Extracting the Anharmonic Properties of the G-Band in Graphene Nanoplatelets

Efthimiopoulos, Ilias; Mayanna, Sathish; Stavrou, Elissaios; Torode, Antonius; Wang, Yuejian

doi:10.1021/acs.jpcc.9b10875

Extracting the Anharmonic Properties of the G-Band in Graphene Nanoplatelets

Journal Article · Fri Jan 31 00:00:00 EST 2020 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.9b10875· OSTI ID:1602661

^[1]; Mayanna, Sathish ^[2]; ^[3]; Torode, Antonius ^[4]; ^[4]

Oakland Univ., Rochester, MI (United States); Deutsches GeoForschungsZentrum, Potsdam (Germany)
Deutsches GeoForschungsZentrum, Potsdam (Germany)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Oakland Univ., Rochester, MI (United States)

We have examined the effect of temperature and pressure on the Raman-active G-band of graphene nanoplatelets with an average thickness of 4 nm. Measuring the Raman mode frequency and width of the G-band as a function of temperature and pressure allowed us to extract the individual factors contributing to the frequency and width of the G-band, that is, the volumetric (thermal expansion) and anharmonic (phonon–phonon interactions) terms responsible for the Raman shift and the electron–phonon coupling and anharmonic contributions controlling the width/lifetime of the G-band. Considering the available literature, the significant role of the anharmonic effects in understanding the G-band physical processes in carbon-based systems is highlighted.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1602661

Alternate ID(s):: OSTI ID: 1605440

Report Number(s):: LLNL-JRNL--798948; 998963

Journal Information:: Journal of Physical Chemistry. C, Journal Name: Journal of Physical Chemistry. C Journal Issue: 8 Vol. 124; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (65)

Effect of pressure and temperature on Raman spectra of solids: anharmonicity Lucazeau, Guy Journal of Raman Spectroscopy, Vol. 34, Issue 7-8 https://doi.org/10.1002/jrs.1027	journal	January 2003
Raman-based technique for measuring thermal conductivity of graphene and related materials: Thermal conductivity of graphene and related materials Malekpour, Hoda; Balandin, Alexander A. Journal of Raman Spectroscopy, Vol. 49, Issue 1 https://doi.org/10.1002/jrs.5230	journal	September 2017
Raman scattering studies of graphene under high pressure: Raman scattering studies of graphene under high pressure Machon, Denis; Bousige, Colin; Alencar, Rafael Journal of Raman Spectroscopy, Vol. 49, Issue 1 https://doi.org/10.1002/jrs.5284	journal	November 2017
Lattice anharmonicity in low-dimensional carbon systems: Lattice anharmonicity in low-dimensional carbon systems Bonini, Nicola; Rao, Rahul; Rao, Apparao M. physica status solidi (b), Vol. 245, Issue 10 https://doi.org/10.1002/pssb.200879659	journal	September 2008
Thermal expansion coefficients of graphite crystals Morgan, W. C. Carbon, Vol. 10, Issue 1 https://doi.org/10.1016/0008-6223(72)90011-5	journal	February 1972
Graphite thermal expansion relationship for different temperature ranges Tsang, D. K. L.; Marsden, B. J.; Fok, S. L. Carbon, Vol. 43, Issue 14 https://doi.org/10.1016/j.carbon.2005.06.009	journal	November 2005
Anharmonicity of graphite from UV Raman spectroscopy to 2700K Montagnac, G.; Caracas, R.; Bobocioiu, E. Carbon, Vol. 54 https://doi.org/10.1016/j.carbon.2012.11.004	journal	April 2013
The intrinsic temperature-dependent Raman spectra of graphite in the temperature range from 4K to 1000K Liu, H. -N.; Cong, X.; Lin, M. -L. Carbon, Vol. 152 https://doi.org/10.1016/j.carbon.2019.05.016	journal	November 2019
High pressure transformation of graphene nanoplates: A Raman study Lu, Shuangchen; Yao, Mingguang; Yang, Xigui Chemical Physics Letters, Vol. 585 https://doi.org/10.1016/j.cplett.2013.08.085	journal	October 2013
Temperature and pressure dependent Raman spectroscopy of plasma treated multilayer graphene nanosheets Pawbake, Amit S.; Mishra, K. K.; Machuno, Luis G. B. Diamond and Related Materials, Vol. 84 https://doi.org/10.1016/j.diamond.2018.03.021	journal	April 2018
Raman spectroscopy of graphene and graphite: Disorder, electron–phonon coupling, doping and nonadiabatic effects Ferrari, Andrea C. Solid State Communications, Vol. 143, Issue 1-2, p. 47-57 https://doi.org/10.1016/j.ssc.2007.03.052	journal	July 2007
Thermal properties of graphene and multilayer graphene: Applications in thermal interface materials Shahil, Khan M. F.; Balandin, Alexander A. Solid State Communications, Vol. 152, Issue 15 https://doi.org/10.1016/j.ssc.2012.04.034	journal	August 2012
Few-layer graphene under high pressure: Raman and X-ray diffraction studies Clark, S. M.; Jeon, Ki-Joon; Chen, Jing-Yin Solid State Communications, Vol. 154 https://doi.org/10.1016/j.ssc.2012.10.002	journal	January 2013
Phonon Anharmonicity of PdO Studied by Raman Spectrometry Zhao, Zhouying; Elwood, Jacqueline; Carpenter, Michael A. The Journal of Physical Chemistry C, Vol. 119, Issue 40 https://doi.org/10.1021/acs.jpcc.5b07652	journal	September 2015
Thermal Conductivity and Pressure-Dependent Raman Studies of Vertical Graphene Nanosheets Mishra, K. K.; Ghosh, Subrata; Ravindran, T. R. The Journal of Physical Chemistry C, Vol. 120, Issue 43 https://doi.org/10.1021/acs.jpcc.6b08754	journal	October 2016
Infrared Spectroscopic Study of Vibrational Modes across the Orthorhombic–Tetragonal Phase Transition in Methylammonium Lead Halide Single Crystals Schuck, Götz; Többens, Daniel M.; Koch-Müller, Monika The Journal of Physical Chemistry C, Vol. 122, Issue 10 https://doi.org/10.1021/acs.jpcc.7b11499	journal	February 2018
Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene Graf, D.; Molitor, F.; Ensslin, K. Nano Letters, Vol. 7, Issue 2, p. 238-242 https://doi.org/10.1021/nl061702a	journal	February 2007
Temperature Dependence of the Raman Spectra of Graphene and Graphene Multilayers Calizo, I.; Balandin, A. A.; Bao, W. Nano Letters, Vol. 7, Issue 9 https://doi.org/10.1021/nl071033g	journal	September 2007
Superior Thermal Conductivity of Single-Layer Graphene Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong Nano Letters, Vol. 8, Issue 3, p. 902-907 https://doi.org/10.1021/nl0731872	journal	March 2008
Thermal Transport in Suspended and Supported Monolayer Graphene Grown by Chemical Vapor Deposition Cai, Weiwei; Moore, Arden L.; Zhu, Yanwu Nano Letters, Vol. 10, Issue 5, p. 1645-1651 https://doi.org/10.1021/nl9041966	journal	May 2010
Thermal Conductivity of Graphene in Corbino Membrane Geometry Faugeras, Clement; Faugeras, Blaise; Orlita, Milan ACS Nano, Vol. 4, Issue 4 https://doi.org/10.1021/nn9016229	journal	March 2010
Structure of graphite by neutron diffraction Trucano, Peter; Chen, Ruey Nature, Vol. 258, Issue 5531 https://doi.org/10.1038/258136a0	journal	November 1975
The shear mode of multilayer graphene Tan, P. H.; Han, W. P.; Zhao, W. J. Nature Materials, Vol. 11, Issue 4 https://doi.org/10.1038/nmat3245	journal	February 2012
Raman spectroscopy as a versatile tool for studying the properties of graphene Ferrari, Andrea C.; Basko, Denis M. Nature Nanotechnology, Vol. 8, Issue 4 https://doi.org/10.1038/nnano.2013.46	journal	April 2013
Crystal structure of graphite under room-temperature compression and decompression Wang, Yuejian; Panzik, Joseph E.; Kiefer, Boris Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00520	journal	July 2012
Studying disorder in graphite-based systems by Raman spectroscopy Pimenta, M. A.; Dresselhaus, G.; Dresselhaus, M. S. Phys. Chem. Chem. Phys., Vol. 9, Issue 11 https://doi.org/10.1039/b613962k	journal	January 2007
Measurement of specific heat and thermal conductivity of supported and suspended graphene by a comprehensive Raman optothermal method Li, Qin-Yi; Xia, Kailun; Zhang, Ji Nanoscale, Vol. 9, Issue 30 https://doi.org/10.1039/c7nr01695f	journal	January 2017
The intrinsic temperature effect of the Raman spectra of graphite Tan, PingHeng; Deng, YuanMing; Zhao, Qian Applied Physics Letters, Vol. 74, Issue 13 https://doi.org/10.1063/1.123096	journal	March 1999
Anisotropic Thermal Expansion of Pyrolytic Graphite at Low Temperatures Bailey, A. C.; Yates, B. Journal of Applied Physics, Vol. 41, Issue 13 https://doi.org/10.1063/1.1658609	journal	December 1970
Raman Spectrum of Graphite Tuinstra, F.; Koenig, J. L. The Journal of Chemical Physics, Vol. 53, Issue 3 https://doi.org/10.1063/1.1674108	journal	August 1970
General equation for the determination of the crystallite size La of nanographite by Raman spectroscopy Cançado, L. G.; Takai, K.; Enoki, T. Applied Physics Letters, Vol. 88, Issue 16 https://doi.org/10.1063/1.2196057	journal	April 2006
Extremely high thermal conductivity of graphene: Prospects for thermal management applications in nanoelectronic circuits Ghosh, S.; Calizo, I.; Teweldebrhan, D. Applied Physics Letters, Vol. 92, Issue 15, Article No. 151911 https://doi.org/10.1063/1.2907977	journal	April 2008
Ruby under pressure Syassen, K. High Pressure Research, Vol. 28, Issue 2 https://doi.org/10.1080/08957950802235640	journal	June 2008
Graphite at high pressures: Amorphization at 44 GPa Goncharov, A. F. High Pressure Research, Vol. 8, Issue 4 https://doi.org/10.1080/08957959208203223	journal	March 1992
XLI. Precision measurements of crystal parameters Owen, E. A.; Yates, E. L. The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 15, Issue 98 https://doi.org/10.1080/14786443309462199	journal	February 1933
Thermal enhancement of chemical doping in graphene: a Raman spectroscopy study Malard, L. M.; Moreira, R. L.; Elias, D. C. Journal of Physics: Condensed Matter, Vol. 22, Issue 33 https://doi.org/10.1088/0953-8984/22/33/334202	journal	August 2010
Temperature effects on the Raman spectra of graphenes: dependence on the number of layers and doping Late, Dattatray J.; Maitra, Urmimala; Panchakarla, L. S. Journal of Physics: Condensed Matter, Vol. 23, Issue 5 https://doi.org/10.1088/0953-8984/23/5/055303	journal	January 2011
Temperature and layer number dependence of the G and 2D phonon energy and damping in graphene Apostolov, A. T.; Apostolova, I. N.; Wesselinowa, J. M. Journal of Physics: Condensed Matter, Vol. 24, Issue 23 https://doi.org/10.1088/0953-8984/24/23/235401	journal	May 2012
Modelling the coefficient of thermal expansion in graphite crystals: implications of lattice strain due to irradiation and pressure Marsden, Barry; Mummery, Andrew; Mummery, Paul Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 474, Issue 2218 https://doi.org/10.1098/rspa.2018.0075	journal	October 2018
Anharmonic Decay of Optical Phonons Klemens, P. G. Physical Review, Vol. 148, Issue 2 https://doi.org/10.1103/physrev.148.845	journal	August 1966
Temperature Dependence of the Width of the Fundamental Lattice-Vibration Absorption Peak in Ionic Crystals. II. Approximate Numerical Results Ipatova, I. P.; Maradudin, A. A.; Wallis, R. F. Physical Review, Vol. 155, Issue 3 https://doi.org/10.1103/physrev.155.882	journal	March 1967
Pressure Dependence of Infrared Eigenfrequencies of KCl and KBr Postmus, C.; Ferraro, J. R.; Mitra, S. S. Physical Review, Vol. 174, Issue 3 https://doi.org/10.1103/physrev.174.983	journal	October 1968
Self-energy of phonons in an anharmonic crystal of order λ 4 . III. Approximate numerical results for ionic crystals Monga, M. R.; Jindal, V. K.; Pathak, K. N. Physical Review B, Vol. 19, Issue 2 https://doi.org/10.1103/physrevb.19.1230	journal	January 1979
Anharmonic effects in light scattering due to optical phonons in silicon Balkanski, M.; Wallis, R. F.; Haro, E. Physical Review B, Vol. 28, Issue 4 https://doi.org/10.1103/physrevb.28.1928	journal	August 1983
Temperature dependence of the first-order Raman scattering by phonons in Si, Ge, and α − S n : Anharmonic effects Menéndez, José; Cardona, Manuel Physical Review B, Vol. 29, Issue 4 https://doi.org/10.1103/physrevb.29.2051	journal	February 1984
Graphite under pressure: Equation of state and first-order Raman modes Hanfland, M.; Beister, H.; Syassen, K. Physical Review B, Vol. 39, Issue 17 https://doi.org/10.1103/physrevb.39.12598	journal	June 1989
X-ray diffraction data for graphite to 20 GPa Zhao, You Xiang; Spain, Ian L. Physical Review B, Vol. 40, Issue 2 https://doi.org/10.1103/physrevb.40.993	journal	July 1989
Raman scattering in diamond up to 1900 K Zouboulis, E. S.; Grimsditch, M. Physical Review B, Vol. 43, Issue 15 https://doi.org/10.1103/physrevb.43.12490	journal	May 1991
High-pressure in situ x-ray-diffraction study of the phase transformation from graphite to hexagonal diamond at room temperature Yagi, Takehiko; Utsumi, Wataru; Yamakata, Masa-aki Physical Review B, Vol. 46, Issue 10 https://doi.org/10.1103/physrevb.46.6031	journal	September 1992
Raman-scattering probe of anharmonic effects in GaAs Verma, Prabhat; Abbi, S. C.; Jain, K. P. Physical Review B, Vol. 51, Issue 23 https://doi.org/10.1103/physrevb.51.16660	journal	June 1995
First-principles determination of the structural, vibrational and thermodynamic properties of diamond, graphite, and derivatives Mounet, Nicolas; Marzari, Nicola Physical Review B, Vol. 71, Issue 20 https://doi.org/10.1103/physrevb.71.205214	journal	May 2005
Phonon dispersion of graphite by inelastic x-ray scattering Mohr, M.; Maultzsch, J.; Dobardžić, E. Physical Review B, Vol. 76, Issue 3 https://doi.org/10.1103/physrevb.76.035439	journal	July 2007
Theory of the evolution of phonon spectra and elastic constants from graphene to graphite Michel, K. H.; Verberck, B. Physical Review B, Vol. 78, Issue 8 https://doi.org/10.1103/physrevb.78.085424	journal	August 2008
Uniaxial strain in graphene by Raman spectroscopy: G peak splitting, Grüneisen parameters, and sample orientation Mohiuddin, T. M. G.; Lombardo, A.; Nair, R. R. Physical Review B, Vol. 79, Issue 20 https://doi.org/10.1103/physrevb.79.205433	journal	May 2009
High-pressure Raman spectroscopy of graphene Proctor, John E.; Gregoryanz, Eugene; Novoselov, Konstantin S. Physical Review B, Vol. 80, Issue 7 https://doi.org/10.1103/physrevb.80.073408	journal	August 2009
Anharmonic phonon effects in Raman spectra of unsupported vertical graphene sheets Lin, Jingjing; Guo, Liwei; Huang, Qingsong Physical Review B, Vol. 83, Issue 12 https://doi.org/10.1103/physrevb.83.125430	journal	March 2011
Temperature evolution of infrared- and Raman-active phonons in graphite Giura, P.; Bonini, N.; Creff, G. Physical Review B, Vol. 86, Issue 12 https://doi.org/10.1103/physrevb.86.121404	journal	September 2012
Raman spectroscopy of graphene at high pressure: Effects of the substrate and the pressure transmitting media Filintoglou, K.; Papadopoulos, N.; Arvanitidis, J. Physical Review B, Vol. 88, Issue 4 https://doi.org/10.1103/physrevb.88.045418	journal	July 2013
Pressure-Raman effects and vibrational scaling laws in molecular crystals: S 8 and As 2 S 3 Zallen, Richard Physical Review B, Vol. 9, Issue 10 https://doi.org/10.1103/physrevb.9.4485	journal	May 1974
Crystal Structure of Cold Compressed Graphite Amsler, Maximilian; Flores-Livas, José A.; Lehtovaara, Lauri Physical Review Letters, Vol. 108, Issue 6 https://doi.org/10.1103/physrevlett.108.065501	journal	February 2012
Phonon Anharmonicities in Graphite and Graphene Bonini, Nicola; Lazzeri, Michele; Marzari, Nicola Physical Review Letters, Vol. 99, Issue 17 https://doi.org/10.1103/physrevlett.99.176802	journal	October 2007
Bonding Changes in Compressed Superhard Graphite Mao, W. L. Science, Vol. 302, Issue 5644 https://doi.org/10.1126/science.1089713	journal	October 2003
In situ high-temperature Raman and FTIR spectroscopy of the phase transformation of lizardite Trittschack, R.; Grobety, B.; Koch-Muller, M. American Mineralogist, Vol. 97, Issue 11-12 https://doi.org/10.2138/am.2012.4162	journal	October 2012
From soft to superhard: Fifty years of experiments on cold-compressed graphite Wang, Y.; Lee, K. K. M. Journal of Superhard Materials, Vol. 34, Issue 6 https://doi.org/10.3103/s106345761206010x	journal	November 2012
Graphene Nanoplatelets-Based Advanced Materials and Recent Progress in Sustainable Applications Cataldi, Pietro; Athanassiou, Athanassia; Bayer, Ilker Applied Sciences, Vol. 8, Issue 9 https://doi.org/10.3390/app8091438	journal	August 2018

Similar Records

Probing electronic lifetimes and phonon anharmonicities in high-quality chemical vapor deposited graphene by magneto-Raman spectroscopy

Journal Article · Sun Dec 06 23:00:00 EST 2015 · Applied Physics Letters · OSTI ID:22486204

Phonon Anharmonicities in Graphite and Graphene.

Journal Article · Wed Oct 24 00:00:00 EDT 2007 · Physical Review Letters, 99(176802):1-4 · OSTI ID:921224

Anisotropic thermal expansion and anharmonic phonon behavior of mullite-type Bi{sub 2}Ga{sub 4}O{sub 9}

Journal Article · Sun Sep 01 00:00:00 EDT 2013 · Materials Research Bulletin · OSTI ID:22341772

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
Anode materials
Carbon
Phonons
Raman spectroscopy
Two dimensional materials

Extracting the Anharmonic Properties of the G-Band in Graphene Nanoplatelets

Citation Formats

References (65)

Similar Records

Related Subjects