Materializing rival ground states in the barlowite family of kagome magnets: quantum spin liquid, spin ordered, and valence bond crystal states

Smaha, Rebecca W.; He, Wei; Jiang, Jack Mingde; Wen, Jiajia; Jiang, Yi-Fan; Sheckelton, John P.; Titus, Charles J.; Wang, Suyin Grass; Chen, Yu-Sheng; Teat, Simon J.; Aczel, Adam A.; Zhao, Yang; Xu, Guangyong; Lynn, Jeffrey W.; Jiang, Hong-Chen; Lee, Young S.

doi:10.1038/s41535-020-0222-8

Materializing rival ground states in the barlowite family of kagome magnets: quantum spin liquid, spin ordered, and valence bond crystal states

Journal Article · Tue Apr 14 00:00:00 EDT 2020 · npj Quantum Materials

DOI:https://doi.org/10.1038/s41535-020-0222-8· OSTI ID:1602253

^[1]; ; ; ; ; ; ; ; ; ; ; ; Xu, Guangyong; ; ;

SIMES

The spin-

\frac{1}{2}

kagome antiferromagnet is considered an ideal host for a quantum spin liquid ground state. We find that when the bonds of the kagome lattice are modulated with a periodic pattern, new quantum ground states emerge. Newly synthesized crystalline barlowite (Cu₄(OH)₆FBr) and Zn-substituted barlowite demonstrate the delicate interplay between singlet states and spin order on the spin-

\frac{1}{2}

kagome lattice. Comprehensive structural measurements demonstrate that our new variant of barlowite maintains hexagonal symmetry at low temperatures with an arrangement of distorted and undistorted kagome triangles, for which numerical simulations predict a pinwheel va- lence bond crystal (VBC) state instead of a quantum spin liquid (QSL). The presence of interlayer spins eventually leads to an interesting pinwheel q=0 magnetic order. Partially Zn-substituted bar- lowite (Cu_3.44Zn_0.56(OH)₆FBr) has an ideal kagome lattice and shows QSL behavior, indicating a surprising robustness of the QSL against interlayer impurities. The magnetic susceptibility is simi- lar to that of herbertsmithite, even though the Cu²⁺ impurities are above the percolation threshold for the interlayer lattice and they couple more strongly to the nearest kagome moment. This system is a unique playground displaying QSL, VBC, and spin order, furthering our understanding of these highly competitive quantum states.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-05CH11231; AC02-06CH11357; AC02-76SF00515; AC05-00OR22725

OSTI ID:: 1602253

Alternate ID(s):: OSTI ID: 1617810

Journal Information:: npj Quantum Materials, Journal Name: npj Quantum Materials Journal Issue: 1 Vol. 5; ISSN 2397-4648

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (64)

Structural phase transitions of clinoatacamite and the dynamic Jahn–Teller effect Malcherek, Thomas; Mihailova, Boriana; Welch, Mark D. Physics and Chemistry of Minerals, Vol. 44, Issue 5 https://doi.org/10.1007/s00269-016-0859-9	journal	November 2016
Quantum kagome frustrated antiferromagnets: One route to quantum spin liquids Mendels, Philippe; Bert, Fabrice Comptes Rendus Physique, Vol. 17, Issue 3-4 https://doi.org/10.1016/j.crhy.2015.12.001	journal	March 2016
Synthesis-dependent properties of barlowite and Zn-substituted barlowite Smaha, Rebecca W.; He, Wei; Sheckelton, John P. Journal of Solid State Chemistry, Vol. 268 https://doi.org/10.1016/j.jssc.2018.08.016	journal	December 2018
Neutron Scattering with a Triple-Axis Spectrometer Shirane, Gen; Shapiro, Stephen M.; Tranquada, John M. https://doi.org/10.1017/CBO9780511534881	book	January 2009
Structural Phase Transition in the S = 1 / 2 Kagome System Cs 2 ZrCu 3 F 12 and a Comparison to the Valence-Bond-Solid Phase in Rb 2 SnCu 3 F 12 Reisinger, Sandra A.; Tang, Chiu C.; Thompson, Stephen P. Chemistry of Materials, Vol. 23, Issue 18 https://doi.org/10.1021/cm201762f	journal	September 2011
A Structurally Perfect S = ¹ / ₂ Kagomé Antiferromagnet Shores, Matthew P.; Nytko, Emily A.; Bartlett, Bart M. Journal of the American Chemical Society, Vol. 127, Issue 39 https://doi.org/10.1021/ja053891p	journal	October 2005
Site Specific X-ray Anomalous Dispersion of the Geometrically Frustrated Kagomé Magnet, Herbertsmithite, ZnCu ₃ (OH) ₆ Cl ₂ Freedman, Danna E.; Han, Tianheng H.; Prodi, Andrea Journal of the American Chemical Society, Vol. 132, Issue 45 https://doi.org/10.1021/ja1070398	journal	November 2010
Spin liquids in frustrated magnets Balents, Leon Nature, Vol. 464, Issue 7286 https://doi.org/10.1038/nature08917	journal	March 2010
Fractionalized excitations in the spin-liquid state of a kagome-lattice antiferromagnet Han, Tian-Heng; Helton, Joel S.; Chu, Shaoyan Nature, Vol. 492, Issue 7429 https://doi.org/10.1038/nature11659	journal	December 2012
Pinwheel valence-bond solid and triplet excitations in the two-dimensional deformed kagome lattice Matan, K.; Ono, T.; Fukumoto, Y. Nature Physics, Vol. 6, Issue 11 https://doi.org/10.1038/nphys1761	journal	September 2010
Identifying topological order by entanglement entropy Jiang, Hong-Chen; Wang, Zhenghan; Balents, Leon Nature Physics, Vol. 8, Issue 12 https://doi.org/10.1038/nphys2465	journal	November 2012
Order–disorder transition in the S = ½ kagome antiferromagnets claringbullite and barlowite Henderson, Alyssa; Dong, Lianyang; Biswas, Sananda Chemical Communications, Vol. 55, Issue 77 https://doi.org/10.1039/C9CC04930D	journal	January 2019
Quantum spin liquids: a review Savary, Lucile; Balents, Leon Reports on Progress in Physics, Vol. 80, Issue 1 https://doi.org/10.1088/0034-4885/80/1/016502	journal	November 2016
Gapped Spin-1/2 Spinon Excitations in a New Kagome Quantum Spin Liquid Compound Cu ₃ Zn(OH) ₆ FBr Feng, Zili; Li, Zheng; Meng, Xin Chinese Physics Letters, Vol. 34, Issue 7 https://doi.org/10.1088/0256-307X/34/7/077502	journal	June 2017
From Claringbullite to a New Spin Liquid Candidate Cu ₃ Zn(OH) ₆ FCl Feng, Zili; Yi, Wei; Zhu, Kejia Chinese Physics Letters, Vol. 36, Issue 1 https://doi.org/10.1088/0256-307X/36/1/017502	journal	December 2018
Structural and magnetic phase transitions of AV ₆ O ₁₁ (A = Na, Sr, and Pb) Kato, Harukazu; Kato, Masaki; Yoshimura, Kazuyoshi Journal of Physics: Condensed Matter, Vol. 13, Issue 41 https://doi.org/10.1088/0953-8984/13/41/319	journal	September 2001
On the crystal and magnetic ordering structures of clinoatacamite, γ-Cu ₂ (OD) ₃ Cl, a proposed valence bond solid Wills, A. S.; Henry, J-Y Journal of Physics: Condensed Matter, Vol. 20, Issue 47 https://doi.org/10.1088/0953-8984/20/47/472206	journal	November 2008
Kagome´- and triangular-lattice Heisenberg antiferromagnets: Ordering from quantum fluctuations and quantum-disordered ground states with unconfined bosonic spinons Sachdev, Subir Physical Review B, Vol. 45, Issue 21 https://doi.org/10.1103/PhysRevB.45.12377	journal	June 1992
Dirac structure, RVB, and Goldstone modes in the kagomé antiferromagnet Hastings, M. B. Physical Review B, Vol. 63, Issue 1 https://doi.org/10.1103/PhysRevB.63.014413	journal	December 2000
Hidden long-range order in kagomé Heisenberg antiferromagnets Syromyatnikov, A. V.; Maleyev, S. V. Physical Review B, Vol. 66, Issue 13 https://doi.org/10.1103/PhysRevB.66.132408	journal	October 2002
Physics of low-energy singlet states of the Kagome lattice quantum Heisenberg antiferromagnet Nikolic, P.; Senthil, T. Physical Review B, Vol. 68, Issue 21 https://doi.org/10.1103/PhysRevB.68.214415	journal	December 2003
Low temperature magnetization of the S = 1 2 kagome antiferromagnet Zn Cu 3 ( O H ) 6 Cl 2 Bert, F.; Nakamae, S.; Ladieu, F. Physical Review B, Vol. 76, Issue 13 https://doi.org/10.1103/PhysRevB.76.132411	journal	October 2007
Ground state of the spin-1/2 kagome-lattice Heisenberg antiferromagnet Singh, Rajiv R. P.; Huse, David A. Physical Review B, Vol. 76, Issue 18 https://doi.org/10.1103/PhysRevB.76.180407	journal	November 2007
X-ray scattering study of the spin-Peierls transition and soft phonon behavior in TiOCl Abel, E. T.; Matan, K.; Chou, F. C. Physical Review B, Vol. 76, Issue 21 https://doi.org/10.1103/PhysRevB.76.214304	journal	December 2007
Properties of an algebraic spin liquid on the kagome lattice Hermele, Michael; Ran, Ying; Lee, Patrick A. Physical Review B, Vol. 77, Issue 22 https://doi.org/10.1103/PhysRevB.77.224413	journal	June 2008
Schwinger-boson approach to the kagome antiferromagnet with Dzyaloshinskii-Moriya interactions: Phase diagram and dynamical structure factors Messio, L.; Cépas, O.; Lhuillier, C. Physical Review B, Vol. 81, Issue 6 https://doi.org/10.1103/PhysRevB.81.064428	journal	February 2010
Quantum criticality of the kagome antiferromagnet with Dzyaloshinskii-Moriya interactions Huh, Yejin; Fritz, Lars; Sachdev, Subir Physical Review B, Vol. 81, Issue 14 https://doi.org/10.1103/PhysRevB.81.144432	journal	April 2010
Synthesis and characterization of single crystals of the spin- 1 2 kagome-lattice antiferromagnets Zn x Cu 4 − x (OH) 6 Cl 2 Han, T. H.; Helton, J. S.; Chu, S. Physical Review B, Vol. 83, Issue 10 https://doi.org/10.1103/PhysRevB.83.100402	journal	March 2011
Spin- 1 2 Heisenberg antiferromagnet on the kagome lattice: Z 2 spin liquid with fermionic spinons Hao, Zhihao; Tchernyshyov, Oleg Physical Review B, Vol. 87, Issue 21 https://doi.org/10.1103/PhysRevB.87.214404	journal	June 2013
First-principles determination of Heisenberg Hamiltonian parameters for the spin- 1 2 kagome antiferromagnet ZnCu 3 (OH) 6 Cl 2 Jeschke, Harald O.; Salvat-Pujol, Francesc; Valentí, Roser Physical Review B, Vol. 88, Issue 7 https://doi.org/10.1103/PhysRevB.88.075106	journal	August 2013
Renormalization group analysis of competing quantum phases in the J 1 - J 2 Heisenberg model on the kagome lattice Suttner, Raik; Platt, Christian; Reuther, Johannes Physical Review B, Vol. 89, Issue 2 https://doi.org/10.1103/PhysRevB.89.020408	journal	January 2014
Chiral and critical spin liquids in a spin- 1 2 kagome antiferromagnet Zhu, W.; Gong, S. S.; Sheng, D. N. Physical Review B, Vol. 92, Issue 1 https://doi.org/10.1103/PhysRevB.92.014424	journal	July 2015
Barlowite as a canted antiferromagnet: Theory and experiment Jeschke, Harald O.; Salvat-Pujol, Francesc; Gati, Elena Physical Review B, Vol. 92, Issue 9 https://doi.org/10.1103/PhysRevB.92.094417	journal	September 2015
Selectively doping barlowite for quantum spin liquid: A first-principles study Liu, Zheng; Zou, Xiaolong; Mei, Jia-Wei Physical Review B, Vol. 92, Issue 22 https://doi.org/10.1103/PhysRevB.92.220102	journal	December 2015
Anisotropy: Spin order and magnetization of single-crystalline Cu 4 ( OH ) 6 FBr barlowite Han, Tian-Heng; Isaacs, Eric D.; Schlueter, John A. Physical Review B, Vol. 93, Issue 21 https://doi.org/10.1103/PhysRevB.93.214416	journal	June 2016
Correlated impurities and intrinsic spin-liquid physics in the kagome material herbertsmithite Han, Tian-Heng; Norman, M. R.; Wen, J. -J. Physical Review B, Vol. 94, Issue 6 https://doi.org/10.1103/PhysRevB.94.060409	journal	August 2016
Reduction of magnetic interlayer coupling in barlowite through isoelectronic substitution Guterding, Daniel; Valentí, Roser; Jeschke, Harald O. Physical Review B, Vol. 94, Issue 12 https://doi.org/10.1103/PhysRevB.94.125136	journal	September 2016
Gapped spin liquid with Z 2 topological order for the kagome Heisenberg model Mei, Jia-Wei; Chen, Ji-Yao; He, Huan Physical Review B, Vol. 95, Issue 23 https://doi.org/10.1103/PhysRevB.95.235107	journal	June 2017
Effect of Zn doping on the antiferromagnetism in kagome Cu 4 − x Zn x ( OH ) 6 FBr Feng, Zili; Wei, Yuan; Liu, Ran Physical Review B, Vol. 98, Issue 15 https://doi.org/10.1103/PhysRevB.98.155127	journal	October 2018
Bond and site percolation in three dimensions Wang, Junfeng; Zhou, Zongzheng; Zhang, Wei Physical Review E, Vol. 87, Issue 5 https://doi.org/10.1103/PhysRevE.87.052107	journal	May 2013
External Magnetic Field Effects on a Distorted Kagome Antiferromagnet Kim, J. -H.; Ji, S.; Lee, S. -H. Physical Review Letters, Vol. 101, Issue 10 https://doi.org/10.1103/PhysRevLett.101.107201	journal	September 2008
Density Matrix Renormalization Group Numerical Study of the Kagome Antiferromagnet Jiang, H. C.; Weng, Z. Y.; Sheng, D. N. Physical Review Letters, Vol. 101, Issue 11 https://doi.org/10.1103/PhysRevLett.101.117203	journal	September 2008
Refining the Spin Hamiltonian in the Spin- 1 2 Kagome Lattice Antiferromagnet ZnCu 3 ( OH ) 6 Cl 2 Using Single Crystals Han, Tianheng; Chu, Shaoyan; Lee, Young S. Physical Review Letters, Vol. 108, Issue 15 https://doi.org/10.1103/PhysRevLett.108.157202	journal	April 2012
Nature of the Spin-Liquid Ground State of the S = 1 / 2 Heisenberg Model on the Kagome Lattice Depenbrock, Stefan; McCulloch, Ian P.; Schollwöck, Ulrich Physical Review Letters, Vol. 109, Issue 6 https://doi.org/10.1103/PhysRevLett.109.067201	journal	August 2012
Striped Spin Liquid Crystal Ground State Instability of Kagome Antiferromagnets Clark, Bryan K.; Kinder, Jesse M.; Neuscamman, Eric Physical Review Letters, Vol. 111, Issue 18 https://doi.org/10.1103/PhysRevLett.111.187205	journal	November 2013
Barlowite: A Spin- 1 / 2 Antiferromagnet with a Geometrically Perfect Kagome Motif Han, Tian-Heng; Singleton, John; Schlueter, John A. Physical Review Letters, Vol. 113, Issue 22 https://doi.org/10.1103/PhysRevLett.113.227203	journal	November 2014
Gapless Spin-Liquid Ground State in the S = 1 / 2 Kagome Antiferromagnet Liao, H. J.; Xie, Z. Y.; Chen, J. Physical Review Letters, Vol. 118, Issue 13 https://doi.org/10.1103/PhysRevLett.118.137202	journal	March 2017
Density matrix formulation for quantum renormalization groups White, Steven R. Physical Review Letters, Vol. 69, Issue 19 https://doi.org/10.1103/PhysRevLett.69.2863	journal	November 1992
Spin Dynamics of the Spin- 1 / 2 Kagome Lattice Antiferromagnet ZnCu 3 ( OH ) 6 Cl 2 Helton, J. S.; Matan, K.; Shores, M. P. Physical Review Letters, Vol. 98, Issue 10 https://doi.org/10.1103/PhysRevLett.98.107204	journal	March 2007
Projected-Wave-Function Study of the Spin- 1 / 2 Heisenberg Model on the Kagomé Lattice Ran, Ying; Hermele, Michael; Lee, Patrick A. Physical Review Letters, Vol. 98, Issue 11 https://doi.org/10.1103/PhysRevLett.98.117205	journal	March 2007
Single-crystal growth of C u 4 ( OH ) 6 BrF and universal behavior in quantum spin liquid candidates synthetic barlowite and herbertsmithite Pasco, C. M.; Trump, B. A.; Tran, Thao T. Physical Review Materials, Vol. 2, Issue 4 https://doi.org/10.1103/PhysRevMaterials.2.044406	journal	April 2018
Nuclear and magnetic structures of the frustrated quantum antiferromagnet barlowite, Cu 4 ( OH ) 6 FBr Tustain, K.; Nilsen, G. J.; Ritter, C. Physical Review Materials, Vol. 2, Issue 11 https://doi.org/10.1103/PhysRevMaterials.2.111405	journal	November 2018
Colloquium : Herbertsmithite and the search for the quantum spin liquid Norman, M. R. Reviews of Modern Physics, Vol. 88, Issue 4 https://doi.org/10.1103/RevModPhys.88.041002	journal	December 2016
OLEX2 : a complete structure solution, refinement and analysis program Dolomanov, Oleg V.; Bourhis, Luc J.; Gildea, Richard J. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889808042726	journal	January 2009
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data Momma, Koichi; Izumi, Fujio Journal of Applied Crystallography, Vol. 44, Issue 6 https://doi.org/10.1107/S0021889811038970	journal	October 2011
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Bilbao Crystallographic Server. II. Representations of crystallographic point groups and space groups Aroyo, Mois I.; Kirov, Asen; Capillas, Cesar Acta Crystallographica Section A Foundations of Crystallography, Vol. 62, Issue 2 https://doi.org/10.1107/S0108767305040286	journal	March 2006
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
Spin-Liquid Ground State of the S = 1/2 Kagome Heisenberg Antiferromagnet Yan, S.; Huse, D. A.; White, S. R. Science, Vol. 332, Issue 6034 https://doi.org/10.1126/science.1201080	journal	April 2011
Evidence for a gapped spin-liquid ground state in a kagome Heisenberg antiferromagnet Fu, M.; Imai, T.; Han, T. -H. Science, Vol. 350, Issue 6261 https://doi.org/10.1126/science.aab2120	journal	November 2015
Symmetry-Based Computational Tools for Magnetic Crystallography Perez-Mato, J. M.; Gallego, S. V.; Tasci, E. S. Annual Review of Materials Research, Vol. 45, Issue 1 https://doi.org/10.1146/annurev-matsci-070214-021008	journal	July 2015
Herbertsmithite, Cu ₃ Zn(OH) ₆ Cl ₂ , a new species, and the definition of paratacamite Braithwaite, R. S. W.; Mereiter, K.; Paar, W. H. Mineralogical Magazine, Vol. 68, Issue 3 https://doi.org/10.1180/0026461046830204	journal	June 2004
Claringbullite, a new hydrated copper chloride Fejer, E. E.; Clark, A. M.; Couper, A. G. Mineralogical Magazine, Vol. 41, Issue 320 https://doi.org/10.1180/minmag.1977.041.320.02	journal	December 1977
Barlowite, Cu ₄ FBr(OH) ₆ , a new mineral isotructural with claringbullite: description and crystal structure Elliott, Peter; Cooper, Mark A.; Pring, Allan Mineralogical Magazine, Vol. 78, Issue 7 https://doi.org/10.1180/minmag.2014.078.7.17	journal	December 2014

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CSD 1898751: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21qt1n The current record is supplemented by this dataset	dataset	January 2020
CSD 1898752: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21qt2p The current record is supplemented by this dataset	dataset	January 2020
CSD 1898753: Experimental Crystal Structure Determination W., Smaha, Rebecca; Wei, He,; Mingde, Jiang, Jack https://doi.org/10.25505/fiz.icsd.cc21qt3q The current record is supplemented by this dataset	dataset	January 2020
CSD 1898754: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21qt4r The current record is supplemented by this dataset	dataset	January 2020
CSD 1898756: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21qt6t The current record is supplemented by this dataset	dataset	January 2020
CSD 1899242: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21r9w0 The current record is supplemented by this dataset	dataset	January 2020
CSD 1899243: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21r9x1 The current record is supplemented by this dataset	dataset	January 2020
CSD 1899250: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21rb49 The current record is supplemented by this dataset	dataset	January 2020
CSD 1899252: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21rb6c The current record is supplemented by this dataset	dataset	January 2020
CSD 1899365: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21rfv3 The current record is supplemented by this dataset	dataset	January 2020
CSD 1899367: Experimental Crystal Structure Determination W., Smaha, R.; W., He,; M., Jiang, J. https://doi.org/10.25505/fiz.icsd.cc21rfx5 The current record is supplemented by this dataset	dataset	January 2020
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Materializing rival ground states in the barlowite family of kagome magnets: quantum spin liquid, spin ordered, and valence bond crystal states

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