R.; Heuchel, Matthias Macromolecules, Vol. 39, Issue 26 https://doi.org/10.1021/ma061562r	journal	December 2006
Swelling and Diffusion during Methanol Sorption into Hydrated Nafion Soniat, Marielle; Houle, Frances A. The Journal of Physical Chemistry B, Vol. 122, Issue 34 https://doi.org/10.1021/acs.jpcb.8b03169	journal	August 2018
Sorption and transport of CO2 and CH4 in chemically modified poly(phenylene oxide) Story, Brooks J.; Koros, W. J. Journal of Membrane Science, Vol. 67, Issue 2-3 https://doi.org/10.1016/0376-7388(92)80025-F	journal	March 1992
The solution-diffusion model: a review Wijmans, J. G.; Baker, R. W. Journal of Membrane Science, Vol. 107, Issue 1-2 https://doi.org/10.1016/0376-7388(95)00102-I	journal	November 1995
Gas transport properties of biphenol polysulfones Aitken, C. L.; Koros, W. J.; Paul, D. R. Macromolecules, Vol. 25, Issue 14 https://doi.org/10.1021/ma00040a008	journal	July 1992
Materials Science of Membranes for Gas and Vapor Separation Yampolskii, Yuri; Pinnau, Ingo; Freeman, Benny https://doi.org/10.1002/047002903X	book	June 2006
Gas transport properties of polyphenylene ethers Aguilar-Vega, M.; Paul, D. R. Journal of Polymer Science Part B: Polymer Physics, Vol. 31, Issue 11 https://doi.org/10.1002/polb.1993.090311114	journal	October 1993
Canonical sampling through velocity rescaling Bussi, Giovanni; Donadio, Davide; Parrinello, Michele The Journal of Chemical Physics, Vol. 126, Issue 1 https://doi.org/10.1063/1.2408420	journal	January 2007
Molecular Dynamics Simulations of Water Permeation across Nafion Membrane Interfaces Daly, Kevin B.; Benziger, Jay B.; Panagiotopoulos, Athanassios Z. The Journal of Physical Chemistry B, Vol. 118, Issue 29 https://doi.org/10.1021/jp5024718	journal	July 2014
Probing theα-Helical Structural Stability of Stapled p53 Peptides: Molecular Dynamics Simulations and Analysis Guo, Zuojun; Mohanty, Udayan; Noehre, Justin Chemical Biology & Drug Design, Vol. 75, Issue 4 https://doi.org/10.1111/j.1747-0285.2010.00951.x	journal	April 2010
Polymer Free Volume and Its Connection to the Glass Transition White, Ronald P.; Lipson, Jane E. G. Macromolecules, Vol. 49, Issue 11 https://doi.org/10.1021/acs.macromol.6b00215	journal	May 2016
Probing the microstructure of Nafion-117 using positron annihilation spectroscopy Sodaye, H. S.; Pujari, P. K.; Goswami, A. Journal of Polymer Science Part B: Polymer Physics, Vol. 35, Issue 5 https://doi.org/10.1002/(SICI)1099-0488(19970415)35:5<771::AID-POLB5>3.0.CO;2-P	journal	April 1997
Adsorption of Atmospheric Gases at the Air−Water Interface. I. NH ₃ Donaldson, D. J. The Journal of Physical Chemistry A, Vol. 103, Issue 1 https://doi.org/10.1021/jp9833247	journal	January 1999
Effect of molecular weight and temperature on physical aging of thin glassy poly(2,6-dimethyl-1,4-phenylene oxide) films Huang, Y.; Paul, D. R. Journal of Polymer Science Part B: Polymer Physics, Vol. 45, Issue 12 https://doi.org/10.1002/polb.21173	journal	January 2007
Volume Change of Glassy Polymers by Sorption of Small Molecules and Its Relation to the Intermolecular Space Gotthardt, P.; Grüger, A.; Brion, H. G. Macromolecules, Vol. 30, Issue 25 https://doi.org/10.1021/ma9708252	journal	December 1997
Gas–Surface Scattering Dynamics of CO ₂ , NO ₂ , and O ₃ in Collisions with Model Organic Surfaces Lu, Jessica W.; Morris, John R. The Journal of Physical Chemistry A, Vol. 115, Issue 23 https://doi.org/10.1021/jp111395z	journal	June 2011
Structure and gas permeability of silylated polyphenylene oxide Assogna, A.; Perego, G.; Roggero, A. Journal of Membrane Science, Vol. 71, Issue 1-2 https://doi.org/10.1016/0376-7388(92)85009-8	journal	July 1992
Free Volume Distributions in Ultrahigh and Lower Free Volume Polymers: Comparison between Molecular Modeling and Positron Lifetime Studies Hofmann, D.; Heuchel, M.; Yampolskii, Yu. Macromolecules, Vol. 35, Issue 6 https://doi.org/10.1021/ma011360p	journal	March 2002
Discrete simulation methods in combustion kinetics Bunker, Don L.; Garrett, Bruce; Kleindienst, Tadeusz Combustion and Flame, Vol. 23, Issue 3 https://doi.org/10.1016/0010-2180(74)90120-5	journal	December 1974
Investigation on CO2-induced plasticization in polycarbonate membrane using positron annihilation lifetime spectroscopy Lo, Chia-Hao; Hung, Wei-Song; De Guzman, Manuel Journal of Membrane Science, Vol. 363, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.07.049	journal	November 2010
The effect of structural isomerism on carbon dioxide sorption and plasticization at the interface of a glassy polymer membrane Neyertz, Sylvie; Brown, David Journal of Membrane Science, Vol. 460 https://doi.org/10.1016/j.memsci.2014.03.002	journal	June 2014
An overview of current issues in the uptake of atmospheric trace gases by aerosols and clouds Kolb, C. E.; Cox, R. A.; Abbatt, J. P. D. Atmospheric Chemistry and Physics, Vol. 10, Issue 21 https://doi.org/10.5194/acp-10-10561-2010	journal	January 2010
Molecular Dynamics Simulation of Sub-Transition for Polyethersulfone Shi, Tongfei; Jiang, Wei; An, Lijia Macromolecular Theory and Simulations, Vol. 10, Issue 4 https://doi.org/10.1002/1521-3919(20010401)10:4<232::AID-MATS232>3.0.CO;2-E	journal	April 2001
Effect of antiplasticization on gas sorption and transport. II. Poly(phenylene oxide) Maeda, Y.; Paul, D. R. Journal of Polymer Science Part B: Polymer Physics, Vol. 25, Issue 5 https://doi.org/10.1002/polb.1987.090250502	journal	May 1987
Scaled Effective Solvent Method for Predicting the Equilibrium Ensemble of Structures with Analysis of Thermodynamic Properties of Amorphous Polyethylene Glycol–Water Mixtures Shin, Hyeyoung; Pascal, Tod A.; Goddard, William A. The Journal of Physical Chemistry B, Vol. 117, Issue 3 https://doi.org/10.1021/jp310422q	journal	January 2013
Effect of antiplasticization on gas sorption and transport. III. Free volume interpretation Maeda, Y.; Paul, D. R. Journal of Polymer Science Part B: Polymer Physics, Vol. 25, Issue 5 https://doi.org/10.1002/polb.1987.090250503	journal	May 1987
Quantitative analysis of gaseous diffusion in glassy polymers Petropoulos, J. H. Journal of Polymer Science Part A-2: Polymer Physics, Vol. 8, Issue 10 https://doi.org/10.1002/pol.1970.160081014	journal	October 1970
A smooth particle mesh Ewald method Essmann, Ulrich; Perera, Lalith; Berkowitz, Max L. The Journal of Chemical Physics, Vol. 103, Issue 19 https://doi.org/10.1063/1.470117	journal	November 1995
Unified Dual Mode Description of Small Molecule Sorption and Desorption Kinetics in a Glassy Polymer Guo, Juchen; Barbari, Timothy A. Macromolecules, Vol. 42, Issue 15 https://doi.org/10.1021/ma9007576	journal	August 2009
A general method for numerically simulating the stochastic time evolution of coupled chemical reactions Gillespie, Daniel T. Journal of Computational Physics, Vol. 22, Issue 4 https://doi.org/10.1016/0021-9991(76)90041-3	journal	December 1976
Development and characterization of homopolymers and copolymers from the family of polyphenylene oxides Tran, A.; Kruczek, B. Journal of Applied Polymer Science, Vol. 106, Issue 3 https://doi.org/10.1002/app.26055	journal	January 2007
Nonequilibrium Lattice Fluids: A Predictive Model for the Solubility in Glassy Polymers Doghieri, Ferruccio; Sarti, Giulio C. Macromolecules, Vol. 29, Issue 24 https://doi.org/10.1021/ma951366c	journal	January 1996
Detailed-atomistic molecular modeling of small molecule diffusion and solution processes in polymeric membrane materials Hofmann, Dieter; Fritz, Lydia; Ulbrich, Jens Macromolecular Theory and Simulations, Vol. 9, Issue 6 https://doi.org/10.1002/1521-3919(20000701)9:6<293::AID-MATS293>3.0.CO;2-1	journal	July 2000
Macroscopic Volume Changes versus Changes of Free Volume As Determined by Positron Annihilation Spectroscopy for Polycarbonate and Polystyrene Bohlen, J.; Kirchheim, R. Macromolecules, Vol. 34, Issue 12 https://doi.org/10.1021/ma001297o	journal	June 2001
Subnanometer hole properties of CO2-exposed polysulfone studied by positron annihilation lifetime spectroscopy Yuan, J. -P.; Cao, H.; Hellmuth, E. W. Journal of Polymer Science Part B: Polymer Physics, Vol. 36, Issue 17 https://doi.org/10.1002/(SICI)1099-0488(199812)36:17<3049::AID-POLB5>3.0.CO;2-O	journal	December 1998
Simple kinetic models from Arrhenius to the computer Bunker, Don L. Accounts of Chemical Research, Vol. 7, Issue 6 https://doi.org/10.1021/ar50078a005	journal	June 1974
Instantaneous Liquid Interfaces Willard, Adam P.; Chandler, David The Journal of Physical Chemistry B, Vol. 114, Issue 5 https://doi.org/10.1021/jp909219k	journal	February 2010

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