Gas-Phase Formation of 1-Methylcyclopropene and 3-Methylcyclopropene via the Reaction of the Methylidyne Radical (CH; X 2 Π) with Propylene (CH 3 CHCH 2 ; X 1 A')
- Univ. of Hawaii at Manoa, Honolulu, HI (United States); University of Hawaii at Manoa
- Univ. of Hawaii at Manoa, Honolulu, HI (United States)
- Florida International Univ., Miami, FL (United States); Samara National Research Univ., Samara (Russian Federation)
- Florida International Univ., Miami, FL (United States)
The crossed molecular beam reactions of the methylidyne radical (CH; X2Π) with propylene (CH3CHCH2; X1A') along with (partially) substituted reactants were conducted at collision energies of 19.3 kJ mol–1. Combining our experimental data with ab initio electronic structure and statistical calculations, the methylidyne radical is revealed to add barrierlessly to the carbon–carbon double bond of propylene reactant resulting in a cyclic doublet C4H7 intermediate with a lifetime longer than its rotation period. These adducts undergo a nonstatistical unimolecular decomposition via atomic hydrogen loss through tight exit transition states forming the cyclic products 1-methylcyclopropene and 3-methylcyclopropene with overall reaction exoergicities of 168 ± 25 kJ mol–1. These C4H6 isomers are predicted to exist even in low-temperature environments such as cold molecular clouds like TMC-1, since the reaction is barrierless and exoergic, all transition states are below the energy of the separated reactants, and both the methylidyne radical (CH; X2Π) and propylene reactant were detected in cold molecular clouds such as TMC-1.
- Research Organization:
- Univ. of Hawaii at Manoa, Honolulu, HI (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
- Grant/Contract Number:
- FG02-03ER15411
- OSTI ID:
- 1603231
- Journal Information:
- Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Issue: 49 Vol. 123; ISSN 1089-5639
- Publisher:
- American Chemical SocietyCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Similar Records
Gas-Phase Formation of C5H6 Isomers via the Crossed Molecular Beam Reaction of the Methylidyne Radical (CH; X2Π) with 1,2-Butadiene (CH3CHCCH2; X1A')
Directed gas phase preparation of ethynylallene (H2CCCHCCH; X1A') via the crossed molecular beam reaction of the methylidyne radical (CH; X2Π) with vinylacetylene (H2CCHCCH; X1A')