Reaction Dynamics in Astrochemistry: Low-Temperature Pathways to Polycyclic Aromatic Hydrocarbons in the Interstellar Medium
- Univ. of Hawaii at Manoa, Honolulu, HI (United States)
- Florida International Univ., Miami, FL (United States)
Bimolecular reactions of phenyl-type radicals with the C4 and C5 hydrocarbons vinylacetylene and (methyl-substituted) 1,3-butadiene have been found to synthesize polycyclic aromatic hydrocarbons (PAHs) with naphthalene and 1,4-dihydronaphthalene cores in exoergic and entrance barrierless reactions under single-collision conditions. The reaction mechanism involves the initial formation of a van der Waals complex and addition of a phenyl-type radical to the C1 position of a vinyl-type group through a submerged barrier. Investigations suggest that in the hydrocarbon reactant, the vinyl-type group must be in conjugation with a –C≡CH or –HC=CH2 group to form a resonantly stabilized free radical intermediate, which eventually isomerizes to a cyclic intermediate followed by hydrogen loss and aromatization (PAH formation). Finally, the vinylacetylene-mediated formation of PAHs might be expanded to more complex PAHs, such as anthracene and phenanthrene, in cold molecular clouds via barrierless reactions involving phenyl-type radicals, such as naphthyl, which cannot be accounted for by the classical hydrogen abstraction–acetylene addition mechanism.
- Research Organization:
- Univ. of Hawaii at Manoa, Honolulu, HI (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- FG02-03ER15411; FG02-04ER15570
- OSTI ID:
- 1602874
- Journal Information:
- Annual Review of Physical Chemistry, Vol. 66, Issue 1; ISSN 0066-426X
- Publisher:
- Annual ReviewsCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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